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The experiments reveal that solvent outflow is controlled by the system's viscosity while non-solvent inflow is controlled by the hydrophile of the interface.

实验表明,溶剂外扩散受控于体系的粘度,非溶剂的向内扩散受控于界面的亲水性。

A composition that can be used as catalyst is disclosed, which comprises or is produced by combining, a titanium compound; either a complexing agent, a combination of a complexing agent, hypophosphorous acid or a salt thereof, and optionally a solvent, a zirconium compound, or both, combinations thereof; a phosphorus compound; and, optionally, a solvent.

公开了一种可用作催化剂的组合物,该组合物包括钛化合物;络合剂,或络合剂、次磷酸或其盐和选择性使用的溶剂、锆化合物或二者的组合,或它们的组合;磷化合物和选择性使用的一种溶剂;或是用它们的组合制成的催化剂。

Recently years, with the increasing concern on the environmental of human being lived, the use of water as a medium in organic reaction has received considerable attention due to its several advantages, for example, it is cheaper, nonflammable, nontoxic and easily available on the earth, and had incommutable advantages relative to organic solvents.

随着人们对生存环境的日益重视,以水作为溶剂的有机反应的研究越来越受到人们的关注,这是由于水作为反应介质,具有价廉、易得、不可燃、无污染等优点,具有有机溶剂无可取代的优越性。

" Described in this article modei-method " one is pursuant to the same or are similar to the solubility parameter can be miscible the judgment resin in solvent or mixture is dissolved and inks and substrate intersolubility.

本文所述的&两维制墨方法&其一是依据溶解度参数相同或相近可以互溶的原则,对判断树脂在溶剂或混合溶剂中是否溶解及油墨与承印物的互溶性。

The complex was characterized by FT-IR, XRD, BET, SEM and EDS. The resin-supported catalyst exhibited high catalytic activity in the Heck reaction and could be reused up to 17 times in NMP or 16 times in DMF at 90 ℃ in the Heck reaction of iodobenzene with acrylic acid.

该负载型催化剂对Heck反应表现出高的催化活性和很好的重复使用性能,于90℃的碘苯与丙烯酸的Heck反应中,在NMP溶剂中能重复使用17次,在DMF溶剂中能重复使用16次。

We have developed a simple and easy-handling procedure for copper-catalyzed cyanation of aryl halides using K4[Fe_6] as the cyanide source. The present procedure has ligand- and base-free advantages, and was accomplished under the conditions of exposure to the air without degassing of the solvent.4. We carried out the selective control of preparation for phenyl ether and phenol from iodobenzene with 10 mol% of Cu_2·H_2O as the catalyst under the condition of exposure to air.

这个程序有无配体无碱的好处,并能够在暴露于空气的条件下进行,溶剂也不用脱气。4、空气气氛下,用10 mol%的Cu_2·H_2O催化碘苯偶联,实现了制备二苯醚和苯酚的选择性控制:即在有(来源:Aa955BC55论文网www.abclunwen.com)机溶剂NMP中实现了碘苯直接制备二苯醚的Ullmann反应,在H2O中实现了碘苯直接制备苯酚。

Furthermore, the one-dimensional complexes 26 and 28 with strongπ-πpacking interactions are prepared from DMF solvent, which indicates that the traditional solvent volatilizing method could bring low-dimensional complex.4. By measuring the enthalpy changes of the liquid phase formation reaction for complexes a~e, and calculating the electronic densities of five 5-substituted derivation of isophthalic acid, we can make a conclusion that 5-substituted group changing of the ligand has a little influence on oxygen atoms of carboxyl groups.5. Fluorescence experiments of these complexes indicated that they could be used for luminescence materials in future.6. Using packing saturation rule we calculated and analyzed these series of complexes, and the results showed that the changes of complexes with changes of ligands could be explained from the rule.

在DMF溶剂中得到了具有强π-π堆积作用力的一维配位聚合物[Ln(5-NO_2-bdc)(NO_3)]Ln=Pr(26和Ho(28),表明传统的溶剂挥发合成条件可以得到低维的配合物。4、通过配合物a~e的液相生成反应焓的测定,以及配体阳离子的电子密度计算,进一步佐证了间苯二甲酸的5位取代基变化对配体的羧基氧原子配位能力影响不大的结论。5、荧光特性表明此类配合物可以用于发光材料。6、利用堆积饱和规律对所得系列的配合物的进行计算和分析,发现随着配体的变化,配合物的变化可以从堆积饱和规律出发进行解释。

The relationship between apparent equilibrium constants Kex, and the physical parameters of solvents can be derived.

考察了在不同溶剂中HDEHP对镨、钕、钐、镝、钬、镱等的萃取,计算得到萃取表观平衡常数Kex、热力学平衡常数KΘex和萃合物的溶解度参数δc,建立了lgKex与溶剂极性参数ET (30)、α间的经验方程。

Besides those used in water to clean dishes and laun dry , detergents that function in other solvents are used in lubricating oils, gasolines, and dry -cleaning solvents to prevent or remove unwanted deposits.

洗涤剂除了用在水中洗碗碟或衣服之外,还可用于其它溶剂如润滑油、汽油和干洗溶剂以防止沉淀或移除无法去掉的污渍。

The solubility in general organic solvents, oleic acid and lipin of both derivatives were also studied. In order to find out the solubilities in general organic solvents, PhCS that had satisfied solubility in DMF, DMAC and DMSO and EHCS that was amphiphilic were prepared.

为考察壳聚糖衍生物在通用有机溶剂中溶解性问题,我们制备出了在DMF、DMAC、DMSO等通用有机溶剂中溶解性很好的邻苯二甲酰化壳聚糖以及水油两亲性的乙醚胺壳聚糖。

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