烧结性

The influences of forming solid solution, generating new compound and addition of flux on sinterability, phase-structure and microwave dielectric properties of zinc titanate were analyzed.

对钛酸锌介电陶瓷的改性研究进行了综述，分析了形成固溶体、生成新的化合物和添加助熔剂对钛酸锌陶瓷的烧结性、相结构和微波介电性能的影响。

The challenges of these material are screen printing and sintering process. Many long fine patterned lines should be printed on a large piece of glass and sustain a smooth, continuous and uniform line pattern; on the other hand, the sintering process is rapidly increasing sintering temperature to a peak in a short time, then cooling the glass substrate to low temperature under a short time shock.

汽车钢化玻璃除霜加热线，是采用在玻璃基板上印刷银浆，在玻璃的钢化热处理过程中完成银导体膜的烧结附着，由于烧结时间短(总时间250sec)和温度骤变条件相当苛刻，要求导电细线无脱落断线，在功率满足要求的情况下，与外蓄电池连接的电极的焊接及附着强度也有具体要求，另外耐候性及耐擦洗等后步要求也较苛刻。

The effect of mixture of rare earth oxides on the sintering properties,microstructure and mechanical properties of magnesia refractory were studied.

研究了添加Y_2O_3的混合稀土氧化物对镁质耐火材料的烧结性、力学性能和显微结构的影响。

Experimental study of high temperature phase transformation for pyrophyllite

利用场发射扫描电镜表征了Zr-Co粉体的形貌特征和烧结后的陶瓷薄膜结构，热重分析了Zr-Co粉体烧结过程的失重和相转变吸放热过程，X射线衍射分析跟踪了不同温度段烧结体系的组成变化趋势，在此基础上对粉体烧结后陶瓷薄膜的防氧化效果进行了分析，结果表明：温度对粉体的颗粒形貌和晶相结构有较大的影响，高温烧结的粉体性质稳定，经过1200℃烧结后的陶瓷膜层具有很好的致密性，具有很好的防氧化效果。

Preparation of the cathode includes:shaping under the press of 40Mpa, sintering at 550℃for 1 hour and at 900℃for 8 hours and threading with molybdenum bar; Considering the literatures we choose CaCl2 as salt for preparation titanium. Pretreatment of salt is for 1 hour at 100℃and for 2 hours at 300℃. Partial pressure of oxygen which need lower than 5.11×10-7Pa to reduct titanium oxides and hygroscopic property of salt need a sealed equipment to electrolyse. And finally successfully designed a satisfied one and the results show that the equipment can be satisfied the requirment of the experiment. Flow of the inert gas is 1.5L/min, the voltage is 2.8 V, temperature is 850℃and time is 2 hours during pre-electrolysis. Flow of the inert gas is 0.2L/min, the voltage is 3.1 V, temperature is 900℃and time changes with the mass of TiO2 during electrolysis, namely the greater need the longer time; To eliminate influence of salt and other impurities, the products need to wash with distilled water and dilute chlorhydric acid , then wash with dilute hydrochloric acid under supersonic wave assistant. Finally, electrometical properties of the electrolysis of TiO2 is researched by cyclic voltammetry and chronoamperometry, and results show that there are two main reodox steps, namely from TiO2 to TiO and from TiO to Ti.

阴极制备主要包括40MPa压力下模压成型、两段式烧结(1小时内升至550℃保温1小时，再1小时升温至900℃保温8小时)及烧结后TiO2块打孔用钼棒串接三个主要环节；实验中选用CaCl2作为电解熔盐，并对其进行预处理(100℃，保温1小时； 300℃，保温2小时)；经热力学计算，还原钛氧化物的氧分压至少要低于5.11×10-7Pa，结合电解过程中所用熔盐CaCl2有极强的吸水性的特点，电解装置应有较高的密封性，自行设计了一套密封性可靠的电解装置，便于实验过程中熔盐预处理和氧分压的控制；通过干燥处理预电解过程中Ar流量大约为1.5L/min、电压为2.8 V、温度为850℃、时间为2小时，电解过程中Ar流量大约为0.2L/min、电压为3.1V、温度为900℃，实验结果表明电解时间与TiO2质量密切相关，质量越大需要电解的时间越长；通过自来水冲洗—稀盐酸浸泡、洗涤—在超声波辅助作用下稀盐酸洗涤，可减少熔盐及其它杂质对电解产物检测结果的影响；最后，通过循环伏安法、计时电流法对电解机理的研究，确定电解还原TiO2制备金属钛主要经历了TiO2-TiO-Ti的过程。

