热化

Thermal exposured at 175℃ for 100 h and 500 h, the yield strength decreases by 5.5% and 14%, and the elongation decreases by 4% and 9.3%, respectively. The fact that S'(AI2CuMg) precipitates get coarsen and the precipitate-free-zones get wider are responsible for the decline of the tensile properties of 2124-T851 aluminum alloy under thermal exposure condition.

于175℃热暴露500h屈服强度和伸长率就分别降低14%和9%；于热暴露条件下，2124-T851合金拉伸性能衰退的主要原因是合金固溶体基体内主要强化相S'(Al2CuMg)相粗化以及晶界无沉淀析出带的宽化。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题，系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性，通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析，全文主要内容如下： 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明：红磷在空气中发生缓慢氧化、歧化反应，微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度，其中铜离子的作用最为明显，而铝、锌等离子减慢了红磷的氧化速度，银离子对减少红磷的吸湿性效果最好。

E. , Cu-Co, Co-W, Ni-W, and Ni-Sc system, were selected to study the physical mechanism involved in SSR and/or IBM.For the Cu-Co system (+10KJ/mol), some metastable phases such as amorphous, fcc-structured superlattice and dodecagonal phase were obtained by SSR and/or IBM.

比如说，离子束混合非晶化是一个非常复杂的过程，而热峰模型只给出了一个笼统的等效冷却的概念，对于最近在离子束混合实验中发现的一些新现象，如顺序非晶化现象，用热峰概念就无法给予恰当的解释。

Spiral steel pipe company's existing production lines, two of hot-rolled seamless steel pipe production line and four thermal expansion seamless tube production lines, the production φ219-1820 double-helical SAW pipe joints 200,000 tons,φ57-377 seamless hot-rolled 200,000 tons of steel pipes,φ377-630 thermal expansion Seamless Steel Tube 60,000 tons, product implementation SY/T5037, GB/T9711, GB/T8163, API 5L, API 5CT standards, widely applicable to oil and natural gas industry, chemical industry, general Fluid transport and infrastructure projects such as a bridge piling, sells to 27 provinces, municipalities and autonomous regions, and over 700 sales outlets, the reliable quality and high quality services to our customers has won the recognition and welcome.

公司现有六条螺旋钢管生产线、两条热轧无缝化钢管生产线和四条热扩无缝管生产线，年生产φ219-1820螺旋缝双面埋弧焊钢管20万吨、φ57-377热轧无缝化钢管20万吨、φ377-630热扩无缝钢管6万吨，产品执行SY/T5037、GB/T9711、GB/T8163、API 5L、API 5CT标准，广泛适用于石油天然气工业、化学工业、普通流体输送及桥梁打桩基建工程等，销往全国27个省、市、自治区，700多个销售网点，可靠的质量和优质的服务赢得了广大客户的认可和欢迎。

Specimens of the SBCB with different graphitizing degree were obtained in laboratory. Effects of graphitizing degree on the properties of the SBCB, including structure, thermal conductivity, thermal expansivity, resistance to thermal shock, resistance to erosion of molten iron and slag, were studied respectively.

在实验室制备了不同石墨化度的自焙碳块，并研究了石墨化度对自焙碳块的结构性质、高温冶金性能(包括恒压比热容、热扩散率、导热性、热膨胀性、抗热震性)、抗铁水和熔渣侵蚀性能及铁水渗透的影响。

The results show that the compound conductive fiber has typical structure of sheath-core consists of black greened polyaniline electric conductive deposition as the skin and the white polypropylene matrix fiber as the core, which makes the compound fiber preferable physical mechanical property. The intensity and the elongation ratio of the electric conductive fiber are decreased but the thermal stability is enhanced after modified. The compound fiber has the good acid resistance but poor base resistance. The thermal stability of the compound fiber prepared by 4-methyl-benzene sulfonic acid is better than that prepared by hydrochloride acid. Moreover, the compound fiber can be re-doped by other organic or inorganic acid after freed from the adsorbed acid. Furthermore, the electric conductivity of the compound fiber decreases with the temperature increasing but hardly changed with the humidity. The adsorptive ability and therefore the content of the polyaniline, the constant of electric conduction, and the durability of the compound fiber can be enhanced by thinning the diameter, section heteromorphosis, section heteromorphosis and plasma treatment of the surface or blending with COPET of the fiber.

