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The results show that the reactive characters of macro-kinetics are different from that of intrinsic kinetics under the same experimental conditions. The isobutene dimeric reaction follows 1.5 order reaction because of the effect of inner diffusion, and isooctane dimeric reaction follows zero order reaction.

结果表明,在相同的实验条件下,反应的宏观动力学行为与本征动力学行为有较大的不同,异丁的反应级数受内扩散影响由2级变为1.5级,异辛的反应级数则为0级。

A novel Ziegler-Natta type catalyst for the hydrogenation reaction of isooctene to isooctane was developed by investigated the effect of the solvent and the ratio of aluminium/nickel on the conversion,and the influence of process conditions on the hydrogenation reaction by Ziegler-Natta type catalyst was also studied.

探讨了在Ziegler-Natta型均相催化剂上进行异辛加氢反应时,催化剂中的溶剂和铝/镍质量比对反应转化率的影响,得到了优化的Ziegler-Natta型均相催化剂,并考察了工艺条件对异辛加氢反应的影响。

In particular, the present invention concerns a process and an apparatus for continuous polymerisation olefin monomers like ethylene and other monomers, wherein an olefin monomer is polymerised in slurry phase in an inert hydrocarbon diluent in at least one loop reactor.

本发明尤其涉及连续聚合烃单体如乙和其它单体的方法和设备,其中烃单体在至少一个回路反应器内惰性烃稀释剂中的浆料相内聚合。

In addition, 65% ee was obtained for 1, 3-dimethylprop-2-enyl acetate. Interestingly, the reactivities of these ligands are all very high.

对于1, 3-二苯基丙基醋酸酯的烷基化和胺化反应, ee 值最高分别为93%和98%,此外,在对1, 3-二甲基丙基醋酸酯的烷基化反应中 ee 值最高也可达65%。

On the basis of the above N-vinylaiton of amides,the Cu-catalyzed intramolecular C-S coupling of thiols was implemented for the first time with CuI (10 mol%) as the catalyst and K_3PO_4·3H_2O2 equiv.

在酰胺氮基化研究的基础上,我们进而开展了烷基硫醇分子内基化反应研究。

In this work, alpha-olefin (carbon number 14, 16, 18) were used as materials, the alpha-olefinsulfonates (AOS-h,AOS-14, AOS-16, AOS-18) were synthesized with applying gas SO_3 Film-Reactor,and its application properties in EOR were studied.

本文以直链α-烃为原料,采用气体三氧化硫膜式磺化合成了α-烃磺酸盐(AOS-h,AOS-14,AOS-16,AOS-18),并应用于三次采油工业中。

The catalyst for IB dimerization, reactive site, reactive mechanism and dynamics research date was reviewed in this paper and try to explain the mechanism of selectivity enhancing by adding Tertiary butyl alcohol during IB dimerization and provide reference for the study of dimerization afterwards.

本文对异丁二聚催化剂、反应活性位、机理及动力学研究成果进行了综述,试图解释在异丁二聚时,加入的叔丁醇对二聚反应选择性提高的作用机理,为今后二聚反应的研究提供参考。

Dibutyl maleate was prepared from maleic anhydrideand n- butyl alcohol in the presence of tungstophosphoric acid or molybdophosphoric acid .

用顺丁二酸酐和正丁醇为原料,分别以磷钨酸和磷钼酸为催化剂,合成了顺丁二酸二丁酯。

In this paper,the physical propertites and reactivity of allyl xy lob resin are introduced, and a new matrix resin— allyl xylok /BMI resin system is showed.The properties of this resin system and its fiber reinforced compression moloding materials.

文中论述了丙基新酚的物性和反应性,研究了丙基新酚/BMI树脂体系以及用它制成的玻璃纤维压塑料的性能,如反应性、力学性能、韧性、耐热性、耐湿热性和绝缘性能等。

A new train of thought of copolymerising modification of the boron phenolic resin was applied and a new resin contained allyl was synthesized through allyl phenol, phenol, boric acid and polyformaldehyde.

运用硼酚醛树脂共聚改性的新思路,利用丙基苯酚、苯酚、硼酸、多聚甲醛等合成出结构中含有丙基活性基团的可与其它含不饱和双键树脂发生共聚反应的新型硼酚醛树脂,表征了它们的物理性能和结构。

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