热力学

In this thesis, the author uses analytics, fluid mechanics and thermodynamic to analogize internal condensation on the basis of container charging and discharging, and find theoretical judging method of internal condensation.

因此本文的研究工作以最基本的气动系统——容器的充放气过程为出发点，首次用解析法，利用流体力学和热力学理论分析容器在充放气过程中的内部结露现象，找出对内部结露问题的理论判别方法。

To understand the thermodynamic process of the transesterification, the thermodynamic properties (△r H o,△r S o,△r G o, K p ) of the reaction for production of DPC and anisole from 373 K to 473 K was calculated by using Material Studio and ChemCAD software as well as Benson and Joback group contribution methods.

DMC与苯酚酯交换合成DPC反应热力学方面的研究报道很少，散见于一些工艺设计专利中，且都未对数据来源做详细介绍，很难对数据的可靠性进行验证。

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1，美丽红豆杉素B的首次全合成以价廉，易得的邻苯二酚和1，3-环己二酮为原料，经过改良的Friedel-Crafts烷基化反应，热力学控制的α，β-不饱和酮结构的α一位双烷基化，烯丙位的选择性氧化，以及选择性还原位阻较小的碳碳双键等十一步反应，以8.19％的总收率首次完成了美丽红豆杉素B的全合成。

As a result, the author discusses the thermodynamics habitus for the minerals either. With the calculation of the thermodynamics modeling, we run the dissolutionmodeling experiments for primary minerals (potash feldspar, albite, anorthite, andpyroxene, hornblende), which is under the conditions of organic acidic and 20 varietytemperature and pressure. The dissolution modeling experiments include 4 anorthitedissolution experiments, 8 pyroxene dissolution experiments, 8 hornblendedissolution experiments. We catch the records on the X ray diffraction, chemistryanalysis, SEMphotos, and the PH parameters. By theway, we discuss the dissolution habitus for the minerals either.

在热力学模拟计算的基础之上，进行20个不同温度和压力条件下，以有机酸作为溶解介质的储层砂岩骨架颗粒(钾长石、钠长石、钙长石以及铁镁暗色矿物中的辉石、角闪石等)的水—岩相互作用的溶解模拟实验，包括：4个钙长石的溶解实验、8个辉石的溶解实验和8个角闪石的溶解实验，获得了溶解模拟实验前后全部参与实验矿物的X射线衍射分析、化学全分析数据、扫描电镜照片，以及介质流体在实验过程中化学参数pH值的检测，在此基础上讨论了铁镁暗色矿物、长石等铝硅酸盐矿物在埋藏成岩过程中酸性介质条件下的溶解习性。

Citizenship is precisely not a form of brotherhood, of the kind that follows from a shared act of heartfelt submission: it is a relation among strangers, a collective apartness, in which fulfillment and meaning are confined to the private sphere.

但是我们没有考虑到两个非常重要的事实：第一，热力学第二法则告诉我们如果没有新能量进入，所有秩序都会衰弱。第二，我所说的"排斥一切的文化"的兴起。

It was found that both lgI and Z of both apolar and polar small solutes have the characters of thermodynamical equilibrium constant.

发现非极性与极性小分子溶质的lgI和Z均具有热力学衡常数的特征。

Based on the physical meaning of each term in the linear parameter log I (a constant correlating the affinity of solut e t o stationary phase) of stoichiometric displacement model for retention o f solute, the thermodynamic characteristics of log I of solute in revers ed-phase liquid chromatography were investigated theoretically. This poi nt was tested by experimental data with two linear relationships:(1) plot of log I vs 1/T with apolar, polar small solut es and proteins;(2) plot of log I vs log Po/w (partition co effi cient of solute between n-octanol and water) with apolar and polar smal l solutes.

依据液相色谱中溶质计量置换保留模型及线性参数log I(与1 mol溶质对固定相的亲和势大小有关的常数)，通过作图得知非极性和极性小分子溶质及生物大分子的log I与绝对温度的倒数1/T，以及小分子溶质的log I与其在正辛醇-水中分配系数的对数log Po/w呈线性关系，从两方面进一步证明了log I具有热力学平衡常数的性质。

We have also studied the kinetics of the cyclohexene epoxidation catalyzed by 2 with TBHP and the apparent reaction order, frequency factor and activation energy are obtained.

本文对该反应的动力学及热力学性质也进行了研究，确定了表观反应级数、速率常数和反应活化能。

However, there are many differences between the static and the dynamical spcetimes. Using the the general analysis, from the unified first law of thermodynamics dE_H = TdS+WdVwhere W =(ρ- P/2 on the apparent horizon, we study the effect of Hawking radiation of the apparent horizon of the FRW universe.

其次，基于静态黑洞时空隧穿方法的一般性研究，那里黑洞的辐射率Γ-exp，是视界上热力学第一定律dE_H=TdS+PdV的必然结果，我们在动力学时空FRW宇宙背景下，发展了这种分析。

Comparing it with the standard electrode potential of nitric acid,the reason of dissolution of HgS in aqua regia was quantitatively revealed,and this is that the high concentration of chloride ions reduces the reduction potential of sulfur in HgS,thus raising the reducing power of HgS rather than that the oxidizing power.

根据热力学平衡原理和设计的可逆电池反应，由 E~0Hg~(2++S/HgS数据，计算了 E~0HgCl_4~(2++S/HgS+4Cl~-数值，将其与 HNO_3的标准电极电位比较，定量地揭示了 HgS 溶于王水的原因在于该溶液中高浓度 Cl~-离子降低了 HgS 中硫的还原电位，从而提高了 HgS 的还原性所致，并非王水的氧化性比 HNO_3的更强。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。