烯

In addition, a benzene, toluene (0.32%), was also detected in 80% ripening fruit. In 90% ripening fruit were detected 27 kinds of aroma components belonging to 2 categories. Among the components, 17 were esters, and 10 alkenes. Of the 17 esters, methyl octanoate is the highest (21.00%), followed by ethyl hexanoate (17.64%), methyl hexanoate (14.34%). Of the 10 alkenes cis-β-ocimene is the highest (1.00%), followed by à-copaene (0.81%) and trans-ocimene (0.48%).

在9成熟果实中检测到2类共27种香气成分，分别是酯类17种和烯类10种；在酯类中，相对含量最高的是辛酸甲酯(25.27%)，其次是辛酸乙酯(21.00%)、己酸乙酯(17.64%)、己酸甲酯(14.34%)；在烯类中相对含量较高的有β-顺式－罗勒烯(1.00%)、à-蒎烯(0.81%)和反式－罗勒烯(0.48%)。

From the influnce of pH change in water on the copolymerization, the copolymerization mechanism was provided. The copolymerization mechanism is that there is hydrogen bond, which can enhance the copolymerization, between acrylic acid and crotonaldehyde at low pH and there is"Charge Transfer Complex", which gives the more crotonaldehyde in P (acrylic acid-crotonaldehyde), between acrylic acid and crotonaldehyde at high pH.

根据共聚合反应介质pH值变化对丙烯酸-丁烯醛共聚合反应的影响，提出了丙烯酸-丁烯醛共聚合反应机理，即在低pH值时，丙烯酸、丁烯醛之间可形成氢键，从而使共聚合体系具有较高的聚合反应速率和转化率；在较高pH值时，丙烯酸、丁烯醛之间则有电荷转移络合物形成，从而使共聚物中含有更多的丁烯醛链段。

From comparative research of synchronous and asynchronous reaction of dehydrogenation and cracking of dipentene,it is shown that farraginous extent of by-products from synchronous reaction is relatively high.

双戊烯脱氢裂解的同步反应和异步反应对比研究显示，双戊烯脱氢裂解的同步反应产物比较混杂，反应产物中甲苯的相对含量仅为24.03%，双戊烯相对于甲苯的料耗比为5.34，甲苯的得率为30.79%，中间产物对伞花烃的得率为2.49%；双戊烯脱氢裂解的异步反应产物混杂程度相对较低，反应产物中甲苯的相对含量为40.74%，对伞花烃的相对含量为18.31%，双戊烯相对于甲苯的料耗比为3.33，甲苯的得率为49.26%，中间产物对伞花烃的得率为16.92%。

The results showed that the unsaturated fatty acid content of pecan kernel oil was 89 0%,and 13 kinds of unknown components such as nonadecaol,8 hexyl pentadecane,10 methyl eicosane,11,14 eicosadienoic acid,1 bromo 8 heptadecyne,9 hexyl heptadecane,tetracosane,13 docosenoic acid,1 bromo 7 nonadecyne,15 tetracosenoic acid,hexacosanoic acid,7 hexyl ei...

研究结果表明：山核桃仁油中的不饱和脂肪酸 w =89 0 %，未知成分是十九醇、8 己基十五烷、10 甲基二十烷、11，14 二十碳二烯酸、1溴 8 十七炔、9 己基十七烷、二十四烷、13 二十二碳烯酸、1 溴代 7 十九炔、15 二十四碳烯酸、二十六酸、7 己基二十烷、二十七烷共 13种，其中13 二十二碳烯酸、15 二十四碳烯酸、十九醇等具有较强的生理活性和药用价值

Chapter 2 has analysized the conversly synthetic means of solanesol and designed novelly synthetic routes of solanesol and key intermediate Chapter 3 has summarized the preparation of trans-3-methyl-4-hydroxy (bromo-2-butenyl oxy methyl benzene In chapter 4 ,a novel technology of important intermediate(all trans-8-bromo geranyl acetate),which is suitable for industrial procedure , was found .meanwhile,an another new way has been invented ,of which the key intermediate (all trans-8-hydroxy geranyl acetate) has been produced.

