热力学

The mechanism,thermodynamics and kinetics of ion-exchange reactions between alkali,alkaline-earth and transition metal ions and zirconium phosphate and its derivatives ar...

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性，另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The mechanism, thermodynamics and kinetics of ion-exchange reactions between alkali, alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed, progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性，另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The results obtained provide basic thermodynamic data for studying alkylation of phenol with DEC and developing catalysts for it.

为烷基化反应条件的控制和催化剂的探索研究提供了热力学依据。

The field of alternative stress was generated through a strong sound field system set up in our lab, and the thermodynamic properties of cells were studied by Differential Scanning Calorimeter. We found that the effects of stress on cells depended greatly on the intensity and frequency of stress.

研究了交变应力对烟草愈伤组织细胞的影响，采用本实验室研制的强声波发生装置来产生交变应力场，并利用差式扫描量热仪研究了不同强度和频率的交变应力作用后烟草细胞热力学相行为的变化。

ABSTRACT In the present paper experimental studies on thermodynamic behaviour of titanium and silicon oxides in a number of quaternary and pentanary molten slags have been made by means of H〓O/H〓 chemical equilibrium between copper melts and molten slags in alundum crucibles with the molybdenum plate as the liners.

本文采用H〓O/H〓定组成混合气体与钼衬坩埚中熔渣之间的化学平衡方法，实验研究了多个四元和五元熔渣中钛和硅氧化物的热力学行为。

The thermodynamic theories of separating aluminum and silicon in alunite ore with acid melting method were introduced herein,and the test results were presented also.

介绍了酸熔法分离明矾石矿中铝硅的热力学理论和实验结果。

Americium has lots of species in aquatic solution. It is difficult to measure the distribution of americium species while they can be calculated by many geochemical software.

Am在水溶液中的形态分布复杂，直接测量困难，使用相关软件依据热力学常数推算核素的形态分布简单可行。

At the same temperature, k〓 in the reversed micelles was always less than k＇〓 in the buffer. According to the thermodynamic analysis for inactivation of penicillin amidase in the reversed micelles, the free energy of activation was increased by 2. 71%, while the entropies and enthalpies of activation were decreased, corresponding to 63. 9% and 76. 9% of that in pure buffer respectively.

由热力学分析可知，青霉素酰化酶在AOT/异辛烷反胶团中的热失活过程，与水溶液中相比，活化自由能△G〓增加了2.71％，而活化熵△S〓和活化焓△H〓分别减小为原来的63.9％、76.9％，从而使酶热稳定性平均提高了2～4倍。

The experimental results indicate that the addition of NaOH is unfavorable to ammonolysis of α-CDA due to the participation effect of neighboring carboxyl group of α-CDA, which is contrary to the fact that strong alkaline environment is propitious to SN reactions of ordinary chlorinated hydrocarbons.

实验结果表明，与普通氯代烷的亲核取代反应不同，邻位羧基参与效应使得加入NaOH不利于α-CDA的氨解反应动力学和热力学。

Capric betaine was prepared through ammonolysis of α-chlorododecanoic acid with trimethylamine. The participation effect of the neighboring carboxyl group of α-CDA on dynamics and thermodynamics of the reaction was investigated.

以α-氯代十二酸与三甲胺的氨解反应制备α-癸基甜菜碱，研究了α-CDA在与三甲胺氨解反应中邻位羧基对反应动力学和热力学的影响。

In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是，在否定句或疑问句里，这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