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溴化钾

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Take for the amount of test materials, precision that set, place beaker, unless otherwise specified, may be added 40ml of water and hydrochloric acid solution (1-2) 15ml, and then set on a magnetic stirrer, stirring allows the dissolved, together with potassium bromide 2g insert platinum - platinum electrode, it will insert the solution of the following buret tip is about 2 / 3, using sodium nitrite titration solution (0.1mol / L, or 0.05mol / L) rapid titration, side drops while stirring, to near point, Burette tip surface will be presented with a small amount of water leaching cutting-edge, lotion, and solution and continue titration slowly until the sudden deflection of galvanometer pointer, namely, titration end point.

取供试品适量,精密称定,放置烧杯中,除另有规定外,可加水40ml与盐酸溶液(1-2)15ml,而后置电磁搅拌器上,搅拌使溶解,再加溴化钾2g,插入铂-铂电极后,将滴定管的尖端插入溶液下面约2/3处,用亚硝酸钠滴定液(0.1mol/L或0.05mol/L)迅速滴定,边滴边搅拌,至近点时,将滴定管的尖端提出液面,用少量水淋洗尖端,洗液并溶液中,继续缓缓滴定,至电流计指针突然偏转,即为滴定终点。

In the medium of H2SO4 with KBr as the catalyst, the color of Cresol Red oxidized by iodate can be faded, and the degree of color fading is proportional to the concentration of iodine and the linear range of determination is 20 μg/25 mL~50 μg/25 mL.

在硫酸介质中、在溴化钾催化条件下,碘酸根对甲酚红有褪色作用,且褪色的程度与碘酸根的量有关,碘定量测定的线性范围为20μg/25mL~50μg/25mL,检出限为6。

The effects of the molar ratio of potassium bromide to cyclohexanol, the amount of water and concentrated sulfuric acid, and reaction time on the yield was investigated.

考察了溴化钾与环己醇摩尔比、水用量、浓硫酸用量、反应时间对产率的影响。

Bromocyclohexane was synthesized from potassium bromide and cyclohexanol in the prensence of concentrated sulfuric acid in water.

溴化钾和环己醇为原料,在浓硫酸存在条件下,以水为溶剂合成溴代环己烷。

Bromobutane was synthesized from potassium bromide and n-butyl alcohol by adding concentrated sulfuric acid in water. Various affecting factors were investigated.

溴化钾、正丁醇为反应原料,水为溶剂,滴加浓硫酸合成溴代正丁烷。

Bromooctane was synthesized from potassium bromide(by-product of synthesizing 2-hydroxy-4-octyloxybenzophenone) and n- octanol using concentrated sulfuric acid as a catalyst.

以生产2-羟基-4-正辛氧基二苯甲酮的副产物溴化钾和正辛醇为原料,浓硫酸为催化剂,合成了溴代正辛烷。

Benzyl bromide was synthesized from potassium bromide ,a by-product from synthesis of 2-hydroxy-4-n-octyloxybenzophenone(UV-531),and benzoic alcohol in the presence of concentrated sulfuric acid.

溴化钾作为工业生产2-羟基-4-正辛氧基二苯甲酮的副产品,在浓硫酸存在的条件下,与苯甲醇进行反应合成苄基溴。

The floatation separation behaviuor of Pd (superscript 2+) by KBr-cetyl pyridinium bromide system in the presence of NaNO3 and the conditions for the separation of Pd (superscript 2+) from other metal ions were studied.

研究了硝酸钠存在下,溴化十六烷基吡啶-溴化钾体系浮选分离钯的行为及与一些金属离子分离的条件。

The results show that Pd (superscript 2+) combines with KBr and cetyl pyridinium bromide into a ternary ion association precipitate2(PdBr4) in the aqueous solutions, which floated above the surface of water phase with clear interface.

结果表明,在水溶液中,Pd(上标2+)与溴化钾、溴化十六烷基吡啶形成不溶于水的三元缔合物2(PdBr4),此三元缔合物可浮于水相上层分成界面清晰的液-固两相。

The floatation rate of Pd (superscript 2+) reaches 100% when the concentrations of NaNO3, KBr and cetyl pyridinium bromide in solution are 0.05 g/mL, 3.0×10^(-2) mol/L, 5.0×10^(-4) mol/L(pH 4.0), respectively. Pd (superscript 2+) could be separated from Ru (superscript 3+), Al (superscript 3+), Cr (superscript 3+), Ni (superscript 2+), Ga (superscript 3+), Fe (superscript 3+) and Zn (superscript 2+) by floatation quantiatively. A method of flotation separation and enrichment of Pd (superscript 2+) was established.

当溶液中硝酸钠、溴化钾、溴化十六烷基吡啶的浓度分别为0.05 g/mL,3.0×10^(-2)mol/L,5.0×10^(-4)mol/L,在pH 4.0时,Pd(上标 2+)的浮选率达到100%,Pd(上标 2+)可与Ru(上标 3+),Al(上标 3+),Cr(上标 3+),Ni(上标 2+),Ga(上标 3+),Fe(上标 3+),Zn(上标 2+)定量分离,据此建立了浮选分离和富集Pd(上标 2+)的新方法。

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