热化学

Tantalum is an ideal material for hot cathode. It has a low electronic work function, high melting-point, low evaporativity, and good mechanical, high-temperature, chemical properties. Especially in a PCVD ambient for diamond film deposition, its surface is transformed into tantalum carbide which has a much higher melting-point, lower evaporativity and better properties of electron emission.

钽是一种理想的热阴极材料，它具有电子逸出功低、熔点高、蒸发率小、良好的机械性能、高温性能、化学稳定性等优异特点，尤其是在辉光放电PCVD制备金刚石膜的特殊气氛中形成的碳化钽表面层，具有比钽更高的熔点、更低的蒸发率和更好的热电子发射特性。

There are three categories of maturity indicators of organic matter in current petroleum industry to evaluate the degree of thermal evolution for source rocks, including: 1 optical indicators, i.e., vitrinite reflectance, bitumen reflectance, sporopollen color and thermal alteration index, conodont color alteration index, and reflectance of fossil fragments; 2 chemical indicators, i.e., the maximum temperature in pyrolysis of organic matter, methyl phenanthrene indicator, the atomic ratio of H/C, carbon isotope indicator, and biomarker indicators; 3 indicators of spectroscopy, i.e., the free radical concentration of kerogen, the average structural scale of aromatic nucleus of kerogen, and the laser-Raman spectrum of organic carbon.

摘 要：当前常用的有机质成熟度指标包括3大类：1 光学指标，包括镜质体反射率、沥青反射率、孢粉颜色、热变指数(thermal alteration index， TAI)、牙形石色变指数(color alteration index， CAI)和生物碎屑反射率；2 化学指标，包括有机质最大热解峰温度、甲基菲指数(methyl phenanthrene indicator， MPI)、H/C原子比值、碳同位素指标和生物标志物指标；3 谱学指标，包括干酪根的自由基浓度、干酪根芳核平均结构尺寸和有机碳激光拉曼光谱。

This article describes the conditions of production and application of middle and small-sized RE-Mg ductile iron ingot mold during the last three years, and gives main properties of these ingot molds mechanic properties at room and high temperatures, resistance to oxidation and thermal fatigue, critical phase transformation temperatures and coefficient of thermal expansion,etc.

本文介绍了三年来采用稀土镁球铁材质制造中、小型钢锭模的生产试制和使用情况。报导了此种钢锭模的主要性能(常温与高温机械性能、抗氧化与热疲劳性能、临界相变点与热膨胀系数等)和表示出机械性能与化学成分间相互关系的回归方程。

Comparing with water, the optimal heat transfer enhancement is achieved near the critical micelle concentrations of surfactants. The degree of heat transfer enhancement is different with different surfactants and is influenced by solubility characteristic, ionic nature and chemical structure of surfactants. Boiling in surfactant solutions, when compared with that in water, is observed to be more vigorous with smaller-sized, more regularly shaped and faster departure frequency bubbles, but the surfactant solutions of Triton X-100 and Triton X-114 become cloudy for the cloud point of surfactants.

和水相比，表面活性剂强化池内核态沸腾换热的最佳浓度为临界胶束浓度；不同种类表面活性剂强化换热程度不同，它们与表面活性剂的溶解特性、离子类型和化学结构有关；溶液沸腾时，沸腾汽泡的脱离直径变小，脱离频率变快和更不易聚集，但非离子表面活性Triton X-100和Triton X-114由于存在浊点其沸腾溶液变浑浊。

The characteristics of charge storage in APCVD Si 3N 4/thermal\|grown SiO 2 double layers electret films, charged by coroma were investigated by measurements of isothermal surface potential decay and thermally stimulated discharge.

利用等温表面电位衰减及热刺激放电(thermallystimulateddischarge ，TSD)方法探讨了恒栅压电晕充电经常压化学气相沉积的Si基Si3N4 和热生长SiO2 双层薄膜驻极体电荷的存储特性。

The thermal properties, mechanical properties of PI-MWNTs nanocomposite were analyzed by Thermogravimetric analysis, Universal Test Machine and Hardness Pencil Test. The morphology of PI-MWNTs was observed by scanning electron microscopy. The dispersion of MWNTs in matrix were observed by transmission electron microscopy. The electrical property of composite were obtained by Super Megohmmeter.