第二部分分析了茄尼醇的逆合成方法，设计了一条适合于合成茄尼醇的合成路线及其重要中间体的合成路线。第三部分研究了重要中间体[Trans-3-甲基-4-羟基-2-丁烯基乙酰基(苄基，2，3-二氢吡喃基)醚]的合成新方法，找到了一条适合于工业化生产的制备反式-3-甲基-4-羟基-2-丁烯基苄基醚的新方法。第四部分研究了重要中间体[-3，7-二甲基-8-羟基-2，6-辛二烯-1-醇乙酸酯、-3，7-二甲基-8-溴-2，6-辛二烯-1-醇乙酸酯]的合成新方法，找到了一条适合于工业化生产的制备它们的新方法；同时研究了一条制备-3，7-二甲基-8-羟基-2，6-辛二烯-1-醇乙酸酯的另一新方法。

SM6 and SM7 of uncrystal were analyzed through GC-MS, the results showedthat SM6 main contained unsaturated fatty aldehyde with fragrance, i.e.-2,4-decadienal(58%), tetradecanoic acid (55.78%), 2-decenal(50%), Phthalic acid isobutylundecyl ester(47%), 2, 4-Decadienal(41%), 2-Undecenal (31%), 2-Methyl-Z,Z-3, 13-octadecadi-enol(18.84%), and SM7 contained saturation alkanes, i.e. 1, 2-Benzenedicarboxylic acid, butyl cyclohexyl ester(23.90%), Triacontane(22.63%),Nonacosane(21.04%), Heptadecane(18.84%), Octacosane(13.58%). Toxicological experiments were done to insure the pigment safety.

并对紫红丝膜菌色素非晶体部分的黄色油状物SM6和紫色粉末物SM7作了GC-MS分析，结果显示SM6中主要为具有香气成分的不饱和脂肪醛，其中含量较高的依次为：-2，4-癸二烯醛(58％)、十四烷酸(55.78％)、2-癸烯醛(50％)、邻苯二甲酸异丁基十一烷酯(47％)、2，4-癸二烯(41％)、2-十一碳烯醛(31％)、2-甲基-Z，Z-3，13-十八碳二烯酸(18.45％)等；SM7中主要为饱和直链烷烃，其中含量较高的依次为：1，2-苯二羧酸丁基环己酯(23.90％)、三十烷(22.63％)、二十九烷(21.04％)、十七烷(18.84％)、二十八烷(13.58％)。

The kinetic behaviors of ethylene homo- olymerization and ethylene / l-hexene co-polymerization , catalyzed by the metallocene catalyst PS-DVB-MC in an 0.5 L stainless steel reactor , were studied. The effects of polymerization conditions on ethylene polymerization , such as concentration of catalyst , temperature of polymerization , pressure of ethylene , molar ratio of AI / Z r , etc ., were also investigated . Some leading results were as follows : the activity of the catalyst PS–DVB- MC for ethylene homo-polymerization was high ( 1.053 x 107 gPE / mol Zr·h ), but the molar ratio of AI / Zr was low ( 350:1 ); the catalytic ability for ethyleneα-olefin ( such as l hexene etc .) co-olymerization was great , and the corresponding activity come up to a maximum of 1.753 x 107 gPE / mol Zr·h while concenlration of l-hexene was 0.080 mol / L ; the molecular weight of polyethylene was about 180,000 , meanwhile the molecular weight distribution was narrow ( 2.19 ); the bulk density of polyethylene and ethylene / l-hexene co -polymer were 0.25 and 0.34 respectively .

