烯

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1，3-偶极体，可以与一系列芳基或烷基取代的腈反应，高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物；也可以与富电子的链状和环状的烯基醚反应，以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物；而与2，5-二甲基呋喃的反应，由于甲基的位阻作用，只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

Synthesis of perfluorous nonene (C9F18) by oligomerization of hexafluoropropylene (C3F6) was studied.

研究了六氟丙烯(C3F6)齐聚合成全氟壬烯(C9F18)的工艺。

Benzene perfluorous nonene ether was prepared by the reaction of perfluo-rous nonene (C9F18) and phenol,and the molecular structure of which was identified by IR and NMR spectra.

以全氟壬烯、苯酚和氯磺酸为主要原料，经醚化、磺化和中和反应制备对全氟壬烯氧基苯磺酸表面活性剂，用红外光谱和19FNMR，1HNMR对分子结构进行了表征。

Alkylphenol ethoxylates are nonionic surfactants and extensively used in industry. Manufacturers in Taiwan used to import nonene to produce nonylphenol and nonylphenol ethoxylates. They used to import octylphenol directly because it isn't easy to get octenes.

烷基酚聚乙基醚醇是工业上用途非常广泛的非离子性界面活性剂，国内目前有进口壬烯生产壬基酚及壬基酚聚乙基醚醇，而由於受限於辛烯原料取得不易，辛基酚都是直接进口。

Results9-Octadecenoic acid,9-Hexadecenoic acid,Octadecanoic acid and so on were the chief components.

结果主要组分为9-十八碳烯酸、9-十六碳烯酸、十八烷酸等。

Results9-Octadecenoic acid,9-Hexadecenoic acid,Octadecanoic acid and so on were the chief components.

结果主要组分 9-十八碳烯酸、9-十六碳烯酸、十八烷酸等。

In the 29 Aroma material studied, the content of the material having important effect such as norambreinolide, octadecanoic lactone(1), octadecanoic lactone(2), octadecanoic, 8,15-labdanum-1-ol,8,12-external oxidative labdanum-14-en-2-ol(1), 8,12-external oxidative labdanum-14-en-2-ol(2), 8,13-external oxidative labdanum-14-en-13-one(1), 8,13-external oxidative labdanum-14-en-13-one(2) Dihydroactinidiolide, solanone, norsolanone have Significant increasing trend in the aging, the peak of the content of material appear in the 18~21 months in the aging process.

在所测定的29种香气物质中，对香料烟特征香气有重要影响的香味物质如降龙涎香内酯、硬尾内酯2种异构体、硬尾醛、8，15－赖百当醇、2种8，13外氧赖百当－14－烯－13醇异构体和2种8，13外氧赖百当－14－烯－13－酮异构体，二氢猕猴桃内酯、茄酮和降茄二酮等成分在陈化过程中有明显的增加，总的香气物质含量变化的高峰期出现在陈化18~21个月。

Octylene was synthesized via tetramerization of ethylene at the presence of a catalyst system consisted of chromium acaet as primary catalyst, methylaluminoxane as cocatalyst, bis amine as ligand under high pressure. The effects of different PNP ligands on catalyst activity and selectivity to 1-octene were investigated.

在乙酰丙酮铬、甲基铝氧烷、配体三元催化体系中，以乙烯为原料在高压下齐聚生成1-辛烯，主要考察N原子上取代基不同的PNP配体对催化剂活性及1-辛烯选择性的影响。

Conditions to prepare the NHS-esters of all olefine acids" and polymer-NHS esters were studied. And these products" basic physical and chemical properties were also tested.

研究了合成烯酸NHS酯及聚合物的NHS酯的合成条件，测试了烯酸NHS酯及聚合物NHS酯的特性。

The above view of isomerization between the structure of olefine alcohol and olefine ketone can succeed to explain that the structure and properties of C〓 Fullerols change with the pH value of its solution.

作者提出的上述富勒醇的结构以及烯醇与烯酮的互变异构的观点能成功地解释C〓、C〓富勒醇的结构随其溶液pH值的变化而发生变化的现象。

By using competitive adsorption of activated carbom to remove unfavorable influence of carbon in carbonaceous gold concentrate on leaching process, the leaching rate of gold concentrate can be improved to 88% as compared with 10%by direct cyanidation.

本文论述了利用活性炭竞争吸附作用，消除含炭金精矿中炭在浸出过程中的影响，使金精矿的浸出率可由直接氰化的10％提高到88％。

The only thing you're ever gonna be king of is King of the Stupids!

你只配做傻瓜的国王！