烯丙基

Sodium allylate was prepared from solid sodium hydroxide and allyl alcohol under mild conditions, and then the solid sodium allylate was reacted with epichlorohydrin in anhydrous system to produce allyl glycidyl ether in high yield and purity.

以固体NaOH和烯丙醇为原料在温和条件下制得烯丙醇钠，再以固体烯丙醇钠为原料，与环氧氯丙烷在无水条件下高产率地得到高纯度的烯丙基缩水甘油醚。

The carbonylation of allyl bromide and hydrogenation of 1-octene were carried out under atmospheric pressure and at 40℃.

研究了它们在烯丙基溴的常压羰基化反应和1-辛烯的常压加氢反应中的催化性能。

Third, Polymerization behaviors of alkenyl substituted Cp Lanthanide complexes as Methyl Methacrylate polymerization catalysts were also studied.

最后，本文还分别考察了烯丁基和烯丙基取代茂的稀土络合物对甲基丙烯酸甲酯的催化聚合反应。

Among the existing means to construct these synthetically and biologically important molecules, metal-mediated allylation and propargylation is one of the easiest and most convenient.

在现存的用来构建这些重要的合成子和生物分子的方法中，金属促进的羰基化合物烯丙基化和炔丙基化是最容易和最方便的。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下，利用2，4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应，合成了中间体4-丙氧基－2-羟基二苯甲酮，将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发，通过与叠氮化钠和碘化物的一锅法1，3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

To improve the effect of CDCA on dissolving cholesterol gallstone, the water-soluble copolymers as polycarboxylic acid of comb-like copolymers and C_(60)-PCC were synthesized, which being used for modification of CDCA and strengthening effects of CDCA on dissolving the cholesterol gallstones by their entropy-repelled properties of comb-shaped side chains in buffers of phosphate and in model bile.The design theory of polymer was mainly employed to synthesis the conjugate of PCC-CDCA and C_(60)-PCC-CDCA by C_(60), polyoxyalkylene allylalkyldiether and maleic anhydride, which were copolymerized with AIBN as initiator, and then PCC or C_(60)-PCC were reacted with CDCA. The structures of the copolymers and the conjugates of PCC-CDCA and C_(60)-PCC-CDCA were confirmed with IR, TLC and TEM. The dissolving effects and the dissolution kinetics mechanism of cholesterol gallstone was inverstigated in PBS and in model bile of different cholesterol saturated index at pH7.4, including PCC-CDCA or C_(60)-PCC-CDCA.

利用高分子设计理论，以烯丙基聚氧乙烯基醚、顺丁烯二酸酐、C_(60)和CDCA为原料，以偶氮二异丁腈为引发剂，合成具有梳状侧链结构的梳状共聚物-CDCA结合物和C_(60)-梳状共聚物-CDCA结合物，以IR、TLC和TEM法表征共聚物的结构，并在pH7.4的PBS液和不同胆固醇饱和指数的模拟胆汁中进行溶石效果的研究，探讨在PBS液和不同CSI的模拟胆汁中结合物溶解胆固醇结石的效果和溶解动力学机制。

The catalytic performance of PhTMG was evaluated in the reaction for synthesis of diethylene glycol bis via carbon dioxide route and the highest yield of ADC was 95.3%.

考察了PhTMG对以二甘醇、氯丙烯和CO2为原料合成二甘醇双烯丙基碳酸酯反应的催化性能，ADC的最高收率为95.3%。

This novel reagent was treated with LDA to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides and epoxides, followed by stereospecific selenoxide syn-elimination to give olefins and allylic alcohols respectively.

它与LDA反应形成α—硒基稳定的碳负离子，再与卤代烃或环氧化合物发生α—烷基化反应，烷基化后的树脂可以在30%的双氧水中进行氧化-消除，以良好产率和较高纯度合成了取代烯烃或烯丙基醇。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新