热化学的

Our process capability: Plates: FR4, High TG FR4, high CTI FR4, high frequency materials, halogen-free materials, aluminum and other low-rise Materials :2-20 layer of finished copper thickness :0.5-5 OZ finished thickness: 0.2 -6.0mm Minimum line width: 3mil Minimum line spacing: 3mil smallest shape tolerances:+/-0.1mm minimum finished diameter: 0.1mm maximum thickness aperture ratio: 12:1 wide minimum solder bridge: 4mil characters minimum line width: 5mil Minimum height of characters: 30mil Solder Mask Color: Green, black, blue, white, yellow, purple characters such as color: white, yellow, black and other surface processes: spray tin, lead-free HASL, Electroless gold plating Shuijin, OSP, chemical Shen tin, silver and other chemicals Shen Process: Goldfinger, blue gum, Blind-via/Buried-via, characteristic impedance control, rigid-flexible combination of reliability testing such as: Open / Short testing, impedance testing, solderability testing, thermal shock testing, metallographic analysis of micro-slice curvature Isoptera: 0.7% flame retardant Level: 94V-0

我们公司的制程能力：板材：FR4、高TG FR4、高CTI FR4、高频材料、无卤素材料、铝基材料等层数：2-20层成品铜厚：0.5-5 OZ成品板厚：0.2-6.0mm最小线宽：3mil最小线间距：3mil最小外形公差：+/-0.1mm最小成品孔径：0.1mm最大板厚孔径比：12：1最小阻焊桥宽：4mil最小字符线宽：5mil最小字符高度：30mil阻焊颜色：绿色、黑色、蓝色、白色、黄色、紫色等字符颜色：白色、黄色、黑色等表面工艺：喷锡，无铅喷锡、化学沉金、电镀水金、OSP、化学沉锡、化学沉银等其它工艺：金手指、蓝胶、盲埋孔、特性阻抗控制、刚柔结合等可靠性测试：开/短路测试、阻抗测试、可焊性测试、热冲击测试、金相微切片分析等翅曲度：≤0.7%阻燃等级：94V-0

At this stage, the solid pyrolyzed products of polysiloxane and polycarbosilane were amorphous silicon oxycarbide and nonstoichiometric silicon carbide containing excess carbon, respectively At higher temperature, structure of the amorphous pyrolyzed products started to rearrange and experienced a disorder →order transformation, even crystallized Cristobalite crystallized from SiO〓C〓, and β-SiC also crystallized from SiO〓C〓 provided carbon content of the starting polysiloxane was high enough, while β-SiC crystallized from SiC〓.

当热解温度达1000℃时，聚合物先驱体的无机化过程已基本完成，其陶瓷转化率值趋于稳定，此时聚硅氧烷的热解产物为非晶态的氧碳化硅，聚碳硅烷的热解产物则为含过量碳的非化学计量比的非晶态碳化硅；随着热解温度的升高，非晶态热解产物的结构逐步调整，发生无序→有序的相变，以至析晶。

SiC ceramic has been extensively applied in precision bearings, sealing element, steam-turbine rotor, burner nozzle, heat interchanger parts, atomic reactor materials and etc. because of its excellent properties in high temperature mechanical properties, antioxidatio, abrasion resistance, thermal stability, smaller coefficient of thermal expansion, larger thermal conductivity, hardness, thermal shock and chemical corrosion.

SiC陶瓷具有优良的高温力学性能，抗氧化性强、耐磨损性好、热稳定性佳、热膨胀系数小、热导率大、硬度高以及抗热震和耐化学腐蚀等优良性能，被广泛应用于精密轴承、密封件、气轮机转子、燃烧喷嘴、热交换器部件及原子热反应堆材料等，并日益受到人们的重视，应用前景十分广阔。

Two polysiloxanes (SR2 and P67) and one polycarbosilane were chosen as preceramic polymers. TG-DTA-MS, FT-IR, XRD,〓Si MAS-NMR, SEM, TEM, SAD, HREM, chemical analysis and density measurement techniques were used to study the cross-linking and pyrolysis mechanisms of the preceramic polymers. The development of chemical composition and structure, density, phase composition and microstructure of the solid pyrolyzed products during pyrolysis process were systematically investigated. While pyrolysis temperature approached 1000℃, ceramization process of the preceramic polymers almost completed, and ceramic yield of the preceramic polymers hardly changed any more.

选取了两种聚硅氧烷（SR2和P67）和一种聚碳硅烷作为聚合物先驱体，利用TG-DTA-MS、FT-IR、XRD、〓SiMAS-NMR、SEM、TEM、SAD、HREM以及化学成分分析、密度测量等手段，研究了聚合物先驱体的固化机理；以N〓为热解气氛，系统地考察了各种聚合物先驱体在热解过程中，其热解产物的化学成分和结构、密度、相组成及显微结构的演变规律。

In this thesis, by the means of calefactive oxidation test of coal samples, the characteristics of different samples spontaneous combustion are analyzed; the infrared spectrum is assimilated to review the rule that coal function corps change in the process of coal low-temperature oxidation ; by the means of thermal analysis by differential scanning calorimeter, thermogravimeter, the kinetic function of coal low-temperature oxidation in spontaneous combustion process are analyzed , depend on the device, the mathematical model of coal spontaneous combustion is developed, the model are dealt with, Finally, the temperature field and the velocity field with velocity of the entry flow is got.

