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The company mainly engaged in bromine and brominated flame retardant epoxy production, the wholesale, retail and import and export business.

本公司主要从事溴系阻燃剂和溴化环氧的生产、批发、零售和进出口的业务。

A new type of difunctional initiator (benzyl dibromide, ethyl dibromoacetate) was proposed in this paper and used to synthesize poly based triblock copolymers such as PSt-PBA-PSt, PMMA-PBA-PMMA.

本论文提出一种新型ATRP双官能团引发剂(如α,α-二溴化苄、α,α-二溴乙酸乙酯),并用聚合反应速度法、GPC法、核磁分析法进行双官能度的验证,并通过两步聚合合成以聚丙烯酸酯为中间嵌段、苯乙烯或甲基丙烯酸甲酯为两端嵌段的ABA型三嵌段共聚物。

The effect of various conditions on the reaction, such as solvent, temperature, the amount of catalyst, the concentration of hydrobromic acid, oxygen/air and so on, was studied.

在此基础上,系统地考察了溶剂、温度、催化剂用量、氢溴酸的浓度、氧气/空气等因素对芳香化合物氧化溴化反应的影响。

Benzyl bromide was synthesized from potassium bromide ,a by-product from synthesis of 2-hydroxy-4-n-octyloxybenzophenone(UV-531),and benzoic alcohol in the presence of concentrated sulfuric acid.

溴化钾作为工业生产2-羟基-4-正辛氧基二苯甲酮的副产品,在浓硫酸存在的条件下,与苯甲醇进行反应合成苄基溴。

Bromination occur s selectively on the PMS methyl group, providing a reactive benzylic bromine functionality which is the key to Exxpro specialty elastomers′ vulcanization and modification versatility.

溴化反应选择性地发生在PMS的甲基基团上,提供活性苄基溴官能团,这也是Exxpro特种弹性体硫化和各种改性的关键。

Bromination occurs selectively on the PMS methyl group, providing a reactive benzylic bromine functionality which is the key to Exxpro specialty elastomers′ vulcanization and modification versatility.

溴化反应选择性地发生在PMS的甲基基团上,提供活性苄基溴官能团,这也是Exxpro特种弹性体硫化和各种改性的关键。

Bromcresol burple - hexadecyldimethyl benzyl ammonium bromide spectrophotometry was used in the determination of anion surface active agent in wastewater from lotion industry or sewage.

采用溴甲酚紫-十六烷基二甲基苄基溴化铵法测定洗涤剂工业的生产废水或生活污水中阴离子表面活性剂的含量。

The effects of different ratio of reacting material, concentration and temperature were studied in the bromination reactions.

研究了溴化反应中反应物物质的量比、反应物浓度、温度付溴代反应的影响。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应:1、二碘化钐促进下α,β-炔基酮的偶联环化反应,提供了一种制备多取代环戊二烯的新方法;2、二碘化钐促进下的二硫醚、二硒醚与α,β-炔基酮的Michael加成反应,为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法;3、二碘化钐促进下的二硫醚、二硒醚与α,β-炔基酮和醛、酮的Michael—aldol串联反应,提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法;4、烯丙基溴化钐与α,β-炔基酮的高度区域选择性的1,2-亲核加成反应;5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

From the starting material: propargyl alcohol, the building block was prepared easily by Jones oxidation, esterfication, bromination and selective trifluoromethylation.

第一部分:从丙炔醇出发,经过Jones氧化,甲酯化,顺式二溴化,再选择性地在酯基的β位实现三氟甲基化,合成了目标含氟砌块。

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