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Generally, these compounds are derived from accessible α–oxoketen dithioacetals and the common methods of preparation involve regioselective sodium borohydride 1,2-reduce of α–oxoketen dithioacetals, 1,2-nucleophilic addition of organomatals such as organomagnesium, organolithium, Reformatsky regent to α–oxoketen dithioacetals, Baylis-Hillman reaction between polarized ketene dithioacetals and aldehydes.

主要方法包括:使用硼氢化钠1,2-选择性还原α-羰基二硫缩酮;利用有机金属化合物(如有机镁试剂,有机锂试剂,Reformatsky试剂等)对α-羰基二硫缩酮进行1,2-亲核加成;通过α-羰基二硫缩酮与芳醛进行Baylis-Hillman反应等获得。

That 1,4-addition reactions of Grignard agent made from 1-bromo-3-triphenylmethoxyl-1-octene and organozinc agent made from 1-iodo-3-trimethysiloxy-1-octene with 2-(6-methoxylcarbonylhexyl)-4-(2- tetrahydro-pyranyloxy)-2-cyclopentenone both gave prostaglandin 〓 methyl ester statethat prostaglandin E compounds can be prepared by 1,4-addition reaction oforganozinc agent.

最后,研究了溴化-3-三苯甲氧基-1-辛基镁和碘化-3-三甲硅氧基-1-辛基锌与2-(6-甲氧羰己基)-4-(2-四氢吡喃氧基)-2-环戊酮通过1,4-加成反应合成〓甲酯的方法,结果表明,用有机锌试剂通过1,4-加成反应来合成PGE类化合物是可行的。

To obtain a flocculant which could effectively remove dyes from dyeing wastewater , the amphoteric polymer was prepared by copolymerization of acrylamide, acrylic acid, cationic monomer and dmethyldiallylammonium chloride or acryloyl oxyethyl trimethyl ammonium chloride.

为制备一种对染色废水有显著脱色效果的絮凝剂,采用溶液聚合法,将两种阳离子单体二甲基二丙基氯化铵和丙酰氧乙基三甲基氯化铵分别与丙酰胺,丙酸共聚,合成了两性聚合物。

The C_(60)-fused tetrahydrofuran derivatives are excellent synthons for further functionalization.While treated with different equiv,of BF_3·OEt_2 at various temperature,several novel functionized fullerene derivatives have been successfully synthesized.2.1,4-Fullerenols C_(60)ArOH were synthesized via the reaction of[60]fullerene with 4-substituted phenylhydrazine hydrochlorides and sodium nitrite under moisture and aerobic conditions.

这种四氢呋喃环合富勒衍生物作为一个合成中间体又可发生进一步的衍生化反应,其与不同当量BF_3·OEt_2在不同温度条件下可以得到二氢呋喃环合富勒衍生物、三元环合富勒衍生物等。2。

In addition, two water-solublephosphonic acid derivatives of C〓 and two diadducts of phosphonate derivative of C〓were also prepared. All the four compounds can be dissolved in DMSO, which is asolvent easy to be soluble in water. Their DMSO aqueous solution could haveprospective applications in the field of biomedicine.

研究了富勒膦酸酯衍生物的水解反应,首次合成了两个水溶性富勒膦酸衍生物,另外还合成了两个二加成的富勒膦酸酯衍生物,这四个衍生物均能很好地溶解在和水互溶的DMSO中,它们的DMSO水溶液可能在生物医学研究中可能会有很好的应用价值。

So piperylene petroleum resin was applied preferably in downstream products,and the products yield was increased by improving post treatment process.

介绍了国内外间戊二石油树脂合成技术的改进进展,主要体现在催化体系的改进及聚合单体和溶剂的改变,通过引入官能团及共混等方法改善间戊二石油树脂的色度、耐候性和相容性等性能,从而使间戊二石油树脂在下游产品中得到更好地应用;通过后处理精制工艺的改进,可提高产品的收率。

The C 5 Fraction derived from ethylene steamcracker contains some very useful components, isoprene, cyclopentadiene and piperylene .

来自裂解乙的 C5馏份含有非常有用的化工原料——异戊二、环戊二、戊间二

A novel fluorescent acrylamide monomer, N-(4-Benzooxazol-2-yl-phenyl)- acrylamide, was prepared from o-aminophenol, p-aminobenzoic acid and acryloyl chloride, with polyphosphoric acid as dehydrating agent and triethylamine as deacidification agent.

以邻氨基苯酚、对氨基苯甲酸和丙酰氯为原料,以多聚磷酸为脱水剂、三乙胺为脱酸剂,研制了一种新的荧光丙酰胺单体N-[4-(苯并噁唑-2-)苯基]丙酰胺。

The thesis consists of two main sections. The synthesis of 1,3,4-thiadiazoles,triazolotriazines and dioxapyrrolinopyrazoles containing chiral pyrazolyl moietyfrom D-glucose is described in the first part and the section one is about theDiels-Alder reactions between dienophile enaminones and diene 1,2,4-triazines,which provides a new methodology to construct the pyridine compounds. A total of37 new compounds were synthesized.

本论文包含两部分内容,一是以D-葡萄糖为原料合成含手性吡唑基的1,3,4-噁二唑、三唑并三嗪及二氧代吡咯啉并吡唑类化合物;二是将胺酮作为亲双体,与双体1,2,4-三嗪类化合物发生Diels-Alder反应,发现了一令人意外的构建吡啶类化合物的新方法。

Two new active esters of acrylic acids monomers, N-p-acryloxybenzoyloxy succini-mide and N-p-methacryloxybenzoyloxy succinimide have been synthesized and polymerized.ABOSu and MBOSu were prepared by coupling of p-acryloxybenzoic acid or p-methacryloxybenzoie acid with N-hydroxy succinimide in the presence of dicyclohexylcarbodimide.

新的丙酸活性酯,N-(对甲基丙酰氧苯甲酰氧基)丁二酰亚胺及N-丁二酰亚胺单体分别由对甲基丙酰氧基苯甲酸、对丙酰氧基苯甲酸与N-羟基丁二酰亚胺在环已基羰二亚胺存在下经偶联反应合成。

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。