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B3LYP/6-311++G** calculations were carried out to study the trimethylamine catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde.

采用密度泛函DFT-B3LYP方法在6-311++G**基组下计算研究了三甲胺催化的丙醛和甲醛的Baylis-Hillman反应的微观过程,获得了两种反应通道(分别对应于顺式-丙醛和反式-丙醛)的势能面。

When there were two kinds of active sites with different properties, isobutene were formed on one kind of active site, and then, spilled over to the other active sites, reacting to MAL, isobutene forming as the final product was restrained, and the oxygenates yield was increased.

当催化剂表面存在相邻的两种化学性质不同活性位时,异丁烷在一种活性位上生成异丁后,异丁可能在催化剂表面迁移到另一种活性位上,继续反应生成甲基丙醛或甲基丙酸,这抑制了异丁作为产物从反应器中流出,并提高含氧有机物收率。

The effect of impurities in DMDAAC monomer solution, such as NaCl, allyl chloride, allyl alcohol, allyl aldehyde, active carbon, low molecular polymer of DMDAAC, yellow residua, Fe~(3+), Fe~(2+), Cu~(2+), on the polymerization reactivity of preparing PDA with 30%cationicty was researched in this paper.

本文研究了二甲基二丙基氯化铵单体溶液中氯化钠、丙基氯、丙醇、丙醛、活性炭、低分子聚合物、黄色物质、Fe~(3+)、Fe~(2+)、Cu~(2+)等杂质对合成阳离子度为30%PDA的聚合反应性能的影响。

Many kinds of organofullerenes are not stable under reductive, oxidative or thermal conditions, where the functional addends are removed from the fullerene sphere and lead to the formation of pristine fullerenes.

在还原、氧化或加热条件下,许多富勒衍生物的加成基团会从富勒骨架上断开,得到富勒母体,是富勒环加成反应的逆反应。

The experimental results for the recovery of mixed and individual alkenes

方法的准确度实验表明,烃单体和混合烃的回收率均在96.5%-101%,说明该方法可用于汽油中烃含量的测定,同时应用该方法可对汽油中烃碳数、类型分布及含量有直观而清晰的认识,可为相关的催化剂及工艺研究提供丰富且准确的组成信息。

The result implied that C-H wagging out-of-plane vibration was most important in classifying alkenes are cycloalkenes or chain alkenes.

实验结果表明,烃的C-H面外弯曲振动是分类烃是环烃或链烃的最重要的片段光谱。

Results showed that terpene-catechol resin could be synthesized directly with the proposed method.The synthesized terpene-catechol resin could be separated from terpene resin and catechol on neutral alumina column with petroleum,absolute ethanol and 5% NaOH-ethanol solution as eluates.

采用柱层析法分离萜树脂和萜-邻苯二酚树脂,分别采用中性氧化铝和强碱性阴离子交换树脂作固定相,汽油、乙醇、NaOH-乙醇溶液作洗脱剂对萜树脂和萜-邻苯二酚树脂进行分离提纯。

Laba garlic, the formation of green pigment and red onion with a certain degree of similarity, diallyl sulfide and propylene oxide exists at the same time, Green took place, there is Propylene oxide sulfide, there is no oxidation of allyl sulfur objects when changes occur red.

腊八蒜绿色素的形成与洋葱红变具有一定的相似性,丙基与丙基硫氧化物同时存在时,就发生绿变,存在丙基硫氧化物,不存在丙基硫氧化物时,就发生红变。

The epoxidation can be performedwell when the concentration of quaternary ammoniumsaltand sodium tungstate is 0.06 mol/L and 0.03 mol/L, respectively.

结果表明,季铵盐和钨酸钠的浓度分别为0.06,0.03 mol/L时的催化效果最佳;α-和β-蒎的转化率随着H2O2与蒎的量比增大而增大,当H2O2与α-蒎和β-蒎的量比分别为2.0和1.8时,其转化率均可达到100%;较高的温度不利于环氧化反应的进行,因此,环氧化反应温度需控制在20℃以下。

For its special conditions of production, fullerene is hardly yielded through the process of the common earth environment and dynamic geology. The first presence of fullerene in Shungite, Russia in 1992 aroused the interest of studying natural fullerene.

富勒的形成条件特殊,普通的地球环境和地质过程不利于富勒的生成。1992年天然富勒在俄罗斯前寒武纪地层桑加岩中被发现,引起了人们对天然富勒研究的兴趣。

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