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The solvent effects were studied with the conductor-like polarizable continuum model respectively in the solvents acetonitrile and water, and we found that the solvent effects reduce the activation energy, but the reduction is small, these reactions are not sensitive to the solvent polarity.

采用导电极化连续介质模型分别研究了在乙腈与水溶液中反应的溶剂化效应,发现这些溶剂可降低反应的活化能,但降低的程度比较小,反应速率变化不大。

Acetone, and water?2?propanol were obtained by the laser method and fitted by the exponential model. Finally, the crystallization metastable zone

异丙醇混合溶剂中的溶解度数据,采用指数模型对溶解度数据进行关联;最后测定头孢唑林钠在水及水与异丙醇混合溶剂中的冷却结晶介稳区数据,为头孢唑林钠的工业生产提供热力学依据。

It can be divided into water-soluble solvent and oil-soluble solvent Protectant Protectant.

它又可分为水溶性溶剂型防护剂和油溶性溶剂型防护剂。

The non linear regression applied to relation of the proton change number of acid with the proton concentration may improve the precision of pKa determination.

它首先牵涉到有机酸在溶剂中的电离形式[1],然后是电离平衡常数中活度系数的测定[2],再者是非水质子溶剂或有机-水溶液中质子浓度的精确测定。

By using a mixture of aromatic hydrocarbon and water as a binary solvent,reaction of pyrogallol with PhCCl 3 was carried out in the presence of a catalyst(ZnCl 2?AlCl 3 or SOCl 2).2,3,4-Trihydroxybenzophenone was obtained in yields of 80%-87% with the advantages of easy control,stable yield,high product quality and low cost.

以焦性没食子酸为起始原料,在惰性气体保护和催化剂(ZnCl2、AlCl3或SOCl2)的存在下,在芳香烃与水组成的二元混合溶剂中,与三氯甲苯反应,经过芳香烃溶剂的后处理,可以得到2,3,4-三羟基二苯酮,产率最高达87%。

A new method of solvent-thermal synthesis of Meso-tetra(4-carboxyphenyl) zincporphyrin complexs, using the propionic acid and the DMF as solvents and the salt of zinc, catalyst-;pyrrol,4-carboxybenzaldehyde, as reagents.

报道了用丙酸和DMF作溶剂和催化剂,直接用吡咯,4 羧基苯甲醛,锌盐合成Meso 5,10,15,20 四锌卟啉配合物的新型方法———溶剂热合成。

The influences of the type and dosage of the aldehyde, organic acids, as well as the water content in the reaction system on the racemization were examined in detail, and L-Glu was racemized quickly in the presence of 0.2 molar ratio of L-Glu to salicylaldehyde in acetic acid containing 20% water.

详细考察了醛的种类及用量、羧酸溶剂的种类、反应体系的含水量对消旋化的影响,结果表明L-谷氨酸在含20%水的乙酸溶剂中,以水杨醛作为催化剂(水杨醛与L-谷氨酸的物质的量比为0.2)的优化条件下可以快速地被消旋化。

Methodsresearched the influences of solvent volume, extracting time and solvent ph value on extraction techniques for rauwolfia vomitoris afzel. with the water soluble alkaloids in extracts as index, the optimal condition by l9(34) orthogonal test was studied. the data obtained were analyzed for glm using sas 8.0 software package.

方法采用l9(34)正交实验,研究溶剂用量、提取时间、提取溶剂的ph条件3个因素对催吐萝芙木醇提工艺的影响,以提取物中的水溶性生物碱为指标,采用sas 8.0统计软件进行方差分析,得到最佳提取工艺。

The chewing gum is dissolved using a water-immiscible solvent requiring either evaporation and redissolution of the sample or solvent change during the SPE step.

口香糖溶解于与水不相溶的溶剂中,在固相萃取中既可以蒸发和重解样品又可以更换溶剂

In recent years, salt-mixed solvent system has become a very important system. And with the development of studies on rare alkali metal rubidium and cesium, it is significant to study the rubidium / cesium salt-mixed solvent system.

近年来,盐—混合溶剂已构成了一类重要的体系,且随着对重稀碱金属铷、铯的了解,人们发现研究铷、铯盐—混合溶剂体系有着极其重要的意义。

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If you have any questions, you can contact me anytime.

如果有任何问题,你可以随时联系我。

Very pretty, but the airport looks more fascinating The other party wisecracked.

很漂亮,不过停机坪更迷人。那人俏皮地答道。