溶胶

This invention discloses a new technology for preparing rear earth ionic doped fiber prefabricated rods with DC-RTA technology in a sol-gel method including preparing sol containing necessary doped ions, coating said sol uniformly on the inner wall of the quartz glass tube and burning it under high temperature to coagulate and vitrify them to a doped layer and repeating the above process to form a fiber prefabricated rod by oxygen and hydrogen flame after the doped layer reaches to a designed thickness and the fiber prefabricated rod can be made to various rare earth ionic doped fibers by an ordinary drawbench technology.

本发明属于光纤制造和光纤激光技术领域，具体公开了一种利用溶胶凝胶方法中的DC-RTA技术制备稀土离子掺杂光纤预制棒的新工艺。该工艺步骤包括预先配制好含有所需掺杂离子的溶胶，将该溶胶均匀涂覆在石英玻璃管的内壁后高温灼烧，使之凝结并玻璃化为一层掺杂层。反复上述涂覆灼烧过程，在掺杂层达到设计厚度后由氢氧焰高温收棒形成光纤预制棒。该方法所得到的光纤预制棒可以通过普通拉丝工艺拉制成各类稀土离子掺杂光纤。

The main object of this research is to investigate synthesis of Cu23Cl Cu and CuO nanoparticles through electrospinning and heat-treated method The research is mainly focused on preparative parameter and the change of heat-treated temperature to form the nanoparticles inlaid in silicon fibers the shape and color change are dicussed First of all to prepare the Polyvinyl butyral and silica dioxide complex nanofiber by electrospinning and then to investigate different heat-treated temperature and reactive time to being an influence on the products The results detected by SEM XRD TEM EDS FTIR combined sol-gel process and electrospinning can prepare Polyvinyl butyral and silica complex nanofiber The experimental result is found when heat-treated temperature is 100~4750C it can produce Cu23Cl nanoparticles; Above 4750C~ 4900C it can produce Cu nanoparticles; Above 450~7000C it can produce CuO nanoparticles And the viscosity is lain between 20~40cp and the sol-gel process time is 3hr it can produce the thinner fibers The average diameter of the fibers are 107 88±21 01nm;Due to the nanoparticles inlaid in the silica fibers the thinner fibers can be inlaid the smaller nanoparticles so this is the result that the experiment is expected To calcine the complex fibers is to produce surface silica fibers contain Cu23Cl Cu and CuO nanoparticles due to surface plasma resonance it make the color of the fibers become yellowish green from light white green turn into the red nuclear finally As the experimental result to utilize sol-gel process combine electrospinning can produce porous silica fibers contain Cu23Cl Cu and CuO nanoparticles

本研究旨在探讨「利用放电纺丝和热处理法来合成Cu23Cl、Cu和CuO奈米粒」之研究，实验著重在制备参数与热处理温度变化对所形成的奈米粒镶嵌在二氧化矽纤维中的形态与颜色变化探讨。首先，利用放电纺丝法制备出聚乙烯醇缩丁醛及二氧化矽之奈米纤维，比较不同的热处理温度与反应时间的改变对产物生成产生影响，进而研究不同热处理温度和时间对生成奈米粒的影响。产物经由SEM、XRD、TEM、EDS和FTIR等仪器分析结果显示，结合溶胶-凝胶法(sol-gel process)和放电纺丝法可产生聚乙烯醇缩丁醛及二氧化矽复合奈米纤维。实验结果发现，若热处理温度在100~4750C下可得到Cu23Cl奈米粒，475~4900C 可得Cu奈米粒，450~7000C以上可得 CuO奈米粒。而黏度介於20~40cp间和溶胶-凝胶时间为3hr时，可产生直径比较细的纤维，纤维直径为107 88±21 01nm；且由於奈米金属颗粒镶嵌在二氧化矽纤维中，直径比较细的纤维，可以得到比较小的奈米金属颗粒，这与实验预期相符。而锻烧此复合物产生多孔的二氧化矽纤维并包含Cu23Cl、Cu和CuO奈米微粒时，由於表面电浆子共震关系，而使纤维颜色由淡白黄绿色变成黄绿色，再变红褐色。由实验结果得知，利用溶胶-凝胶法(sol-gel process)结合放电纺丝法和不同热处理温度，可产生Cu23Cl、Cu和CuO奈米粒镶嵌在二氧化矽纤维。

The effects of thepreparation conditions on the structures and performances of the sol samples were studied,followed by investigating the formation mechanism of the anatase TiO_2 particles. Thecharacterization of the as-obtained sol-gel samples shows that the TiO_2 and P-doped TiO_2sols have anatase crystal structures, and the latter has higher crystallizability than theformer.

