溶解物

The model was used to fit the release profiles of the above three different actives, and the diffusion coefficient and dissolution rate constant were obtained. Based on the modeling study, the relationship of porous microspheres structure, actives performances and release behavior was found, hence a theoretical basis was provided to optimize the microsphere synthesis and desired actives release profile.

采用提出的模型对三种活性物的体外释放实验数据进行拟合，求得不同活性物的有效扩散系数和溶解速率常数，揭示了微球结构、活性物性质和释放性能关系的一些基本规律，为指导微球合成、改善和控制活性物的释放性能提供了基础。

In this paper, with 2-oxo-propionic acid salicyloyl hydrazone as a ligand, one calcium complex, three copper complexes and thirteen rare earth(RE=La, Ce, Pr, Nd, Sm, Eu. Gd, Tb, Dy, Er, Tin, Yb and Lu) complexes have been synthesized. The crystals of four complexes were obtained, and the crystal structures were determined by single crystal X ray diffraction. One of the crystals is calcium complex, the other are binary and trinary complexes of copper.

本文选用2-羰基丙酸水杨酰腙作为配体，在水中分别与钙、铜、稀土(RE=La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er、Tm、Yb和Lu)的盐反应，共制得了17种未见文献报道的配合物，另外还培养了2-羰基丙酸水杨酰腙、咪唑与铜、钙的二元及三元配合物的四种单晶，对La-Gd的稀土的配合物进行了溶解热的测定，并用Gauss-98软件包对铜的配合物进行了有关量化计算。

Through the experiments on hydration of AH in the following sulphate（Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4）, dissoluble sulfate hydrate origining from hydration process of AH affects it's hydrous rate, hydrous rate of AH does not connect with Z/R of cation in stimulation, theory that Z/R affect hydrous rate of AH does not exist. Third, hydration of AH in dissoluble sulfate complies with dissolve-nucleate -grow theory, concentration of Ca~2+ from dissolving of CaSO_4 is higher than one of CaSO_4·2H_2O, calcium sulphate dihydrite gets a motivity of crystallization. dissoluble sulfate takes the following function: double-salt or dissoluble sulfate hydrate from hydration of AH in it becomes heterogeneous particle and a kind of nucleation catalyzer, and reduces surface barrier when DH becomes crystal because the crystal of DH precedently appears in uneven place. Results indicate hydration of AH does not conform with double-salt theory, but it conform with this mechanism: dissolve-nucleate-grow, formation of DH is an uneven nucleation and crystalizaion process.

通过对CaSO_4在Na_2SO_4 、K_2SO_4 、Rb_2SO_4 、Cs_2SO_4 、(NH_4)_2SO_4溶液中水化过程，以及CaSO_4·2H_2O、CaSO_4与以上硫酸盐反应速度、产物的研究，说明复盐理论不正确；CaSO_4在（Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO_4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4）溶液中水化，水化过程中硫酸盐水合物的析晶影响着无水硫酸钙水化，与激发剂阳离子Z/R值大小无关，阳离子的Z/R参数影响水化率的规律并不存在； 3、无水硫酸钙在可溶性硫酸盐中的水化按照溶解-成核-生长理论进行，CaSO_4达到溶解平衡时Ca~2+的浓度大于CaSO_4·2H_2O溶解平衡的Ca~2+的浓度，CaSO_4·2H_2O获得结晶的驱动力，可溶性硫酸盐起到形成晶核的作用：水化过程与CaSO_4生成复盐或析出水合物所形成的细小物相，作为异质微粒使母相中存在不均匀性，这些不均匀性有效地降低成核时的表面能位垒，使CaSO_4·2H_2O晶核优先地在这些具不均匀性的地方形成，因此这些物质起成核催化剂作用。

Iron oxides would continue to be formed or at least not to be dissolved under oxic conditions, and the sediments in brown to red color will then be dominant. While in a reducing environment, iron oxides will be dissolved, with the possible migration of iron ion in the ocean, and then buried as siderite, pyrite, or other ironbearing minerals.

氧化强氧化条件利于沉积物中氧化铁的持续产生或者至少保持不被溶解的状态，从而形成棕色-红色沉积物；还原条件利于沉积物中铁氧化物的溶解，形成菱铁矿、黄铁矿等形式的埋藏，并可能造成溶解铁在海洋内的迁移。

At present,the rate laws and reaction mechanisms of pyrite oxidation,pyrite and chalcopyrite formation,uraninite and magnetite dissolution in aqueous solutions are mainly studied,and it is discovered that (1)oxidation rate of pyrite controlled by surface reaction assume fractional dependence on Fe3+ and O2 molalities in acid solutions;(2)Pyrite cannot nucleate directly from solutions below 300 ℃,it can only form initially through sulfidation of a FeS precursor. The rate equation of reaction between FeS and H2S to form pyrite is of the second order;(3)Chalcopyrite is formed by reactions of pyrrhotite or pyrite with Cu2+,the former proceeds via a series of mediate metastable phases of Cu-Fe sulfide,whereas the rate equation of the latter is apparently of the first order which is controlled by surface reaction;(4)The nonlinear behavior of magnetite dissolution at acid pH can be represented by a shrinking core model coupling with surface reaction and diffusion transport.

