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One of them can efficient catalysed the alkene in the absence of dear additives by introducing an imidazole in the salen ligand.

其中分子内含咪唑的手性吡咯烷Mn催化剂成功实现了不加昂贵添加剂的情况下高效催化取代色环氧化反应。

Chooses picture which you likes, if you need it are the oil paintingor the splendid alkene picture, may write plainly in the order form.

选择你喜欢的图片,如果你需要它是油画或炳画,可以在定单中写明。

Results showed that using aluminum trichloride combined catalyst under the conditions of a catalyst dosage of 5%, a benzene/olefin molar ratio of 8, a reaction temperature of 60℃ and a reaction time of 6 h, the yield of alky-benzene reached 19.6% and the quality of the obtained alkylate was significantly improved as compared with coker gas oil.

结果表明,采用三氯化铝复合催化剂,在催化剂质量分数为5%、反应温度60℃、苯摩尔比为8、反应时间6 h的条件下,烷基苯收率达到19.6%,烷基化油的质量明显优于焦化柴油。

Changes to FCC gasoline cutpoints and the possibility of blending by dilution (adding components such as ethers or alkylate) can be used to meet a sulfur or olefin specification for individual gasoline grades if a preliminary blend is already close to the specification and the refinery desires to increase total gasoline production.

对FCC 汽油cutpoints 的变动和混和的可能性由稀释(增加组分譬如以太或烷基化)可能使用符合各自的汽油等级的硫磺或烃规格如果初步混合已经是紧挨规格和精炼厂渴望增加总汽油生产。

When the mol quantity of Cu2+ dissolved was 5% of those of AlCl3 in ionic liquids, alkylation results from ionic liquids is comparable with those obtained with concentrated sulfur acid: the yield of alkylate reaching 178% of the volume of butene inputted, the selectivity of C8 reaching 75% and the octane number of alkylate reaching 92.2.

溶入Cu2+和Cu+后,离子液体的催化性能有显著的改善,当Cu2+的摩尔加入量为三氯化铝的5%时,烷基化油收率达到丁体积的178%,对C8的选择性为75%,烷基化油辛烷值为92.2,并且离子液体可以重复使用。

In this study enamine was used as the reactive intermediate for alkylation of cyclohexanone alkylate,to provide a new route to synthesize the perfume-α-tert-butylcyclohexanone after overcoming many disadvantages of the traditional technical route,such as the complicated of reaction steps,the expensive reagents adopted,the high demand for the equipment used,and the low yield of product.

利用胺作为环己酮烷基化的活性中间体,为香料α-叔丁基环己酮的合成提供了一条新的途径,克服了传统工艺反应步骤烦琐,试剂昂贵,设备要求较高,产率不高等缺点,易于工业化生产。

The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-丙基苯基苄基醚产生苄正离子,苄正离子亲电进攻3,4,5-三甲氧基甲苯从而进行傅氏烷基化反应的。

Linear alkyl benzenes and linear alkyl dimethyl benzenes, prepared by the alkylate reaction of linear alpha olefin with benzene or dimethyl benzene which were sulfonated by chlorosulfonic acid and then neutralized to produce linear alkyl benzene sulfonates and linear alkyl dimethyl benzene sulfonates.

本文以一定链长的直链α-烃分别与苯和混合二甲苯为原料制备了直链烷基苯和烷基二甲苯,经氯磺酸磺化,中和可得到具有一定链长的直链烷基苯磺酸盐和直链烷基二甲苯磺酸盐。

In addition, the effect of different olefins on alkylation reaction was also investigated.

另外,还考察了烃碳链长度对苯烷基化反应的影响。

These ligands were found to be very effective in construction of quaternary carbon centers by using asymmetric allylic alkylation.

这类配体在前手性亲核试剂的不对称丙基化构筑手性季碳中心的反应中,显示了较好的反应活性及对映选择性。

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