研究中使用傅立叶转换红外光谱仪来鉴定其化学结构，热重损失分析仪探讨材料的热稳定性质，万能试验机及铅笔硬度计观察其机械性质，扫描式电子显微镜与穿透式电子显微镜来观察材料的表面型态及奈米碳管於基材中的分散性，超绝缘仪量测材料的电性。

The thermal properties and mechanical properties were analyzed by Thermogravimetric analysis and Hardness Pencil Test and Universal Test Machine, respectively. The structure of prepared PI-MWNTs was characterized by Fourier transform infrared spectrometry. The morphology of PI-MWNTs were observed by scanning electron microscopy and transmission electron microscopy. The electrical conductivity was analyzed by Super Megohmmeter.

本研究中使用能量分散光谱仪来鉴定多壁奈米碳管纯化效果，热重损失分析仪、铅笔硬度计、万能试验机分别测定材料的热稳定性质和机械性质，傅立叶转换红外光谱仪来鉴定其化学结构，扫描式电子显微镜与穿透式电子显微镜来观察材料的剖面型态与奈米碳管和基材之间的分散性，超绝缘量测仪量测材料的电性。

The adsorption isotherm of neptunium on silica gel correspond to the form of Langmuir isotherm. According to Clausius-Claperon equation,from the slope in InKd vs 1/T plot,adsorption heat could be estimated. From the data of adsorption heat it is concluded that the adsorption of neptunium on silica gel in nitric acid solutions belongs to chemical adsorption and the adsorption process is an endothermic reaction.

三种价态的镎在硅胶上吸附的等温线符合兰格缪尔吸附等温线的形式，是单分子层吸附；根据克劳修斯-克拉柏龙方程，以1nKd对1／T作图，通过直线斜率计算出吸附热，从吸附热的数据可判断三种价态的镎在硅胶上的吸附属于化学吸附，是吸热的过程；对NpOV）、Np和Np（VD在硅胶上的吸附进行了比较，提出了三种价态的锋在硅胶上吸附的机理。

The results show that: the functional groups in coal are the function of coal rank , and the yields of CO 2, H 2O and CO are related to the content of carboxyl, hydroxyl and other oxygen containing groups such as ether groups in coal, and Tar and CH 4 are related to the aliphatic CH, the char yields to the aromatic CH.

借助化学分析和FTIR光谱分析对我国煤化程度不同的18 种煤中官能团的研究表明：煤中官能团含量与煤化程度有关；煤中羧基、羟基及醚键等其他含氧官能团的含量与热解生成物CO2、H2O 和CO 的产率有关，脂肪—CH 的含量与甲烷和焦油的产率相关联，芳香—CH 的含量与热解半焦产率有关。

In Chapter 5,the pyrolysis of substituted six-membered ring model compound 4-methyl pyridine has been investigated.Instead of detail theoretical analysis of the reaction mechanism,the general results have been proposed from the products distribution and the combination of the pyrolysis investigation of its analogous pyridine.The major products are H_2,C_2H_2,C_4H_2,C_3H_3N and HCN,here HCN is not a primary initial product at low extent of decomposition.The mole fraction profiles of products have been obtained from the near threshold ionization.The pyrolysis of 4-methyl pyridine is initiated from the methyl abstraction and hydrogen abstraction procedures which are associated with the understanding of the soot formation and the NOX precursor correspondingly.

主要产物为H_2，C_2H_2，C_4H_2，C_3H_3N和HCN，其中HCN为非低温时的热解产物；通过近阈值电离并导出物种随温度变化的摩尔分数曲线，更详细地定量地描述了产物随温度的变化。4-甲基吡啶热解主要从母体脱甲基和脱氢两个初始反应出发，一种趋势是形成大质量数的苯并或杂环的多环化合物，有助于了解炭黑形成过程中的复杂化学过程；另一趋势是开环生成小的碳氢和腈类物质，实验得出的含氮物质的种类及随温度变化有助于了解NO_x的前驱物质的形成及其变化规律。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。