烯

A plausible process of this reaction is as following: Aldehyde was in equilibrium with the enol form, aldehyde reacted with aniline catalyzed by 2,2,2-trichloroacetic acid to afford imine, the generated imine immediately reacted with enol to form intermediate via intramolecular cyclization.

我们发现一分子芳基叠氮和一分子三苯基磷反应生成一分子磷亚胺，后者与由两分子取代的苯氧乙酰氯原位生成的烯酮反应生成4-亚烷基-β-烷基-内酰胺，其串联过程涉及烯酮亚胺的形成及其与烯酮的[2+2]的环加成反应。

As an essential component of the Baylis-Hillman reaction, activated alkenes are a kind of very important building blocks in organic synthesis, and have been applied in various fields.

作为Baylis-Hillman反应的重要组成部分，烯烃特别是具有一定活性的烯烃，由于它们本身的结构特征，具有与一般烯烃不同的独特的性质，是一类非常重要的有机合成中间体。

As an essential component of the Baylis-Hillman, alkenes especially activated alkenes are a kind of very important building blocks in organic synthesis, and have been applied in various fields.

作为Baylis-Hillman反应的重要组成部分，烯烃特别是具有一定活性的烯类化合物，由于它们本身的结构特征，具有与一般烯烃不同的独特的性质，是非常重要的有机合成中间体。

The content of conjugated dienes in petroleum products is determined by ultraviolet spectrophotometry.

在化学反应－气相色谱法联合测定含烯汽油中共轭二烯烃质量分数的基础上，建立了用紫外分光光度法测定油品中的共轭二烯烃的含量。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失，采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

With 54# half-refined paraffin as raw material,the technology of the second injecting steam of ethane cracking is used for reference in the paraffin cracking process which avoides the coke produced in cracking furnace.

采用优质的54#半精炼石蜡，将乙烯裂解二次注汽技术融合在石蜡裂解技术中，避免了裂解炉结焦；考察了单程裂解、炉前甩残蜡循环裂解、炉后甩残蜡循环裂解在相同的工艺条件下的产品质量、产品收率及存在的问题；验证了新的炉后甩残蜡循环裂解是较好的工艺路线，在较高的水蜡比15%，高温600℃、低烃分压和短停留时间(2s左右)条件下，能生产出高质量的α-烯烃产品(总烯烃质量分数在97%以上，α-烯烃含量为88%)。

With this aim, two different haptens mono- O -3-carboxypropyl- diethylstilbestrol and mono- O -carboxymethyldiethylstilbestrol with carboxylic group that preserve the molecular structure character of diethylstilbestrol were synthesized. The haptens were conjugated with the carrier proteins bovine serum albumin by mixed-anhydride method for immunogen and conjugated with ovalbumin by active ester method for coating antigen.

首先，两种保留己烯雌酚特征结构并具有活性基团的半抗原正丁酸己烯雌酚单醚、乙酸己烯雌酚单醚被合成；然后采用混合酸酐法将半抗原与BSA偶联制备成免疫原，采用活性酯法将办抗原与OVA偶联制备了包被原。

From the potential energy profile, it can be predicted that, the dominant channel of this reaction consists of three steps: the two reactants first form a three-membered ring intermediate (INT1) through a barrier-free exothermic reaction of 19.2 kJ/mol; three-membered ring intermediate (INT1) isomerizes to a four-membered ring silylene(P2) via the transition state (TS2) with an energy barrier of 22.8 kJ/mol; four-membered ring silylene(P2) further reacts with ethene(R2) to form a silicic bis-heterocyclic compound (P3), which is also a barrier-free exothermic reaction of 132.2 kJ/mol.

用CCSD//MP2/6-31G*方法研究了单重态二甲基亚烷基硅烯与乙烯生成硅杂双环化合物环加成反应的机理，根据该反应的势能面可以预言，该反应的主反应通道有三步组成：第一步是两反应物（R1， R2）首先生成了一三元环中间体（INT1），它是一无势垒的放热反应，放出的能量为19.2 kJ/mol；第二步是三元环中间体(INT1)经过渡态TS2异构化为了四元环硅烯（P2），其势垒为22.8 kJ/mol；第三步是四元环硅烯（P2）进一步与乙烯(R2)反应生成了硅杂双环化合物（P3），该反应也是一无势垒的放热反应，放出的能量为132.2 kJ/mol。

Effects of microwave power, reaction time, reaction temperature, solvent etc. on reaction were studied by a single factor tests. The results show that maleic acid is more active than fumaric acid; the introduction of methyl group on the double bond can weak the reactivity of the Michael addition reaction; the ester base is more propitious to complete the Michael addition reaction than the nitrile base.

为研究微波下迈克尔反应的规律，本文采用单模聚焦微波有机合成仪，通过对顺丁烯二酸、反丁烯二酸和氨水合成DL-天冬氨酸、顺式3-甲基丁烯二酸和氨水合成3-甲基天冬氨酸、丙烯酸甲酯和氨水合成β-丙氨酸、丙烯腈和氨水合成β-氨基丙腈等五个反应对迈克尔加成反应进行了研究。

The study of natural fullerenes is a new area of across fullerene science and geological science. So far natural fullerenes have been found in shungite, fulgurite, carbonaceous conglomerates in impact crater, E/K boundary carbonrich clay rock layer, T/P boundary layer, dinosaur eggshell, coal, heavy crude oil, solid bitumen and socalled seminatural fullerenes in common soots, Chinese ink sticks, commercial char, et al., only with low concentrations.

天然富勒烯研究是富勒烯科学和地质科学相交叉的一个新兴研究领域，迄今为止已在桑加岩、闪电熔岩、陨石撞击坑中的含碳质角砾岩、古近系/白垩系地层界线的含碳粘土岩、三叠系/二叠系界线岩石、恐龙蛋壳、煤、重质油、固体沥青以及半天然的烟灰、木炭、书墨等物质中检测到富勒烯的存在，但含量很低。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。