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The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-烯丙基苯基苄基醚产生苄正离子,苄正离子亲电进攻3,4,5-三甲氧基甲苯从而进行傅氏烷基化反应的。

Allyl glycidyl ether was synthesized from allyl alcohol and epichlorohydrin by phase transfer catalysis.

以烯丙醇和环氧氯丙烷为原料,采用相转移催化法,合成了烯丙基缩水甘油醚。

In the first part, we studied the possibility of allyl as the protection group of the hydroxyl in nucleosides.

烯丙基作为糖化学中的一种常用保护基在核酸化学中有一定的应用,曾有人将它作为磷酸酯键及碱基环上羰基的保护基,但作为核苷糖环羟基的保护基还未有研究。

The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.

醚化反应中固体烯丙醇钠与环氧氯丙烷摩尔比为1:1.5,在无水条件下于30℃反应3 h,烯丙基缩水甘油醚的收率达96%以上。

Of these end groups those having an allylic chlorine might be expected to show the highest activity.

在这些端基中,带有烯丙基氯原子的端基活性最高。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章,我们研究了在水相介质中金属铟促进的烯丙基溴对1,1-二氰基-2-芳基乙烯的Michael加成反应,生成一个含碳碳双键和二个碳氮叁键的三官能团化合物,另外,金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联,生成砜。

Because these substrates are synthesized from the corresponding allylic alcohols, palladium-catalyzed conversion of allylic alcohols directly into allylation products are highly desirable, especially from the viewpoint of the atom economy.

因为这些受质是从烯丙醇合成的,钯催化烯丙醇转换直接变成烯丙基化合物从原子经济的观点来看是较有益处的。

Thestercoselectivity of the reaction of propargylide was different completely from that of the reactionof telluronium 3-trimethylsilylalltide with α,β-unsaturaled ketones and trans-trimethysilylacetylenyl-l-benzoyleyelopropane derivatives were obtained.

发现这一反应的立体化学与同样条件下含硅烯丙基碲叶立德和α,β-不饱和酮反应的立体化学完全不同,得到的是又式-2-三甲基硅基乙炔基-1-酮基环丙烷衍生物。

E. . The epoxidation of cis-allylic alcohols is difficult, and with 20%mol Ti 〓 and 30%mol tartrates, up to 80%e.

的对映选择性被得到;对难于环氧化的顺式烯丙基醇,使用20%mol四异丙氧基钛和30%mol酒石酸酯得到最高80%e.e。

The results of IR and DSC indicated that the curing reaction of BMI-modified phenolic resin mainly consists of two steps: the allyl groups in the Novolak resin react with maleimide group via"Ene"addition, and addition reactions of the C=C bonds formed thereby are followed.

IR与DSC方法研究表明:BMI改性酚醛树脂的固化反应主要是Novolak树脂上的烯丙基首先与酰亚胺基团的烯加成反应,然后烯加成反应所形成的C=C双键发生进一步加成。

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