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Gold Scorpionates Capture Ethylene ― Transition metal-ethylene complexes, known for nearly 200 years, were first made famous by Zeise's salt, K[PtCl3(C2H4)] H2O, a once-mysterious complex in which an ethylene molecule binds side-on to the platinum atom.

金蝎合物俘获乙――人们早在1827就制备了过渡金属烃复合物,最近因蔡斯盐,K[PtCl3(C2H4)] H2O,一种烃分子缠绕铂原子曾经很神奇的复合物,而首次名满天下。

Treatments contained skim milk and 50 g fat from high–oleic acid safflower and canola oils (monounsaturated fatty acid; MUFA), MUFA + 3.5 g α-linolenic acid (ALA; MUFA + ALA) from high-ALA canola oil, or MUFA + 4.0 g both eicosapentaenoic acid and docosahexaenoic acid (DHA; MUFA + EPA/DHA) from sardine oil.

处理因素为:脱脂奶及50g脂肪(来源于含高油酸的草红花和芸苔油)(单不饱和脂肪酸,MUFA组), MUFA+3.5g γ-亚麻酸(来源于高γ-亚麻酸含量的芸苔油),MUFA+4.0g二十碳五酸和二十二碳六酸(MUFA+EPA/DHA组)。

Expert knowledge: deep sea fish oil to deep-sea salmon as raw material derived, is rich in OMEGA-3 (Omega -3) fatty acids, which is a kind of polyunsaturated fatty acids, including eicosapentaenoic acid, docosahexaenoic acid and linolenic acid, can effectively regulate blood lipids, promote health.

专家常识:深海鱼油以深海三文鱼为原料提炼而成,含丰富的OMEGA-3(奥米加-3)脂肪酸,它是一种多元不饱和脂肪酸,包括二十碳五酸、二十二碳六酸及亚麻酸,能有效调节血脂、促进健康。

The copolysiloxane PSII3A the raio of fed monomers (M1/M2)=1/9, M1 is 4-undecylen-

比较了异构反应速率和异构转换率,以聚硅氧烷共聚物PSII3A[侧基比(M1/M2)=1/9, M1是对十一酰基偶氮苯, M2是对十一酰氧对氧基苯酯]为最佳。

This paper reviews the recent progress in the studies on the aromaticity as well as the general syn the tic method of annulenes.

本文综述了近年来轮的合成及芳香性的研究进展,介绍了各种轮的一般合成方法。

Advances in Research on Plants Reactions under Phosphate Starvation;2. Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二基及类环戊二基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二基及类环戊二基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

Both Mg and Al has no bonding with perfect sheet due to negative binding energy at all symmetric positions, however, the introduction of a Stone-Wales defect increased the binding energy at all adsorption sites to negative values.

Mg和Al不能稳定吸附在完整的石墨片上,但是引入SW缺陷降低结合能,使其能够稳定吸附在石墨片上。

The photo-oxidation has been initiated by irradiation ofα-pinene/NOx mixture, and ozonolysis has been initiated by injection of ozone orα-pinene under dark condition.

光氧化实验在恒温(303K)、恒湿(40%RH)用黑光灯辐照α-蒎与NOx的混合物引发;臭氧氧化在黑光灯关闭的条件下通过注入臭氧或α-蒎引发,并以甲醇作为OH自由基清除剂。

To attaining longlived charge separated states, the new compounds 7 and 8 of C60-S-2-thioxo-1, 3-dithioles derivatives were synthesized by Diels-Alder cycloaddition reaction. The structures generated by AM1 were used as the initial configurations for the density functional optimization at the B3LYP/3-21G level for all carbon and sulfur clusters, and some geometry conformation indexes were obtained. We found that C60 has been half-packed by the curved 2-thioxo-1, 3-dithioles derivatives.

为了获得具有长寿命电荷分离态的[60]富勒-富硫衍生物有机功能分子,我们设计了用单键硫桥键联[60]富勒和硫酮衍生物的分子7和8,用半经验AM1方法得出最低能量的几何结构,在此基础上用密度泛函 B3LYP/3-21G方法,对其进行计算,得出电子相关的优化参数,预测其稳定性。

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