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溶胶化

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In the aspects of research method, we took the method of preparing sol at first and then impregnating the wood to obtain ceramic-wood composite; this method made the wood use efficiently and increased the wood's weight gain percent. The ceramic-wood composite with performances of well decay resistance, dimensional stability, effloresce resistance and high strength was obtained by importing the cymene to the net of gel as the result of co-hydroxylation between MTES and TEOS. Making use of XPS ,we found that the apex of Si2p、O1s、C1s had evident chemical shift , which validated the existence of Si-O-C bonding.Key Words: Sol-gel, Ceramic-wood composite, Modified sol, Ecomaterials

在工艺方法上,采用先制备溶胶,然后浸注木材的工艺方法具有原料利用率高、提高增重率的优点;采用甲基三乙氧基硅烷和正硅酸乙酯共水解的方法,将甲基引入陶瓷化复合木材的凝胶内部,所制备的材料具有尺寸稳定性好、具有耐风化和耐腐朽性,强度高的特点;首次利用X射线光电子能谱,发现了Si2p、O1s和C1s谱峰发生了明显的化学位移,证实了Si-O-C键合作用的存在。

The composite film appeared semitransparent and brown to yellow from optical microscopy. Results show that shorter time sol-heating results in thiner film with less surface roughness, less conglutination to base, and easily to disconnect, while longer time sol-heating results in thicker film with better conglutination to base and worse roughness. RDX distributes in the film everywhere on the whole but discretely on the scale of 2.4 μm according to EDS results. XRD curve of RDX/RF film shows the superposition of RF non-crystal bread curve and RDX crystals diffraction curve. RDX diffraction peaks are broadened and its crystal size is calculated to be lower to 43 nm.

实验所得薄膜半透明,呈棕红色至黄色;实验表明,溶胶恒温加热时间较短时,所得薄膜的单层厚度较小,较平整,但附着力小,干燥后易脱落;恒温加热时间较长时,所得薄膜的单层厚度较大,不易脱落,但表面平整性较差;能谱测试表明,薄膜中的RDX整体上分布较为均匀,但在测试点位间距为2.4μm的微观尺度上呈离散状分布;XRD测试表明,RDX/RF复合物薄膜表现为RF的非晶态馒头峰与RDX衍射峰的叠加,RDX衍射峰明显宽化,其晶粒度可低至43 nm。

The styrene-acrylate spheres were coated with the TiO2 colloidal particles via electrostatic effect and hydrogen bond interactions with the increase of aging time, thus the film-forming capability of the solution was changed. The poor film-forming capability results in the formation of the porous structure with dense, homogeneous island morphology. Then the TiO2 porous films with dense pores can be obtained after two coating-dissolving cycles.

结果表明,TiO2溶胶与苯丙乳液混合后,陈化时间的延长有利于TiO2胶粒通过静电、氢键作用在苯丙乳液粒子表面形成吸附层,从而改变涂膜液的成膜性,形成较为密集、且均匀分布的岛状多孔结构,在此基础上经两次涂膜,即可获得具有致密孔洞的TiO2多孔薄膜。

In this paper, we recounted the recent development of solid supeeracids and their appliance in esterification.

采用溶胶一凝胶法制备SO_4~(2-)/TiO_2-SiO_2固体超强酸催化剂,考察它在乙酸甲酯酯化反应中的催化活性。

Seventh: The sol-gel method developed here for the synthesis of nanocrystalline film gate are compatible with conventional silicon planar technology, and there is no any limitation to the polarity of the film type n or p for making different kinds of nanocrystalline-film-gate-OSFET sensor. This is a very important basic work for the extending, improving and integrating of the similar devices.

七、研究开发的制备氧化物及复合氧化物纳米晶薄膜的溶胶—凝胶工艺可以实现与硅平面工艺兼容,采用该工艺可以制作不同纳米薄膜栅的OSFET新型气敏元件,薄膜的导电类型不受限制,可以是N型的,也可以是P型半导体,为该种类器件的推广和改进以及进一步的集成化创造了基础。

From probability consideration, the curing theory of A〓+A〓-type and A〓+ B〓-type polymerization involving initiation stepis proposed. The sol-gel distribution equations which can describethe behaviour of the conversions in the curing process are givenand the gelation condition, the number fractional distribution andits invariant property are obtained.

针对含引发机制的〓型和〓型缩聚反应体系的固化问题,利用概率分析的方法进行了系统的理论研究,给出了这两类反应体系的溶胶凝胶分配方程,从而揭示了体系在固化过程中的变化规律,得到了这两类反应体系的凝胶化条件、数量分布函数及其不变性。

The effective factors of reaction temperature,catalyst,gelatinization time and baking condition during the preparation process were studied.

采用溶胶-凝胶法制备10-30nm的二氧化钛,并研究了反应温度、催化剂、凝胶化时间及焙烧条件对粒子形成的影响。

Series automatically paste machine, is currently domestic update generation transport type paper paste gum equipment, this machine provide stable capability, simple operation, quick speed produce, use heat dissolves gum powder, thus avoiding white gum shrinkage and mildewed, can also increase finished product degree of hardness, transform and fold is not easily, can paste document nip, photograph volum, top grade pack envelop, and can produce diversification gift box, the moon cake box, refinement box, rigidity box etc, deluxe paper product, it is ideal choice for large, medium and small scaled packing line.

自动上糊机,是目前国内最新一代输送型纸张上面上胶设备。此机性能稳定,操作简便,生产速度快。使用热溶胶粉,从而避开白胶缩水和发霉问题,也可以增加成品的硬度,不易变形打折。可糊合档夹、相册、精装书封面,并可生产多表化的礼品盒,月饼盒,精品盒,硬盒等高级纸制品。是大、中小型包装行业流水线作业的理想选择。

In this paper, acrylamide-crylic acid hydrosol was synthesized by copolymerizating of acrylamide and crylic acid monomers in aqueous solution.

本文采用共聚法合成了丙烯酰胺-丙烯酸水溶胶,利用羟基化碳纳米管增加其强度和稳定性,制备成了具有温度和pH双重敏感特性的凝胶薄膜。

FT-IR was employed to fllow the sol process and the photopolymerization of the hybrid systems.

利用FT-IR监测了TBT水解缩合形成溶胶的过程及杂化体系的光聚合过程。

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