烯

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

The studies on production of pure cyclopentadiene by depolymerization-rectify of technical dicyclopentadiene and the influenceable factors about preparation of cyclopentene by liquid hydrogenation of cyclopentadiene at the Raney Nickel catalyst were carried out.

介绍了以工业级双环戊二烯为原料，经过解聚-精馏得到高纯度的环戊二烯，以骨架镍为催化剂，对环戊二烯液相加氢制备环戊烯的影响因素进行了研究。

The double bond in norbornene ring of TCPD was easily saturated at a low temperature, and an intermediate 12,13-dihydrotricyclopentadiene (12,13-DHTCPD) was formed. Higher temperature and hydrogen pressure were required for the saturation of remaining double bond in cyclopentene ring to generate a completely hydrogenated compound tetrahydrotricyclopentadiene.That is to say, the reaction occurred via the TCPD→12,13-DHTCPD→THTCPD route.

采用气质联用、红外光谱和核磁共振对加氢产物进行表征，发现在加氢反应中TCPD的降冰片烯双键首先被饱和，生成中间产物12，13-二氢三环戊二烯(12，13-DHTCPD)，残留的环戊烯双键需要在更高的温度和氢压下反应生成四氢三环戊二烯，即反应按照TCPD→12，13-DHTCPD→THTCPD的途径进行。

More than 75%of dodecene,decene,allylplenylether,phenylpropene(1.9×10－3mol) were completely hydrosilylated with 23.2 mg complex containing 4.9×10－6 mol platinum within 0.75 hour.

使用23.2 mg络合物(含4.9×10－6 mol Pt)为催化剂、分别使用1.9×10－3 mol 1－十二烯、癸烯、烯丙基苯基醚、苯丙烯进行硅氢加成反应，在0.75 h内产率超过75%。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

ConclusionThe main constituents in the essential oil from Dictamnus dasycarpus. are calarene( 27.17%),linalool(11.97%)transcaryophyllene(8.07%)βmaaliene (8.04%)gurjunene(6.04%).

结论白鲜皮挥发免费发布信息油主要化学成分是白菖油烯（27.17%）、芳脑醇（11.97%）、反石竹烯（8.07%）、β马榄烯（8.04%）、古芸烯（6.04%）等。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的，将反相微乳液法运用到其制备及改性的有关环节，通过反相微乳液聚合工艺，将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1，8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1，8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚，制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM，并研究其应用性能。

In the second part of the thesis, the pseudo kinetic constant method was used inmodeling vinyl/divinyl cross-linking atom transfer radical polymerization.

对于双烯／单烯的ATRP交联聚合反应，应用拟动力学常数的方法，推导出了双烯／单烯ATRP交联聚合的普适矩方程模型。

Three new fulvene polymeric compounds, namely 1[Ag (L3]CH2C12 , 2[Ag2(L25(H2O)(S03CF3)2]0.5C6H6 and 3 Mn(L42(C2H5OH)2 , were synthesized, respectively. Compounds 1 and 2 reported herein represent the organometallic polymers based on both Ag-N and Ag-C coordination interactions. In the solid state, compound 3 are bound together by strong intermolecular N H-O hydrogen bonding system into a supramolecular one-dimensional H-bonded chain.B.

一、富烯有机配体的合成及与金属离子的反应化学利用富烯负离子的芳酰化反应和Heck-偶联反应合成了富烯配体L1-L18，并合成了三个基于富烯配体的金属有机配位聚合物1[Ag(L3]·CH_2Cl_2、2[Ag_2(L25(H_2O)(SO_3CF_3)_2]·0.5C_6H_6和氢键驱动的超分子聚集体3Mn(L4_2(C_2H_5OH)_2。

It is speculated that this components feedback adjusting the this receptor\'s expression through receptor-binding with 5-HT3A receptor.3.3 Effection of Iridoids composition of Valeriana jatamansi Jones on THP1 mRNA expression of IBS rats induced by chronic stressMethods:Animals were randomly divided into 6 groups:normal group,model group, OSD group,FXT group,MSP group and Iridoids composition of Valeriana jatamansi Jones groups.

表明蜘蛛香环烯醚萜不影响色氨酸羟化酶的转录表达。3.1.3蜘蛛香环烯醚萜对5-HT受体的影响目的：探讨蜘蛛香环烯醚萜对慢性应激所致IBS大鼠5-HT3受体mRNA表达的影响方法：动物随机分为对照组、模型组、昂丹司琼组、氟西汀组、蜘蛛香环烯醚萜24.92mg/kg、12.46mg/kg、6.23mg/kg组，除对照组外，其余各组进行慢性应激实验。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。