溴化的

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

A novel method for the determination of trace bromate in water is proposed which employ GC-ECD. The derivative process with acetylacetone is optimized.

研究了用GC-ECD测定水中痕量溴酸盐浓度的方法，优化了用工程丙酮作溴酸根衍生化试剂的反应条件。

It is characterized by that firstly, preparing silver bromiodide flake microcrstalline emulsion, then utilizing silver halide solution to corrode core of silver bromide to prepare the invented hollow silver bromiodide flake microcrystal whose form is triangle or hexagon and whose surface possesses small holes and pits, and the core of the microcrystal is silver bromide and its external layer is silve bromidiode, its iodine content is 1-10 mol%, and the light sensitivity of the emulsion is greatly raised.

首先制备溴碘化银薄片微晶乳剂，再利用卤化银溶剂使溴化银内核腐蚀，制备成的中空溴碘化银薄片微晶呈三角形或六边形，表面上有小孔和凹坑，微晶的内核为溴化银，外层为溴碘化银，其碘含量为1―10mol％；无论从色盲乳剂，还是经光谱增感乳剂的感光度都有大幅度的提高。

Novel sodium 2-2-(alkylaryloxy-alkylamidoethanesulfonates (m+nAr-T, m, n: carbon numbers; Ar: aromatic nucleus; T: taurine) with high purity were synthesized through bromization, esterification, Fries rearrangement, Pd-catalyzed hydrogenation, Williamson reaction, and acylation, et al, using carboxylic acid, phenol and taurine as starting materials. The structures and purities were characterized.

以羧酸、苯酚和牛磺酸为原料，通过溴代反应、酯化反应、Fries重排反应、催化氢化反应、Williamson反应以及催化酰胺化反应等过程，首次成功合成并表征了系列结构明确的高纯度N-酰基牛磺酸钠(m+nAr-T，m、n为烷基链碳数，Ar为芳环，T表示taurine)。

A sample-pretreated method of ether-extraction-precolumn-derivation was established, and the chromatographic conditions, which was used for determinating the derivant of extracted UDCA, were decided to be Hypersil C_(18) column(250×4.6mm, 10μm), acetonitrile-methol-0.005mol·L~(-1) phosphoric buffer-triethylamine(50:27:42:0.25, adjusted to pH3.0±0.1 by phosphoric acid) as mobile phase with detective UV wavelength at 247nm and column temperature at 35℃.

建立了乙醚提取-柱前衍生化血浆样品预处理方法，采用Hypersil C_(18)柱(250×4.6mm，10μm)，乙腈-甲醇-0.005mol·L~(-1)NaH_2PO_4缓冲液-三乙胺(50：27：42：0.25，磷酸调节pH3.0±0.1)为流动相的HPLC法，以溴苯乙酮为衍生化试剂，在247nm处测定家兔血浆中熊去氧胆酸衍生化产物。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2，3-b：3'，2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子：1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换；2用LDA对二噻吩并[2，3-b：3'，2'-d]噻吩去质子化作用。

The latter is hydrolyzed in the acidic conditions, then the recovered copolymer of EO and glycidol with multi pending hydroxymethyls is esterified with 2-bromoisobutyrylbromide to produce the ATRP macroinitiator with multi pending bromoisobutyryl groups .

共聚物poly的羟基与2-溴异丁酰溴进行酯化反应，得到侧链挂有2-溴异丁酸酯基结构的可以用于原子转移自由基聚合体系的大分子引发剂Poly_

Bromo-2-sulfolene (2) reacted with substituted benzoic acid salt s 3a～3c or alizarin yellow (3d) to give four novel allylic substitution products 4a～4d by esterification reaction, respectively.

以3，4-二溴环戊砜(1)为原料，在无水吡啶作用下发生消除反应，得到反应中间体4-溴-2-环戊烯砜(2)，再分别与一系列取代苯甲酸盐3a～3c以及茜素黄GG(3d)发生酯化反应，合成出4种新环戊烯砜衍生物4a～4d，并用IR，1HNMR，MS，元素分析等表征了它们的结构。

Under these conditions several aryl iodides bearing a wide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

Under these conditions several aryl iodides bearing awide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化储蓄型投资银条合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

And discuss some key point of integrated management system design, include hazard identification and risk assessment and risk control in the occupational health and safety management, the measure of satisfaction target of customer, the flawlessness of law system, the integration of the integrated management system and enterprise standardization system, unify lead institution and work orgnization, integreted internal audit and integrated management review.

同时，论述了一体化管理体系构建中的几个主要问题，包括职业健康安全管理中的危险源辨识、风险评价和风险控制、顾客满意度的科学监测、法律、法规体系的完善、一体化管理体系与企业标准化体系的有机结合、统一的领导机构和工作机构、一体化的内部审核和管理评审。

Deepwater Taranaki is investigated for its petroleum potential, using all available seismic data tied to shallow-water wells.

运用与浅水井相关的现有全部震波探测数据考察了深海区塔拉纳基盆地的油藏前景。