In this article, three kinds of prealloy powder were developed by water atomization method. The base attribute, pattern, phase composition, differential thermal analysis of powder were researched. Sintered density, hardness, bend strength, Young's modulus were researched as hot pressed sintering temperature changing. By using abrasive wearing equipment upbuilt by the authors, the wear resistance were determined. Green-pressing density, simulated green-pressing strength and bonding momental of high frequency brazing were assayed. SEM corrosion structure and SEM appearance of fracture were observed.

本文采用水雾化法开发了三种预合金代钴粉末：对粉末的基本属性、形貌，粉末的相组成，粉末的差热性进行了分析研究；测定了它们的烧结密度、硬度、抗弯强度、弹性模量随热压烧结温度变化的规律；采用作者自行建立的磨料磨损试验方法，测定了它们的质量磨损百分率；测定了它们的冷压生坯密度、模拟生坯强度以及高频钎焊的结合力矩；观察了热压烧结SEM腐蚀组织和SEM断口形貌。

The 〓 composite powder obtained by calcining at 600℃ is well dispersed and has the best sinterability.

当煅烧温度为600℃时，复合粉体的分散性和烧结性最好。

The experimental results show that microwave sintering promotes the densification of green compacts with higher heating rate and reduced sintering cycle. The sintered relative density of 99.8% can be achieved during microwave processing under appropriate conditions. In addition, microwave sintering improves the uniformity and homogenization of W grain size, and yet leads to growth of W grain. Fe sintering aid degrades the microstructure uniformity and further coarsens W grains. The present investigation demonstrates the feasibility of applying microwave sintering technique to consolidate W-Cu composites and its promising outlook in reducing production cycle and cost.

结果表明：微波烧结升温速度快，周期短，能促进W-Cu材料的致密化；在适当条件下，微波烧结能获得相对密度达99.8%的W-Cu样品；微波烧结能改善W-Cu样品中两相分布的均匀性和W晶粒尺寸的一致性，但引起W晶粒的快速长大；Fe烧结助剂导致W-Cu材料显微组织均匀性变差，并引起晶粒进一步粗化；微波烧结技术能够应用于W-Cu材料的制备，在缩短生产周期、降低生产成本方面具有潜在优势。

The results show that high energy ball milling refines and homogenizes the mixed powders, accelerates the sintering process, and with the increase of milling time, the grain is finer and the alloy is denser. HIP and forging is beneficial to decrease or remove the pole formed during the sinter course, and as the last process, forging breaks the junctions between TiC particles, the microstructure and mechanical properties of alloy are improved.

研究结果表明：高能球磨使粉末细化和成分均匀化，促进烧结进程，随球磨时间的延长，合金组织细化且致密；热等静压和锻造工艺可进一步减小和消除合金中烧结后残留的孔洞等缺陷；锻造作为最后工艺，可使TiC颗粒之间的连接破碎，促使硬质相颗粒弥散分布，从而改善烧结组织，提高合金的致密性及力学性能。

The self-binding and self-sintering propertirs of the ultrafine powders of the green coke are analysed theoretically, it is pointed uot that long time grinding is the vital way to improve these properties.

本文从理论上对生焦超细粉的自粘结性和自烧结性进行了分析，指出了长时间研磨是提高生焦粉末自粘结性和自烧结性的主要途径。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