溶胶化

The results indicated that hydrogen bond and covalence bond were formed between PVA and TEOS through the sol-gel reaction.

结果表明PVA与无机相发生溶胶-凝胶反应生成氢键和共价键Si-O-Si，形成交联有机聚合物／无机杂化体系，使杂化膜的结晶度减少，控制了膜的溶胀，提高膜的溶解选择性能，但膜的溶胀减少会使通量有所下降。

From the transform infrared spectroscopy and X-ray photoelectron spectroscopy spectra, the hydroxyl and ethoxyl groups of the silica sol drawn from partially hydrolysis and polycondensation between TEOS and MTES can react with PA6 precursor.

红外图谱和X射线光电子能谱分析结果显示，硅溶胶的羟基和未完全水解的烷氧基能够与PA6的前驱体发生杂化反应。X射线衍射结果显示，采用本实验方法制备出的PA6和疏水型PA6/SiO2有机无机杂化材均为α晶型，而DSC结果表明，PA6/SiO2有机无机杂化材料的熔点略高于PA6。

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

The preparation process of self-holing polyimide with organosilicon block includes the following steps: 1 the first reaction of polyacid anhydride in functionality not lower than 2, silicon oil with 2 or more amino or imino groups and polyamine with 2 or more amino groups, and the second reaction with one or several kinds of added isocyanate with 2 or more isocyanate radicals to produce sol of polyamido acid containing organosilicon block; 2 solidifying the sol to obtain solid polyamido acid containing organosilicon block; and 3 imidonating the solid to obtain self-holing polyimide with organosilicon block.

本发明公开了一种有机硅嵌段自发孔聚酰亚胺的制备方法，该方法包括以下步骤：(1)有机溶剂中具有大于或者等于2的酸酐官能团度的多酸酐与具有大于或者等于2的胺基或亚胺基的硅油以及具有大于或者等于2的胺基的多胺反应，随后添加一种或多种具有含有等于或者大于2个异氰酸酯基的异氰酸酯反应，生成含有机硅嵌段聚酰胺酸的溶胶。(2)溶胶固化制成有机硅嵌段聚酰胺酸固体。(3)固体亚胺化，即得有机硅嵌段自发孔聚酰亚胺。

Results show that some primary factors affect sol-gel transition, gelation formation and quality. These factors include the temperature of solation formation and sol-gel transition, drying time.

对溶胶-凝胶法的研究发现：溶胶形成温度、凝胶干化温度及干化时间等都是影响干凝胶质量的主要因素。

Using cetyl trimethyl ammoniunm bromide as templating agent, the mesoporous TiO_2 with special performance was synthesized by a tartaric acid sol-gel method. The UV irradiation was used in this process.

以十六烷基三甲基溴化胺为模板剂，采用溶胶-凝胶法，在溶胶-凝胶制备过程中引入紫外光照辐射，制备出具有一定特殊性能的中孔TiO2材料。

Silicone/SiO2 organic-inorganic hybrid sol have been prepared from tetraethyl orthosilicate as inorganic precursor, methyl triethoxysilane and diphenyl dimethoxy silane as organic precursor, the hydrochloric acid and water as catalysts, by sol-gel method through the hydrolysis-polycondensation reaction.

采用溶胶－凝胶法，以正硅酸乙酯为无机相前驱体，甲基三乙氧基硅烷和二甲基二甲氧基硅烷为有机相前驱体，盐酸和水为催化剂，通过水解－缩聚反应制备了有机硅／SiO2有机－无机杂化溶胶。

Ni-P-mCMC/mCS bipolar membrane was prepared from carboxymethyl cellulose modified with phosphorylated agent as a cation exchange layer and chitosan modified with glutaraldehyde as an anion exchange layer. The electrolysis cell was constituted by Ni-P-mCMC/mCS BPM as a septum for electrogenerating furfural alcohol and furoic acid.

以磷酸化试剂改性羧甲基纤维素钠制备了阳膜层，以戊二醛改性壳聚糖制备了阴膜层溶胶，将阴膜层溶胶流延于阳膜层上，制备了P-mCMC/mCS双极膜，而后以化学镀方法在阳膜层表面镀镍，制备了Ni-P-mCMC/mCS双极膜，并应用于成对电合成糠醇、糠酸。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术，以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶，再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合，经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

Ceramic-veneer Composites is a three-layers plywood prepared by heat pressing, which composes of ceramic-veneer on the surface and unworked veneer inside. Ceramic-veneer is a material prepared by Sol-Gel method and Vacuum-Pressure method, and constitutes with veneer and ceramic emulsion.

摘 要：陶瓷化单板表层复合材料是以陶瓷化单板为表层材料，未处理木材单板为芯材，经热压工艺制备而成的三层胶合板；陶瓷化单板是以木材单板为基材，陶瓷前驱液为浸注剂，采用溶胶-凝胶法经真空加压浸渍处理而成。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。