炔的

The mechanisms of the ruthenium-catalyzed reaction of organic azide with terminal alkyne have been investigated using density functional theory.

采用密度泛函理论，对在Ru催化剂存在下，有机叠氮化合物和末端炔的反应机理作了深入理论研究。

A novel zwitterion derived from the addition of thiazole carbene to ketene was discovered and captured by an activated alkyne. In this process, we developed a facile and efficient three-component tandem reaction involving thiazole or benzothiazole carbene, disubstituted ketene and activated alkyne.

我们发现了一种新的噻唑卡宾和烯酮形成的两性离子的存在，并用活泼炔成功捕捉，从而发展了一个新的噻唑卡宾或苯并噻唑卡宾、二取代烯酮和活泼炔的三组分串联反应。

Firstly, the reactions of glutaric acid, sebacic acid and propargyl alcohol afforded two dipropargylesters:(CH≡CCH_2OCO)_2(CH_2)_3 (compound 1) and (CH≡CCH_2OCO)_2 (CH_2)_8 (compound 2),respectively.

首先，本文分别选用戊二酸，癸二酸与丙炔醇反应得到了两个新的有机二酸二丙炔醇酯：戊二酸二丙炔醇酯(CH≡CCH_2OCO)_2(CH_2)_3(化合物1)和癸二酸二丙炔醇酯(CH≡CCH_2OCO)_2(CH_2)_8(化合物2)。

The results showed polymeric diaryliodonium salts were effective aryl ion transfer reagents. Thirdly, a new type polymer supported hypervalent iodine reagents poly { [4-Hydroxy iodo] styrene} has been developed. It was an effective oxidative reagent, and could be applied to the one pot synthesis of 4-arylthiazoles.

然后，我们以聚苯乙烯羟基对甲苯磺酰氧基碘苯为原料，成功制备了一类新型聚合物高碘试剂—聚苯乙烯负载的炔基碘盐，并研究了其作为炔基转移试剂的有效性：(1)该试剂可对硫、氮、硒等负离子进行亲电炔基化反应，合成炔基亚砜、0，0-二烃基二硫代磷酸炔基酯、1-苯乙炔基苯并噻唑以及炔基硒醚。

On the other hand, reaction of lactol derived from D-mannose and D-glucose with Grinard reagent of propargyl bromide also proceed both withanti stereoselectivity and with high anti-specificity.

链增长及目标分子中的碳碳双键是由一步Wittig反应和一步末端炔的烷基化再部分氢化而获得，双键构型-选择性可达到95％以上。

The steoreselectiviy showed the E selectivity in most of cases and Z selectivity was presented in larger substituents like mesityl and 1-naphthyl.

进一步增大烯上的取代基则可以得到Z选择性的烯炔产物。利用如此的方式，也许还可以用来合成含烯炔的高分子。

In order to discuss the regioselectivity of nitrile oxide 1,3-dipolar cycloaddition to propyne , 1,3-dipolar cycloaddition reaction of substituted nitrile oxide (RCNO, R=F, NO2, OCH3, OH, COOCH3, CHO, CONH2, H, CH3) with propyne was studied using density functional theory at the 6-311++G** level, and the reaction rates were calculated at different temperature from 200 to 400 K.

用密度泛函B3LYP/6-311++G**方法研究了氧化腈(RCNO，R=F，NO2，OCH3，OH，COOCH3，CHO，CONH2，H，CH3)与丙炔的1，3-偶极环加成反应，并且计算了不同温度下的反应速率常数，讨论了氧化腈上不同取代基R的取代效应和温度对反应区域选择性的影响。

Describe how a mixture of 1-hexyne and 2-hexyne can be separated chemically into two pure components.

答：如何利用化学方法将1-己炔和2-己炔的混合物分离开来？

List alkanes,alkenes,and terminal alkynes in order of decreasing acidity of their terminal C-H.

答：由大到小排列烷，烯和端炔的端碳氢键的酸性

The results show that their thermal stability,compared to the similar linear polys,were improved,and in the meantime,they inherited the optical properties of linear polys.

结果表明，在热稳定性得以提高改善的同时，该系列星状寡聚芴炔衍生物良好的保持了线形聚芴炔的光学性能。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。