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The reduction of energy of activation in the concerted path of the aminolysis of phenyl formate was found to be more significant than that in the neutral stepwise process due to the solvent effect of water, ethanol and acetonitrile.

水、乙醇和乙腈溶剂可降低协同途径的活化能,溶剂化效应的大小对溶剂的极性不敏感。

This results in a higher possibility for the components to enter the unstable demixing gap after the rapid phase separation of the system has taken place.Therefore,a bicontinuous structure is easily formed for CA membrane. For the systems of ScCO_2/toluene/PSt and ScCO_2/solvent/PVB,the increase of temperature or decrease of pressure leads to the binodal curves shifting toward the polymer/solvent axes,and thus results in the decrease of miscibility gap.The membrane toplayers of ScCO_2/solvent/PVB systems are dominated by the equilibrium thermodynamics,while the formation of membranes sublayers is the result of the combination of the equilibrium thermodynamics and membrane formation kinetics.

以下时由双节线、旋节线之间构成的亚稳互溶分相区很窄,使得该体系在快速分相后其组成变化进入旋节线内不稳分相区的可能性极高,从而易导致CA膜形成双连续结构;温度升高或压力减小均可导致ScCO_2/甲苯/PSt与ScCO_2/溶剂/PVB两种铸膜体系的双节线向聚合物/溶剂轴一侧靠近,均相区减小;ScCO_2/溶剂/PVB体系的膜表面结构形成主要受平衡热力学过程的控制,而膜的截面结构是其平衡热力学与扩散动力学共同作用的结果。

It was found that these ionic liquids possess the thermoregulated function of"mono-phase under low temperature, biphase under high temperature".

测定了不同乙氧基链长的上述离子液体在有机溶剂中的溶剂性能,找到了具有&室温均相,高温分相&的温控离子液体/有机溶剂液液双相体系。

Purposes:3-methoxy - Butanoic alcohol used for high boiling point solvents, used nitro - cellulose paint, epoxy coatings, brake oil viscosity regulator, printing ink solvents, cutting oils and dyes, pigments, pesticides, etc will secure vinyl chloride solvent.

用途:3-甲氧基丁醇用作高沸点溶剂,用于硝基纤维素漆、环氧树脂涂料、刹车油粘度调节剂、印刷油墨溶剂,切削油以及染料、颜料、农药、氯乙烯稳妥定剂等溶剂

Then bis chloroformate was reacted with aromatic amines under the appropriate solvent and appropriate catalyst, after removed the solvent to obtain one kind of new amine-terminated polyether.

以聚氧化丙烯为基础原料,与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯,然后再与芳香多胺在合适的溶剂和催化剂下反应,脱除溶剂后得到一种新型的端胺基聚醚。

As a foundation raw material, propylene oxide was reacted with phosgene use the process tradition method that mean low temperature and high temperature two phosgenation sections to synthesis bis chloroformate .

以聚氧化丙烯为基础原料,与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯,然后再与芳香多胺在合适的溶剂和催化剂下反应,脱除溶剂后得到一种新型的端胺基聚醚。

An unprecedented combination of photochromism and solvatochromism for a 1,2-bis cyclopentene derivative,1,2-bis(2-methyl-5-formyl-thien-3-yl) perfluorocyclopentene,is observed:1 BMFTP,dissolved in the alcohols,exhibits the largest positive solvatochromic shift in wavelength witnessed to date.

我们发现了醛基二芳烯BMFTP的溶剂变色效应:1在醇类溶剂中,醛基二芳烯分子闭环态吸收波长将会发生显著红移;2在不同溶剂中,醛基二芳烯闭环态吸收波长不同。

The influence of top temperature of the extraction tower and that of resin tower, solvent rates were studied, and the optimized process conditions were obtained. The correlation between DAO yield and its quality was established. Furthermore, the preliminary explorement was made about the solvent deasphalting process when blending with FCC slurry.

在自行设计的6塔溶剂脱沥青装置上,本文对DHVR混合C〓溶剂脱沥青过程进行了系统的研究,对抽提塔、沉降塔塔顶温度和溶剂比的影响进行了考察,优化了工艺操作条件,建立了预测DAO收率与其质量之间的关系式。

Moreover, the A-B-A triblock copolymer solution in a selective solvent, which is good for the block B, was explored. It was observed that the flowerlike micelles were formed, in which the central block B took on a loop conformation and the two end A blocks became a part of the micellar core. It was found that some of the soluble middle B blocks served as extended bridges between the small clusters by the poorly solvated end A blocks.

在A-B-A三嵌段共聚物溶液体系中,溶剂是链段B的良溶剂,是链段A的不良溶剂,此时我们得到了花型结构的胶束,其中花心是由链段A聚集而成,花瓣是由链段B形成的,而且在体系中也发现了有些胶束间存在着桥,并且在浓度很高时,体系出现了凝胶现象。

For example, solvent polarity strength, on activato colors surfacesf fat…etc, such as adsorption octadecylarnine ingredients solutions of the order is: ethlene-methylbenzenesulfonic? heptoxide? mixtrue.

例如,溶剂的极性不弱度不不不不差别,不不不不不差活性剂颜料暗不天的吸附也有所不不不不差别,如不一八烷基胺在各组份溶剂洋吸附度的挨次是:甲苯﹥二氯乙烷﹥搀和溶剂

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