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Enynes with an aryl ring at the alkyne give 2,3,9,9a-tetrahydro-1H-cyclopentanaphthalenes by a 5-exo-dig cyclization followed by a Friedel-Crafts-type ring expansion.

带有芳环的1,6-二体和炔作用,并通过5-exo-dig路径环化,再紧接着Friedel-Crafts扩环,可以得到2,3,9,9a-四羟基-1H-环戊二并萘。6-endo-dig途径的环化在一些例子中作为副反应被观察到,尽管,这在一些具体的反应中,是作为主反应出现的。

These results show that the ring expansion of cyclopropylsilylene C3H5SiH to silacyclobutene is easy to occur with a barrier of 113.4kJ/mol, while the 1,2-H shift is not competitive to the ring expansion for its much higher barrier.

结果表明,环丙基硅经过113.4kJ/mol的势垒扩环重排为硅杂环丁为自发反应;而其1,2-氢迁移重排反应热垒为190.0kJ/mol,是非自发反应,难于进行,不能与扩环重排相竞争。

Allyl starch was prepared by etherification pretreatment of introducing allyl groups onto starch, and then AS-g-PMA was synthesized through graft copolymerization between allyl starch and methyl acrylate. The adhesion to fibers, sizing film and sizing performance of the blended size composed of AS-g-PMA and PVA-1799 were investigated. And the possibility by using AS-g-PMA to substitute PVA component was studied by contrast experiments.

摘〓要:通过丙基化变性对淀粉进行预处理制取丙基淀粉,再与丙酸甲酯进行接枝共聚合成接枝淀粉,文章探索了这种接枝淀粉与PVA1799混合浆的黏附、浆膜及浆纱性能,与目标配方进行比较,揭示出AS-g-PMA取代PVA的可能性。

Chemical modification is one of the most important research fields in the fullerene chemistry.

在富勒化学中,化学修饰一直是富勒研究的主要领域之一。

In the second part, the preparation and the properties of self-assembled films of Fullerene and Fullerene derivatives have been studied.

第二部分,主要进行了几例富勒与富勒衍生物的自组装薄膜的研究。

We studied the nonlinear optical properties of fullerene and its arylatedderivative.They both exhibit weak self-defocusing and strong RSA.

研究了芳化富勒及富勒的非线性光学性质,它们都具有弱的非线性自散焦和较强的反饱和吸收。

AIM A new process to prepare the glycerides of eicosapentaenoic acid and docosahexenoic acid from purified ethyl esters of EPA and DHA.

目的:用高纯度的二十碳五酸乙酯和二十二碳六酸乙酯制备EPA、DHA甘油酯的工艺。

Plant polyprenols, which have similar structure and biological activity to dolichols in human body, are lipids of polymer with isoprenyl units. However, dolichols are key carriers in biosynthesis process of glycosyl derivatives with protein.

植物聚戊醇是一类异戊基结构聚合体的类脂化合物,与人体内多萜醇具有相似的结构特征和生理活性,而多萜醇是糖基与蛋白质生物合成的关键载体。

Result Among 6 reagents, Dimethomorph, Huishuangte, Gold-ridomil and Miejuncheng all had good control effect on grape downy mildew. In the area where downy mildew was serious, Huishuangte had best disease control effect. In the area where disease was not so severe, Dimethomorph and Gold-ridomil were in the optimal control effect and the next one was Miejuncheng.

结果]6种药剂中,酰吗琳、灰霜特、金雷多米尔和灭菌成对葡萄霜霉病均有较好的防效,其中在霜霉病发生严重的地区,灰霜特防病效果最好,在发生较轻的地区,酰玛琳和金雷多米尔防效最好,其次为灭菌成。

Head blight not only causes the severe grain yield loss, but also causes the harvested grain contaminated with several mycotoxins, such as deoxynivalenol and zearalenone. The consumption of food product made from grains contaminated with these toxins is a potential problem for human and farm animals, which is known to cause carcinogenic, genotoxic acute or chronic diseases or to directly target the kidney, liver or immune system, and has caused great concern of food safety.

赤霉菌引起小麦的穗腐,不仅使小麦籽粒产量降低、品质变劣,而且病麦粒中存留有病菌产生的真菌毒素,如脱氧雪腐镰刀菌醇(Deoxynivalenol,DON)和玉米赤霉酮(Zearalenone,ZEN),食用污染毒素的病麦及其制成品后会引起人畜中毒,还有致癌、致畸和诱变的作用。

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