烧结的

This invention discloses a preparation method for anti-corrosion rare earth magnet material characterizing that it takes the optimized grain-boundary phase design as the starting point on the basis of a dual alloy method to select Nd base alloy with high crystal forming ability as the assist alloy and reduces the temperature of the press mold blank in a quartz container to room temperature from over grain-boundary phase melting point with the water extraction way to get enough cooling rate and guarantee the non-grain-boundary phase, compared with the material of the same composition prepared by ordinary method, the weightlessness of this invented material reduces over 30% after testing the weightlessness of the material by laying it for 96 hours under 121deg.C, 2 atmosphere and 100% humid environment to show the advanced performance of anti-corrosion.

本发明公开了一种耐腐蚀稀土永磁材料的制备方法，其特征是它在双合金法制备工艺的基础上，以优化晶界相设计为出发点，选取具有较高非晶形成能力的Nd基合金为辅合金，并在烧结回火时将置于耐高温石英容器中的压型坯件，从晶界相熔点以上以水淬冷却的方式降温至室温，以达到足够的冷却速率，确保得到非晶晶界相，根据本发明制得的耐腐蚀稀土永磁材料，通过测量在121℃、2个大气压以及100％湿度环境下放置96小时后材料的失重情况，结果显示本发明得到的材料与常规方法制备的相同成分的稀土永磁材料相比失重减少了30％以上，充分证明其具备了更优越的耐腐蚀性能。可广泛应用于电子、汽车、计算机、电力、机械、能源、环保、国防、医疗器械等领域。

Grinding wheel is usually mounted on surface grinding machine, external circular grinding machine and internal circular grinding machine, and can also be mounted on grinding wheel machine, knife grinder and universal cutter grinder for grinding of cutting tool. According to different functions, grinding mode and type of grinding machine, grinding wheel is manufactured into ones with all kinds of shapes and sizes, and common grinding wheel includes plane grinding wheel, cylinder grinding wheel, double hypotenuse grinding wheel, cup grinding wheel, flaring cup wheel, disc wheel, centerless grinding wheel, etc. The types of products include external circular, plane and centerless grinding wheels used for f

公司的产品类型有用于钨钢硬质合金的精粗磨削加工的外圆磨、平面磨、无心磨砂轮；有用于陶瓷、氧化锆白陶瓷、黑陶瓷行业的CBN/SDC金刚石平形砂轮、精密切割片、平行加强形砂轮和开槽电镀磨头；用于钢化玻璃，灯饰玻璃，水晶玻璃，磁性材料行业的CBN/SDC金刚石精密切割片，青铜磨盘，青铜切割片，平行双粒度磨盘和小磨头，深加工行业的CBN电镀和烧结磨轮、抛光磨盘；用于高速钢，45#钢的剪刀、锯片、刀片的精粗加工，用于加工硅片材料、铁氧体及其他材料的金刚石工具；以及其他行业需要的各种要求的非标金刚石工具。

Grinding wheel is usually mounted on surface grinding machine, external circular grinding machine and internal circular grinding machine, and can also be mounted on grinding wheel machine, knife grinder and universal cutter grinder for grinding of cutting tool. According to different functions, grinding mode and type of grinding machine, grinding wheel is manufactured into ones with all kinds of shapes and sizes, and common grinding wheel includes plane grinding wheel, cylinder grinding wheel, double hypotenuse grinding wheel, cup grinding wheel, flaring cup wheel, disc wheel, centerless grinding wheel, etc. The types of products include external circular, plane and centerless grinding wheels used for fine and rough grinding machining of t

公司的产品类型有用于钨钢硬质合金的精粗磨削加工的外圆磨、平面磨、无心磨砂轮；有用于陶瓷、氧化锆白陶瓷、黑陶瓷行业的CBN/SDC金刚石平形砂轮、精密切割片、平行加强形砂轮和开槽电镀磨头；用于钢化玻璃，灯饰玻璃，水晶玻璃，磁性材料行业的CBN/SDC金刚石精密切割片，青铜磨盘，青铜切割片，平行双粒度磨盘和小磨头，深加工行业的CBN电镀和烧结磨轮、抛光磨盘；用于高速钢，45#钢的剪刀、锯片、刀片的精粗加工，用于加工硅片材料、铁氧体及其他材料的金刚石工具；以及其他行业需要的各种要求的非标金刚石工具。

The structure measurement indicates that only a small amount of Bi3+ ions can not enter the A-site of La2/3Ca1/3MnO3 lattice. Because of the low melting behavior of bismuth oxide, the superfluous Bi will segregate as insulating bismuth oxides and bismuthate. Because of the segregation of Bi, the surface of the main phase has different ferromagnetic property from that of the core, namely the magnetic inhomogeneity of the samples is enhanced, which results in the broader ferromagnetism-paramagnetism transition and magnetoresistance plateaus in samples with the high Bi content.