结果表明：复合纤维是聚丙烯与聚苯胺的共混体系，具有典型的皮芯型结构，皮层为墨绿色的聚苯胺沉积层，形成连续的导电通道，芯层为白色的聚丙烯基质纤维，提供物理机械性能；导电改性后纤维的强度、强力和伸长率均有下降，但热稳定性得到提高；复合纤维的耐酸性比耐碱性好，以对甲苯磺酸做掺杂酸比盐酸掺杂聚苯胺热稳定性好，脱掺杂后的复合纤维，可用其它无机酸或有机酸进行再掺杂；复合导电纤维的电导率随温度升高降低幅度较大，但几乎不受湿度影响；基质纤维细旦化、截面异形化、表面等离子体处理或共混COPET等改性处理均能提高纤维的吸附性，进而提高复合纤维表面聚苯胺含量、电导率和耐久性。

Using of optical microscopy, X-ray diffraction, transmission electron microscopy, hardness and tensile testing, the effect of thermal exposure at high temperatures on the microstructures and of high-temperature tensile properties of rapidly solidified AlCrYZr have been studied. The results show that there are two main phases,Al20Cr2Y(cubic, a=1.437 nm) and DO23Al3Zr(terganal, a=0.4 013 nm , c= 1.732 nm), in the as-solidified alloy. The Al20Cr2Y phase can maintain its cubic structure at 500℃, but the particles coarsen remarkably and even become lumpish. In coarse lumpish Al20Cr2Y phase the plane faults and twin structures exist.

摘 要：采用金相、 X射线衍射、透射电镜、硬度测定和拉伸试验研究了高温热暴露对快速凝固AlCrYZr合金显微组织影响和高温下力学性能的热稳定性，结果表明，快速凝固AlCrYZr合金主要第二相为Al20Cr2Y(立方，a=1.437nm)和DO23Al3Zr(正方，a=0.401 3nm， c=1.732nm)，Al20Cr2Y在500℃热暴露尚能保持其立方结构，但质点明显粗化，甚至块状化，在粗大的Al20Cr2Y相中存在有层错和孪晶结构。

This thesis is divided into six parts. The first chapter is preface, the current status of research in the inverse problems for parabolic partial differential equations is reported; the second chapter is "regularization methods for numerical differentiation and their applications ", in this chapter we investigate many regularization methods from a viewpoint of regularization theory and algorithm, some applications in the inverse problems for parabolic partial differential equations are given; the third chapter is "spectral regularization methods". Based on Fourier analysis, within the framework of regularization theory, we apply the spectral methods to some ill-posed problems. Many numerical experiments are done in order to show the validity of the methods; the fourth chapter is devoted to wavelet dual least squares method and a revised wavelet method; in the fifth chapter,we combine finite difference method with method of lines and apply it to the backward heat conduction problem in time; in the sixth chapter "identification problems for unknown source ", the essence and the degree of two problems related to source identification are pointed out, at the same time, some numerical methods are reported.

本文分为六个部分，第一章前言简要分析了国内外抛物型偏微分方程反问题的研究现状；第二章数值微分的正则化及其应用从正则化理论和算法的角度出发，考察了许多正则化方法，还给出了数值微分在抛物型偏微分方程反问题的一些应用；第三章谱正则化方法是在Fourier分析的基础上，在一般正则化理论的框架下，给出了这种方法在各种不适定问题中的应用，数值实验表明谱方法是有效的；第四章研究了小波对偶最小二乘方法和改进的小波方法；第五章主要研究了有限差分方法结合线方法在时间反向热传导问题中的应用；第六章是未知源识别问题，主要指出了两类未知源问题的不适定程度和不适定本质，同时报告了一些数值方法。

The objective is to subjugate and discourage the people, because that allows the elite to continue to rule unopposed.

其目的是压制和打击人民的积极性，因为这可以让实权派继续统治不会沦为反对派。

GOD,this is the second time you vanquished me!

天啊，这是第二次你打败了我！