目前主要研究了水溶液中黄铁矿氧化、黄铁矿和黄铜矿形成、晶质铀矿和磁铁矿溶解的速率定律和反应机理，发现：(1)酸性溶液中黄铁矿的氧化速率对Fe3+和O2浓度呈分数依赖并受表面反应的控制；(2)低于300 ℃时黄铁矿不能从溶液中直接成核，而需初始地通过FeS先驱物的硫化生成，FeS与H2S反应形成黄铁矿的速率方程为二级；(3)磁黄铁矿或黄铁矿与Cu2+反应均可形成黄铜矿，前者经历了一系列准稳的Cu-Fe硫化物的中间物，后者的速率方程为表观一级并受表面反应的控制；(4)酸性pH时磁铁矿的非线性溶解行为可采用表面反应扩散输运耦合的收缩核模型来描述。

Excitation-Emission Matrix Fluorescence Spectroscopy was employed to study fluorescence characteristics of chromophoric dissolved organic matter readily released from sediment particles during episodes of resuspension, and bottom waters and surface sediment pore waters were compared in all corresponding sites.

对采自厦门湾九龙江入海河口的4个沉积物样品进行了室内再悬浮模拟实验，利用荧光激发－发射矩阵光谱研究了再悬浮过程中从沉积物中释放出的有色溶解有机物的荧光特征，同时通过与相应站位沉积物间隙水和底层水的对比分析，探讨了河口近岸海域的沉积物再悬浮作用作为水体中溶解有机物来源之一的可能性。

To improve the effect of CDCA on dissolving cholesterol gallstone, the water-soluble copolymers as polycarboxylic acid of comb-like copolymers and C_(60)-PCC were synthesized, which being used for modification of CDCA and strengthening effects of CDCA on dissolving the cholesterol gallstones by their entropy-repelled properties of comb-shaped side chains in buffers of phosphate and in model bile.The design theory of polymer was mainly employed to synthesis the conjugate of PCC-CDCA and C_(60)-PCC-CDCA by C_(60), polyoxyalkylene allylalkyldiether and maleic anhydride, which were copolymerized with AIBN as initiator, and then PCC or C_(60)-PCC were reacted with CDCA. The structures of the copolymers and the conjugates of PCC-CDCA and C_(60)-PCC-CDCA were confirmed with IR, TLC and TEM. The dissolving effects and the dissolution kinetics mechanism of cholesterol gallstone was inverstigated in PBS and in model bile of different cholesterol saturated index at pH7.4, including PCC-CDCA or C_(60)-PCC-CDCA.

利用高分子设计理论，以烯丙基聚氧乙烯基醚、顺丁烯二酸酐、C_(60)和CDCA为原料，以偶氮二异丁腈为引发剂，合成具有梳状侧链结构的梳状共聚物-CDCA结合物和C_(60)-梳状共聚物-CDCA结合物，以IR、TLC和TEM法表征共聚物的结构，并在pH7.4的PBS液和不同胆固醇饱和指数的模拟胆汁中进行溶石效果的研究，探讨在PBS液和不同CSI的模拟胆汁中结合物溶解胆固醇结石的效果和溶解动力学机制。

P species, main as Ca-P and organic P forms, showing rego〓 pollution and karst area of lake watershed, inorganic P〓 related to Ca〓, Al〓, Fe〓 content in the overlying water, sediments is not a simple reservoir of dissolved phosphate and particle phosphate, near the interface, near 98% of total P existed as active forms, they may release to overlying water through reduction dissolution, deadsorption in the period of early diagenesis, only 2% of P as fixed forms, which mainly remained in the sediments, sediment was an important resource of nutrients of ovrelying water.

高原湖泊沉积物中的磷以有机磷和Ca-P形式存在为主，反映了高原湖泊流域污染和碳酸盐地区的整体背景，无机磷形式与水体吸附体Ca〓，Al〓和Fe〓的含量有关。底部沉积物不是溶解性磷酸盐和颗粒磷酸盐的长期储存场所，几乎有98%的磷是活性的形态存在，它们通过早期成岩作用在还原条件下还原，溶解和释放又重新回到上覆水体，只有2%的磷以固〓态的形式稳定保存于沉积物中，因此，沉积物为水体营养程度的重要来源。

A method for the analysis of zinc oxide phase content in sulfide ore was studied. On the basis of the characteristics of each phase component, the sulfide ore sample was leached twice with NaOH and acetic acid-ascorbic acid, respectively, so that the oxide mineral and zinc oxide were dissolved completely. The leaching rate of zinc oxide phase was up to 98 Vo. Moreover, the dissolution of zinc sulfide phase was effectively inhibited, solving the problems of selective leaching and determination for zinc oxide.

研究了硫化矿中氧化锌相含量的分析方法，根据硫化矿中各物相组分特点，提出了用氢氧化钠溶液和乙酸－抗坏血酸溶液二次浸取硫化矿，使锌氧化矿、氧化锌充分溶解，氧化锌相的浸取率达到98%以上，同时有效地抑制了硫化锌相的溶解，较好地解决了氧化锌相选择溶解测定的问题。

The results show that the as-synthesized chalcone-containing copolymers are a kind of thermosensitive polymer with a lower critic solution temperature and the LCST of the copolymer decreases with the increase of the chalcone content in the copolymer. With the increase of the solvent polarity, both the maximum absorption wavelength and the fluorescence emitting wavelength of the chalcone-containing copolymers redshifts, and the intensity of fluorescence first increases, then decreases, which exhibits solvent polarity sensitive fluorescence properties.

结果表明，侧链查尔酮共聚物是一类具有低临界溶解温度的温敏性聚合物，其LCST温度随着共聚物中查尔酮含量的增加而降低；随着溶剂极性的增加，侧链查尔酮共聚物的紫外-可见最大吸收波长红移，其荧光发光波长红移并且发光强度先增强后降低，具有溶剂极性敏感的荧光特性；同时对比侧链查尔酮共聚物水溶液低温和高温下的荧光，发现低温下几乎无荧光，高温下其荧光得到明显增强，其荧光具有可逆的温度&开/关&特性。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。