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In cases of doubt the changes following hydrogenation, bromination or other chemical attack upon the double bond can be studied.

在有疑问时可以研究双键的氢化,溴化或其他化学反应所引起的变化。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺;NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢;NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

Poly{[2-(4-biphenylamino)phenyl]phenylenevinylene} was prep-ared with 4-nitroanline which was coupled with p-xylene,throughreduction、idionization、Ullmann reaction、bromization、condensepolymerizationto get the final product.

本文提出了两条合成聚(2-芳基苯撑乙烯)的新路线,即聚{ 2-[4-苯基]苯撑乙烯}是以对硝基苯胺为原料,其与对二甲苯经改良的Gomberg-Bachmann反应偶联、再通过还原、碘化、Ullmann反应、溴化、缩聚反应得到。

In the ammonifying procedure, al cohol is used as solvent or phase transfer catalyst is added. The results sh ow that the reaction time decreases evidently and the yield of bactericide in creases further.

在产品制备的胺化步骤,作者采用乙醇作为溶剂或加入相转移催化剂,明显缩短了合成时间,使产品双烷基二甲基溴化铵的产率得到了进一步提高。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下,利用2,4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应,合成了中间体4-丙氧基-2-羟基二苯甲酮,将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

The molecular sieve is prepared in the steps: at the room temperature, hexadecyl trimethyl ammonium bromide is mixed and dissolved with the sodium hydroxide, and is added with TEOS in dropping way, and simultaneously added with Me metal salt water solution and lanthanum nitrate solution in dropping way; the pH value of the mixed solution is adjusted by acetic acid to be 10 to 11, and is mixed for 1 to 2 hours after being stabilized; the sol is moved into a polyfluortetraethylene bottle to be heated and crystallized for 2 days in the oven at the temperature of 100 DEG C; after filtering, washing and drying for nights, and being calcined in a muffle at the temperature of 550 DEG C for 3 to 7 hours, the dual-metal-atom improved MCM-41 mesoporous molecular sieve is obtained.

该分子筛的制备为室温下,将十六烷基三甲基溴化铵和氢氧化钠混合溶解,搅拌并滴加入TEOS,同时滴加入Me金属盐水溶液和硝酸镧溶液并搅拌,用乙酸调节pH值至10~11,稳定后搅拌1~2小时,溶胶转入聚四氟乙烯瓶中在100℃下烘箱水热晶化2天,经过滤、洗涤、干燥过夜,马弗炉550℃焙烧3-7h,得双金属原子改性MCM-41介孔分子筛产品。

Pentek filter systems offer multistage, reverse osmosis, in-line, countertop, shower and faucet filter options, while Pentek specialty products and processes such as ultraviolet, bromination, iodination, and radial flow iron reduction increase our ability to meet specialized needs.

pentek过滤系统提供了多级,反渗透,在网上, countertop ,淋浴和水龙头过滤选项,而pentek特种产品和新工艺,如紫外线,溴化,碘化,并径向流还原铁增加我们的能力,以满足特殊需求。

The results show that the optimal parameters of esterification are as follows: 4% of SO42-/ZrO2, molar ratio of methanol to litsea cubeba kernel oil 101, 68 ℃ of reaction temperature and 4 h of reaction time, the acid value decreases to 2.52 mg/g. Compared with the traditional acidic-catalyzed method, this method has the advantages of no acid proof equipment, easy to recycle catalyst and no acidic waste water emission. The optimal parameters of transesterification are as follows: 25 ℃ of reaction temperature, 0.5% of hexadecyl-trimethyl-ammonium bromide, 1% of NaOH, molar ratio of methanol to the oil 61 and 15 min of reaction time. The ester exchanging rate is 97.6%. This method adopts phase transfer catalyst and produces industry prospect, which has many advantages such as energy-saving and time-saving under room temperature.

研究结果表明,固体酸SO42-/ZrO2催化酯化反应的最佳条件为:油重4%的SO42-/ZrO2,醇油摩尔比为101,温度为68 ℃,反应时间为4 h,原油酸值降到2.52 mg/g;该法相对浓硫酸催化酯化法具有不需耐酸设备、催化剂易回收、无废水排放等优点;相转移催化酯交换反应的最佳条件为:温度为 25 ℃,0.5%的十六烷基三甲基溴化铵,油重1%的NaOH,醇油摩尔比为61,反应15 min,原油酯交换率达到97.6%;采用相转移催化技术,反应在常温下进行,大大减少了能耗,缩短了反应时间,具有的产业化前景。

Respectively proceeding with bromine complexing agent of anode, modified membrane and electrolytic additive of cathode, mainly referring to specific power of battery, ratio of self-discharge and zinc dendrite, this paper has studied the influences of different anode additive and modified membrane on specific energy of battery by means of charge and discharge curves, and the influences of electrolytic additive(NH4+, OP-10, TX-10 and dodecyl trimethyl ammonium bromide) on zinc dendrite by means of current-time curve and microscopic morphology observation.

本文分别从正极溴络合剂、隔膜改性和负极的电解液添加剂入手,以电池的比能量、自放电率以及锌枝晶生长情况为主要的性能指标,用电池充放电曲线等方法研究不同正极添加剂和隔膜改性对电池比能量的影响;用电流-时间曲线以及微观形貌观察等方法研究电解液添加剂(NH_4~+、OP-10、TX-10以及十二烷基三甲基溴化铵)对锌枝晶生长的影响。

Glucose oxidase was immobilised in two silk fibroin membranes prepared by using two neutral salts LiDr and CaCli as a reagent dissolving fibrion derived from Bombyx mori cocoon.

应用二种中性盐溴化红和氯化钙作为溶解蚕丝丝素的试剂,制成了二种固定化葡萄糖氧化酶丝素膜。

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