烯

The key steps involved Friedel-Crafts reaction of o-cresol and the Wittig reaction for construction the skeleton of amine moiety,at the same time, using the synthesis of E,(7S)-7-methoxytetradec-4-enoic acid in chapter 2,and Johnson-Clainsen rearrangement as a key step for construction the fatty acid part,the corresponding acid was prepared in 23%and 50%overall yield,respectively.

随后将手性不饱和脂肪酸和氨片段进行酰胺化反应构筑了malyngamide M的基本骨架，再将Z-烯氯转化为E-烯氯完成了目标分子的全合成，高立体选择性地构筑了末端烯氯结构，为制备其它含有类似烯氯结构的malyngamides探索出行之有效的合成路线。

In order to eliminate disturbance of the feed stock, a feedforward controller was designed in the system.The designed soft sensor and control strategy were used in one selected olefin plant and the results were demonstrated and discussed in this paper.

丙烯浓度智能控制系统对塔釜丙烯指标进行实时控制，提高了塔釜丙烯浓度的控制平稳度，解决了塔釜丙烯浓度超标问题。

Hook, and it has a-pinene, a -cedrene, a-terpineol, B-caryophyllene oxide etc,they have strongly aromatic- muskiness-perfume. It was designed to toilet powder , puff cake and rouge in cosmetics and soap, it has been to append fantastic essence by directly application.

杉术精油主要成分是柏木醇，其含量占精油70％左右，其余还有α-蒎烯、柏木烯、揽香烯、α-松油醇、β-石竹烯等，有强有力的木香-麝香-龙诞香香气，主要用于爽身粉、粉饼、胭脂等脂粉类化妆品和皂类，还可适于配入幻想型香精中。

The results showed that the density of glandular trichome of mature leaves was lowest in lower leaves, the second in cutter leaves, and the highest was found in upper leaves.α-Duvatriene-4-ol,β-Duvatriene-4-ol,α-Duvatriene-4,6-diol and β-Duvatriene-4,6-diol were higher in cutter leaves than that in lower leaves by 282%, 240%, 48% and 80% respectively, while those in upper leaves were higher than that in lower leaves by 991%, 687%, 74% and 129%, respectively.

结果表明：不同部位成熟烟叶腺毛密度表现为下部＜中部＜上部；中部烟叶分泌物中的α-西柏三烯-4-醇、β-西柏三烯-4-醇、α-西柏三烯-4，6-二醇、β-西柏三烯-4，6-二醇的含量分别比下部烟叶增加了282%、240%、48%、80%，上部烟叶的上述四种分泌物的含量分别比下部烟叶增加了991%、687%、74%和129%。

Second, using DBU as the base for enolization of propargylic esters of unsaturated acids 18e-k, we developed a tandem Ireland-Claisen rearrangement /isomerization reactions. It has been shown that the reaction sequence affords triene molecules 42a-b and 43a-b in moderated to high yields. Interestingly, with allyl hexa-3,5-dienoates 18i-j as the substrate, the rearranged products underwent further aromatization to give uniquely substituted benzyl acids 44a-b.

其次，以含有活泼质子的烯酸炔丙酯18e-k为底物，在DBU为烯醇化碱、TMSCl为硅试剂的条件下，底物18e-h发生了Ireland-Claisen重排/异构化串联反应，得到完全共轭的三烯类化合物42a-b及43a-b；而以己二烯酸炔丙基酯18i-j为底物时，重排/异构化后的产物进一步发生电环化等反应最终得到芳构化产物——取代苯甲酸类化合物44a-b。

In addition, there were also some special aromatic substances such as 1-nonanol, hexanoic acid 2-hexenyl ester, propanoic acid 2-hexenyl ester, butanioc acid 3-hexenyl estertrans-2-hexenyl valerate, theaspirane, gerenylacetone, methyl benzoate and ethyl benzoate.

此外还含有一些少量的1-壬醇、己酸－2-己烯酯、丙酸－反－2-己烯酯、丁酸－反－3-己烯酯、戊酸－反－2-己烯酯、茶螺烷、香叶基丙酮、苯甲酸甲酯、苯甲酸乙酯和乙酸辛酯等。

The invention provides a method for homopolymerizing conjugated dialkene or co-polymerizing conjugated dialkene and monovinyl aromatic hydrocarbon. The method comprises the following steps: the conjugated dialkene is homopolymerized or the conjugated dialkene and the monvinyl aromatic hydrocarbon are co-polymerized randomly. The method is characterized in that at least one alkali metal alkoxide compound expressed by the formula is used as a structure regulator; in the formula, R is linear chain or branched chain alkylidene radical having 1 to 10 carbon atoms; M is alkali metal selected from Li, Na, K, Rb and Cs.

本发明提供了一种使共轭二烯烃均聚或者使共轭二烯烃与单乙烯基芳烃共聚的方法，包括在阴离子聚合条件下使共轭二烯烃进行均聚或者使共轭二烯烃与单乙烯基芳烃进行无规共聚，其特征在于采用至少一种式所示的碱金属醇盐化合物作为结构调节剂，其中R为具有1-10碳原子的直链或支链亚烷基；以及M为选自Li、Na、K、Rb和Cs的碱金属。

The allylation reactions of aldehydes with allyl bromide were carried out in 76%～93% yields with Nd-SnCl2-H2O under ultrasound irradiation at room temperature for 50～60 min.

在Nd-SnCl2-H2O体系中，用烯丙基溴超声诱发下进行了一系列芳香醛的烯丙基反应，室温反应50～60min得76%～93%烯丙基化产物；而不用超声波时同样体系中搅拌3～4h高烯丙基醇产率为30%～86%。

Maturation feeding weevils displayed higher anemotaxis responses to -β- pinene, myrene and limonene than those of sexually matured weevils; whereas - carene, which was detected only in volatiles of trunk phloem, elicted more olfactory respones of sexually matured weevils than of maturation feeding weevils.

在华山松枝梢挥发物中含量较高的-β-蒎烯、月桂烯和柠檬烯引起补充营养期华山松木蠹象较大的趋向反应；在华山松树干韧皮部挥发物中含量较高的3--蒈烯则引起交尾产卵期的华山松木蠹象较大的趋向反应。

The separation of tocopherols and tocotrienols by using the method of adsorption chromatography on silica and on silica impregnated with silver nitrate have been discussed. Satisfactory separation could be obtained with argentation column chromatography by eluting batchwise with n-hexane containing increasing amounts of diethyl ether. More than 90% of vitamin E amount in eluate was tocotrienols.

以乙醚正己烷混合溶液为淋洗液，探讨了硅胶柱层析和硝酸银硅胶柱层析分离生育三烯酚和生育酚的效果，结果表明：通过改变淋洗液中乙醚含量可以将生育酚和生育三烯酚大部分分离：硝酸银硅胶柱层析分离生育三烯酚和生育酚的效果明显高于硅胶柱层析，其洗脱液中生育三烯酚可占V〓总量的90％以上，最高达98.47％。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新