论文通过煤的低温氧化和自燃过程，实验研究了煤的低温氧化气体产物特征和变化规律，研究得出了煤的低温氧化过程中气体生成量与氧气消耗量与煤温之间的指数关系式；在煤的低温自热氧化过程中，对煤的官能团等化学结构的变化研究，揭示了煤炭低温自热氧化化学基团变化规律；采用非等温TG和DSC法研究了烟煤低温氧化动力学，得出了煤低温氧化分布活化能及煤低温氧化机理函数的变化规律；建立了煤低温氧化自热数学模型，并对该模型进行数值解算，可得煤样的温度场与速度场随入口风量变化情况。

Synthesizing new compounds are always the goal of chemist. Recent ly, the progress of the hydrothermal synthesis method is giving a new method to synthesize new compounds. The hydrothermal synthesis method is prefectly applied to synthesizing the tunnling materials, micro-and meso-porous mat erials as well as some new materials, so this method obtained the intrest of che mist.

中文题名含有杂原子的金属－氧簇(V，Mo，W，P，As)的合成与结构副题名外文题名论文作者李亚丰导师裘式纶教授学科专业无机化学研究领域\研究方向学位级别博士学位授予单位吉林大学学位授予日期2002 论文页码总数70，68页关键词金属－氧簇化学多酸化学无机合成化学馆藏号BSLW /2003 /O611 /3 合成新结构和新组成的化合物一直是化学家们的目标，近代水热合成技术的发展为合成亲新化合物提供了一种新的方法，水热由于在合成具有孔道结构、微介孔材料以及一其它一些新型材料具有其它方法无可比拟的优越性，因此，越来越受到人们的重视。

Experiment results show as follows in the processing of semiconductor etching, chemical heat centers in the semiconductor material, and is convected gradiently in all directions; the vertical heat convection velocity is obviously swifter than the horizontal; the process of heat convection can be real- timely recorded, and the heat convection situation can be gotten in any small area at any time by infrared camera which makes the analyse and understanding of heat convection characteristic in the processing of wet etching more intuitionistic.

实验结果表明：在半导体腐蚀过程中，化学热以半导体材料为中心，向四周梯度状对流；向上的热对流速率明显大于水平的热对流速率；红外热像仪可以实时纪录热对流过程，并获得任意时刻、任意小区域的热对流情况，使得对湿法腐蚀过程中热对流特性的分析和理解更加直观。

Database of physical and chemical properties for solid wastes were constructed through investigation for single typical component and their mixture of solid wastes. The particulate trajectory model and heat transfer model were developed, based on the studies of Characteristics of solid wastes movement and heat mass transfer in rotary kiln. Pyrolysis experiments of solid wastes in lab and pilot scale rotary kiln pyrolyzers were performed. Mechanism of pyrolysis for typical solid wastes was analyzed. The characteristics of pyrolytic products, such as physical and chemical properties, composition and combustibility, etc, were investigated. A neural network model for the prediction of yields and properties of pyrolysis products was developed. Then, the potential applications of pyrolytic products and the substitution of pyrolytic fuels for corresponding commercial furls were investigated. The optimization of energy recovery and utilization for different wastes through pyrolysis was analyzed.

通过对典型固体废物组分及其混合物特性的分析，建立了固体废物的化学特性分析数据库，并据此进行了物理分类；对固体废物在回转窑内的运动和传热特性进行了研究，建立了固体物料的随机颗粒滚动理论模型和传热模型；在小型和中试回转式热解炉上进行了实验；对各种典型固体废物在回转窑内的热解机理和主要热解产物的性质进行了研究；利用神经网络等方法建立了各典型固体废物的热解产物的产率及特性的数学预测模型；对固体废物热解产物的物性、成分、燃烧特性等开展了研究，分析了其与现有商业燃料匹配的可能性；对热解产物的多种应用性能进行了研究，对不同废物热解中的能源回收和利用进行了优化分析。

The thermatic fibrous sepiolites are ones of rich Magnesium,richened with Magnesium,silicon and few Aluminum,and the sedimentary clayey sepiolites are ones of rich Aluminum,have lower Magnesium,Silicon and higher Aluminum.

本文通过两种不同成因海泡石化学成分特征的研究发现，热液型海泡石和沉积型海泡石的化学组成有较大差异，热液型纤维状海泡石MgO、SiO2含量高，Al2O3含量低，为富镁海泡石；沉积型粘土状海泡石MgO、SiO2含量低，Al2O3含量高，为富铝海泡石。

Thermodynamic analysis and chemical vapor deposition of pyrolytic carbon on the surface of needle-like goethite in a flow reactor were carried out.

采用流动反应器研究了丙烯热解和在铁黄颗粒表面生成热解炭的化学热力学以及化学气相沉积过程。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。