结构测试表明Bi并不能进入La2/3Ca1/3MnO3的晶格锰位，由于A位元素的过量和铋氧化物的低熔点特性，烧结过程中Bi元素析出形成了绝缘性的第二相；并且Bi的析出导致样品主相的表面存在与主相体心磁性质不同的铁磁相，即样品的磁不均匀性增强，使得高Bi含量的样品表现出宽的铁磁-顺磁转变和磁电阻平台效应。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

Systematic research about technology parameters influences on the magnetic properties and microstructure of theses magnets have been done. The better parameters of production have been achieved. They are showed as follows: as-cast alloys with the nominal composition Nd15Fe78-xNbxB7 are prepared by induction-melting under argon atmosphere. As-cast alloys are broken under argon atmosphere and filtered through 40# screen. The coarse grain is ball-milled under 120# avgas for 80 min. The ratio of milling ball and grain is 15:1. Then fine powder is aligned and pressed in a magnet field of 1.5T. The pressure is 80MPa. The green compacts then are shaped by cold isostatic pressing under 280MPa pressure.

通过研究具体工艺参数对磁体磁性能及显微结构的影响，总结出适合于该系列磁体的制备工艺如下：按设计成分将原料放入真空感应熔炼炉内进行合金铸锭的熔炼；合金铸锭在高纯氩气保护下粗破碎过40目筛；以15∶1的球料比在120#航空汽油的保护下滚动球磨80min；球磨好的磁体粉末在1.5T取向磁场下以80MPa的压力模压成型，接着在280MPa压力下进行冷等静压；所得的压坯在1110℃烧结1h，900℃回火处理1h，600℃回火处理2h。

I.S.P is the typical complex and continuous production process. Based on the peculiarity of I.S.P: physical chemistry reaction is quite complex, operation condition is comparatively rigid, the charging ration needs to be exactitude. Temperature variety of zones in furnace including: warm-up charging zone, re-oxidation zone, revivification zone, slag smelting zone, The soft point and soft zone are the key factors, which have an effect on the smelting of ISP and it is a comprehensive parameter appraising the quality of sintered aggregate.

基于密闭鼓风炉铅锌冶炼生产过程特点：物理化学反应十分复杂，操作条件比较严格，入炉物料的配比要求也非常精确，是典型的复杂连续生产过程；论文分析了炉内各带的温度变化：料预热带、再氧化带、还原带、炉渣熔化带；分析、总结了影响鼓风炉生产的因素：鼓风制度(富氧熔炼、预热鼓风熔炼)、炉料的性质对熔炼过程的影响(烧结块、焦炭的性质及消耗)、鼓风炉操作的影响因素(鼓风炉系统、鼓风量与风温调节、炉前操作、冷凝分离系统、煤气洗涤系统、电热前床)。

By applying the technologies of diamond brazing and orientation of the diamond grains to the beads' manufacturing, the diamond wire saw can be used in some special area as its high cutting efficiency. And it will have very important meaning to developing wire saw with minor diameter beads as used to cutting precious materials.

其金刚石分布更为均匀，合金烧结密度更加合理；串珠金刚石钎焊技术和金刚石定向排布技术的应用，因其切割的高效率在一些特定的领域得到了很好的推广；小直径串珠的开发成功，对珍贵材料的切割有着十分重要的意义。

The results indicate that the cell only doped with Al2O3 (Cell 1) is of the worst output performance at 850 ℃, the output power density being 0. 083 W/cm^2, and that the cell doped with Al2O3 and coated with buffer layer (Cell 2) is of the best output performance at the same temperature, the output power density being 0.120W/cm^2. AC impedance spectroscopy analyses indicate that the interface resistance and Ohmic resistance of Cell 2 are obviously less than those of Cell 1, meaning that insulative nickel aluminum spine1 is generated by the reaction of Al2O3 and NiO during the sintering at a high temperature.

结果表明：850℃时，含Al2O3的电池输出性能最差，输出功率约为0.083 W/平方公分；含Al2O3并具有过渡层的电池输出性能最好，输出功率约为0.120 W/平方公分；交流阻抗谱分析表明，含Al2O3并具有过渡层的电池的欧姆电阻与界面电阻均比不含过渡层的明显减小，说明YSZ中添加的Al2O3在高温烧结过程中，与阳极材料NiO发生反应生成不导电的镍铝尖晶石。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。