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It was found that the stereoselectivity of this reaction to produce S-CHBE could be remarkably improved by pretreatment with heating and allyl alcohol.

而烯丙基溴预处理可以使反应立体选择性从通常的生成S-型产物过量转变为R-型产物过量,优化处理条件后能使R-CHBE的e.e。

Overall, this paper is proved to be meaningful in both theoretical explanation and practical application of biodegradation of anthraquinone resembles.

总之,通过本论文的工作,筛选并找到了一株高效降解溴胺酸的菌株,对其降解溴胺酸的特性及降解途径进行了深入的研究,不仅在理论上有助于诠释动胶菌与溴胺酸反应的实质,而且为该菌株处理溴胺酸等蒽醌类染料中间体的实际运用中操作参数的设计和选择提供依据。

Firstly, XRD, TEM and FT-IR were used to characterize the structure of CNTs treated by dense HC1, dense HNO_3, HNO_3, H_2SO_4-HNO_3, K_2Cr_2O_7-H_2SO_4 and bromic acid. The results showed that purification treatment had no change on the structure of CNTs. But on the top of CNTs have function group such as -OH and -COOH after H_2SO_4-HNO_3 and K_2Cr_2O_7-H_2SO_4 were treated.

采用浓HCl、浓HNO_3、H_2SO_4-HNO_3、K_2Cr_2O_7-H_2SO_4、溴水共5组物质分别对CNTs进行纯化处理;借助XRD、TEM、FT-IR等分析手段对处理前后CNTs结构及形貌进行表征,发现以上5种物质纯化处理并不会对CNTs结构造成很大影响,其中H_2SO_4-HNO_3和K_2Cr_2O_7-H_2SO_4处理效果较好,除杂的同时CNTs端口带上-OH或-COOH活性官能团。

The effect of six chemical disinfectants of different quality concentrations, namely, povidone iodine、dibromohydantoin、formalin、trichloroisocyanuric acid、calcium hypochlorine and sodium hypochlorite, on the species and quantities of plankton in cultured water were studied.

采用不同质量浓度的聚维酮碘、二溴海因、福尔马林、富氯、漂粉精和次氯酸钠等6种化学消毒剂,对蓄水沉淀池养殖海水进行消毒处理,处理前后分别测定浮游生物种类和数量变化。

Methods The mercury in urine, which is the total amount of inorganic mercury in urine, including those produced from organic mercury after treated by potassium bromate and potassium bromide, is determined by atomic absorption spectrophotometer after reduction into mercury atom with sodium borohydride.

方法]尿样中汞(尿中无机汞和经溴酸钾-溴化钾处理尿中有机汞生成的无机汞之和)以硼氢化钠还原生成汞原子蒸气,用原子吸收光谱仪测定其汞的含量。

Or FR4 PCB, bromide exsited mainly in pyrolysis gas and gas products mainly consisted of CO, CO2, propylene, 2-methacrylate, bromomethane, and a small amount of acetone, C1-C3 halogenation alkyls. The pyrolysis gas could be reclaimed as fules after debromide treatment. Pyrolysis liquid products consisted of 8.333% water and 91.667% oil component.

R4板中溴元素主要存在于气体产物中,气体产物主要为CO、CO2、丙烯、2-甲基丙烯、溴甲烷以及其他小分子烯烷烃产物,气体产物可通过除溴无害化处理作可燃气回收;液体产物中含有8.333%的水和油质成分。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SO〓 solution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究,采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓,以光催化降解溴代甲烷为模型反应,系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响,结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段,深入地讨论了超强酸化对TiO〓的改性机理,阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

Bromoundecanoic acid was synthesized with 10-undecanoic acid and hydrobromic acid as raw materials.

以10-十一烯酸和溴化氢为原料合成11-溴代十一酸,考察了引发剂、溶剂、反应温度、后处理方法、熟化时间等因素对反应和产品的影响。

Bromoundecanoic acid was synthesized with 10-undecanoic acid and hydrobromic acid as raw materials. The effects of initiating agent, solvent, reaction temperature, the ways of disposal, ripening time etc. on the reaction and product were investigated.

以10-十一烯酸和溴化氢为原料合成11-溴代十一酸,考察了引发剂、溶剂、反应温度、后处理方法、熟化时间等因素对反应和产品的影响。

Alkanes can be chlorinated or brominated by treatment with chlorine or bromine in the presence of visible or uv light.

烷在可见光或紫外光照射下,用氯或溴处理才能氯化或溴化。

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