采用0.5L高压不锈钢反应釜，对催化剂PS–DVB-MC催化乙烯均聚和乙烯/ l-己烯共聚合的动力学行为进行了研究，详细考察了催化剂浓度、反应温度、压力、Al/ Zr比、1-己烯浓度等因素对乙烯聚合反应的影响，得到如下主要结论：催化剂PS-DVB-MC具有催化乙烯均聚的高活性(1.053×107g PE / mo1 zr.hr)，低Al / Zr比( 350：1 )；具有良好的催化乙烯与α-烯烃(如1-己烯等)共聚的能力，在1-己烯浓度为0.080 mol / L时，催化活性达到最大(1.783×107 g PE / molZr.hr)；乙烯均聚产物的分子量在18万左右，分子量分布窄( 2.19 )。

Sugar water choosed degree have no significant change. It means that Iridoids composition of Valeriana jatamansi Jones has central inhibitory action.2.2 Effection of Iridoids composition of Valeriana jatamansi Jones on weight and food intake of IBS rats induced by chronic stressAnimals were randomly divided into 7 groups:normal group,model group, OSD group,FXT group and Iridoids composition of Valeriana jatamansi Jones groups in quantiy of 24.92mg/kg,12.46mg/kg,6.23mg/kg.

蜘蛛香环烯醚萜可以减缓正常小鼠的胃肠运动和利血平化小鼠的胃肠功能亢进，降低慢性应激所致IBS模型大鼠的内脏敏感性，显著减少了IBS模型大鼠的排便数量，从而改善腹泻型IBS的临床症状。2蜘蛛香环烯醚萜对神经系统功能的影响目的：探讨蜘蛛香环烯醚萜对精神活动的影响2.1蜘蛛香环烯醚萜对慢性应激所致IBS大鼠精神活动的影响方法：动物随机分为对照组、模型组、昂丹司琼组、氟西汀组、蜘蛛香环烯醚萜24.92mg/kg、12.46mg/kg、6.23mg/kg组，除对照组外，其余各组进行慢性应激实验。

It means that Iridoids composition of Valeriana jatamansi Jones has central inhibitory action.2.2 Effection of Iridoids composition of Valeriana jatamansi Jones on weight and food intake of IBS rats induced by chronic stressAnimals were randomly divided into 7 groups:normal group,model group, OSD group,FXT group and Iridoids composition of Valeriana jatamansi Jones groups in quantiy of 24.92mg/kg,12.46mg/kg,6.23mg/kg.

蜘蛛香环烯醚萜可以减缓正常小鼠的胃肠运动和利血平化小鼠的胃肠功能亢进，降低慢性应激所致IBS模型大鼠的内脏敏感性，显著减少了IBS模型大鼠的排便数量，从而改善腹泻型IBS的临床症状。2蜘蛛香环烯醚萜对神经系统功能的影响目的：探讨蜘蛛香环烯醚萜对精神活动的影响2.1蜘蛛香环烯醚萜对慢性应激所致IBS大鼠精神活动的影响方法：动物随机分为对照组、模型组、昂丹司琼组、氟西汀组、蜘蛛香环烯醚萜24.92mg/kg、12.46mg/kg、6.23mg/kg组，除对照组外，其余各组进行慢性应激实验。

It may means that Iridoids composition of Valeriana jatamansi Jones doesn\'t regulate the TPH1 transcription expression.3.4 Effection of Iridoids composition of Valeriana jatamansi Jones on SP and VIP of IBS rats induced by chronic stressMethods:Animals were randomly divided into7 groups:normal group,model group, OSD group,FXT group and Iridoids composition of Valeriana jatamansi Jones groups in quantiy of 24.92mg/kg,12.46mg/kg,6.23mg/kg.

造模后，中枢5-HT呈现降低趋势，这可能是导致动物出现活动能力下降和兴趣缺失的原因之一，蜘蛛香环烯醚萜可以增加下丘脑、海马和杏仁核中5-HT含量，推断蜘蛛香环烯醚萜可通过干预中枢的5-HT通路来改善IBS精神症状。3.2蜘蛛香环烯醚萜对胃肠激素的影响目的：探讨蜘蛛香环烯醚萜对慢性应激所致IBS大鼠SP和VIP的影响方法：动物随机分为对照组、模型组、昂丹司琼组、氟西汀组、蜘蛛香环烯醚萜24.92mg/kg、12.46mg/kg、6.23mg/kg组。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新