通过对TiO_2溶胶进行微观结构表征，发现：TiO_2溶胶和掺磷TiO_2溶胶均呈锐钛矿晶型，颗粒呈梭形，分散性较好，后者的结晶度更高；两者在可见光区均有较大的光吸收，最大吸收波长为550nm，磷的加入使得TiO_2的禁带宽度变大。

In this dissertation,the hydrosol of CuO, AgCl and AgI were prepared by precipitation method,while Cu2O by Oxidation-reduction.

本文中采用沉淀法制备氯化银、碘化银水溶胶和氧化铜水溶胶；采用氧化还原法制备氧化亚铜水溶胶。

MoO3 organosol was obtained by using CTAB to modify the nanoparticles in MoO3, hydrosol and n-pentanol to extract MoO3 nanoparticles modified by CTAB. The effect factors on organosol were discussed extensively.

采用表面活性剂CTAB对MoO_3水溶胶中的纳米粒子进行表面修饰，通过正戊醇萃取制备了MoO_3纳米有机溶胶，对制备有机溶胶的条件进行了系统地研究。

AgCl , Agl and CuO organosol were obtained by using oleic acid to extract and modify the nanoparticles in hydrosols. The effect factors on organosol were discussed extensively.AgCl organsol,AgCl and CuO organosol were mixed with MMA.

用油酸萃取并包覆了水溶胶中的氯化银、碘化银和氧化铜纳米粒子，制备了氯化银、碘化银、氧化铜及氯化银与二价铜共存有机溶胶，并对制备有机溶胶的条件进行了系统的研究。

Aluminum Ispropoxide was hydrolyzed to prepare Al〓O〓 sol. The hydrolyzed 〓CHOH affected the sol peptization. The colloidal particle was the smallest when the peptization time was 12 hours.γ-Al〓O〓 membrane without cracks, thickness about 2μm, was prepared from 1M sol with a suitable amount of PVA solution. The mean pore size of the membrane was about 3nm. And, the H〓/N〓 separation factor was 3. 53, exhibiting good separation performance.

异丙醇铝为前驱体，水解制备Al〓O〓溶胶，水解产生的异丙醇影响溶胶的胶溶效果，并且胶溶12小时得到的胶粒最小。1M溶胶加PVA制备厚度2μm左右，无开裂γ-Al〓O〓膜，经600℃煅烧，平均孔径为3nm，H〓/N〓分离系数可达到3.53，表现了很好的分离性能。

The process is composed of three steps: the formation of Ni_2 gel; the nucleation of nickel oxalate; the transition from Ni_2 gel into nickel oxalate sol.The nickel oxalate synthesized is identified by XRD to beα-NiC_2O_4·2H_2O with rhombohedron morphology, while two angles of the rhombus at underside are 106 and 74 degrees separately.

研究中，采用SEM、XRD、FTIR、TGA—DTA、GCMS等方法，对粉末样品进行表征。1凝胶—溶胶法制备单分散草酸镍粉末提出了一种凝胶—溶胶法制备单分散草酸镍的方法，由Ni_2凝胶生成—NiC_2O_4·2H_2O颗粒形核—凝胶Ni(OH_2向溶胶(NiC_2O_4·2H_2O)转化3个步骤组成。

The formation and stability of colloidal gold Nano-particles in different diameters by means of sodium citrate reduction was studied in this paper.

利用紫外可见吸收光谱研究了金溶胶的形成过程，制备了10～50nm不同粒径的金溶胶，研究了不同粒径金溶胶的可见吸收光谱变化和分散稳定性。

The preparation method of the photocatalysis functional ceramics was as follows: firstly, to prepare the titanic acid sol and the titanic acid sol mixing iron ion; then, to load the soil in the stoneware tube and the honeycomb ceramics by the sol-gel technology; finally, to roast the product by the program heating.

先制备钛酸溶胶和掺入Fe3+的钛酸溶胶；用溶胶-凝胶法分别将它们负载于炻器管和矩形蜂窝陶体上；再用程序升温法煅烧，得到纳米TiO2光催化功能陶瓷。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失