溴化的

This new methods can shun corrosiveness of liquid bromine or gas hydrogen bromide released during bromating reaction to the equipments and eliminate harmfulness to the operating worker and environment.

研究以溴化钠/溴酸钠完全代替传统的溴素作为溴代试剂合成了四溴双酚A，避免了使用溴素和因溴素作为溴代试剂时产生的溴化氢对设备、操作人员以及环境的危害。

Is now an annual production capacity of calcium chloride, bromide, DecaBDE, DBDPE three bromine phenol, Tetrabromobisphenol A, octabromodiphenyl ether, benzyl bromide, diphenyl ether, dibenzo ethane and other chemicals, 5,000 tons of bromine, hydrogen bromide by-product 5000 tons, the product export to Europe and Southeast Asia market, the company owns self import and export rights, and have passed the ISO9001: 2000 certification, is the most full-bromine chemical species, product quality, one of the best high-tech enterprises.

现已形成年产氯化钙，溴素，十溴二苯醚、十溴二苯乙烷、三溴苯酚、四溴双酚A、八溴醚、溴化苄、二苯醚，二苯乙烷等各类溴化学品5000吨，副产溴化氢5000吨，产品出口欧洲和东南亚市场，公司拥有自营进出口权，并已通过ISO9001：2000认证，是国内溴化学品种最全、产品质量最好的高新技术企业之一。

The main products are: calcium sulfate / calcium nitrate / calcium carbonate / copper sulfate / chloride, copper / zinc sulfate / nitric acid zinc / zinc chloride / potassium sulfate / potassium chloride / potassium bromide / potassium aluminum sulfate / potassium dihydrogen phosphate / 2 of potassium hydrogen phosphate / sodium bromide / sodium chloride / sodium nitrate / sodium fluoride / trisodium phosphate / sodium dihydrogen phosphate / disodium hydrogen phosphate / crystallization of sodium carbonate / anhydrous sodium carbonate / aluminum sulfate / nitrate aluminum / crystallization of aluminum chloride / aluminum hydroxide / nitrate Fe / hydrobromide / oxalic acid / boric acid / citric acid / barium chloride / Azone / magnesium sulfate / magnesium nitrate / magnesium chloride / ammonium chloride / ammonium sulfate / Bifluoride ammonium / ammonium aluminum sulfate / ferrous ammonium sulfate / ammonium dihydrogen phosphate / diammonium hydrogen phosphate / bromide / tetrabutylammonium bromide / chloride, nickel / nickel nitrate / sulfate nickel / cadmium chloride / cadmium sulfate / nitrate Cadmium / Cadmium Carbonate / Strontium / strontium nitrate / sulfuric acid manganese / manganese chloride / 50% manganese nitrate solution / stannous chloride / zinc chloride, such as crystallization of the four largest packing of chemical reagents AR and CP level.

主要产品有：硫酸钙/硝酸钙/碳酸钙/硫酸铜/氯化铜/硫酸锌/硝酸锌/氯化锌/硫酸钾/氯化钾/溴化钾/硫酸铝钾/磷酸二氢钾/磷酸氢二钾/溴化钠/氯化钠/硝酸钠/氟化钠/磷酸三钠/磷酸二氢钠/磷酸氢二钠/结晶碳酸钠/无水碳酸钠/硫酸铝/硝酸铝/结晶三氯化铝/氢氧化铝/硝酸铁/氢溴酸/草酸/硼酸/柠檬酸/氯化钡/氮酮/硫酸镁/硝酸镁/氯化镁/氯化铵/硫酸铵/氟化氢铵/硫酸铝铵/硫酸亚铁铵/磷酸二氢铵/磷酸氢二铵/溴化铵/四丁基溴化铵/氯化镍/硝酸镍/硫酸镍/氯化镉/硫酸镉/硝酸镉/碳酸镉/碳酸锶/硝酸锶/硫酸锰/氯化锰/50%硝酸锰溶液/氯化亚锡/结晶四氯化锌等大包装化学试剂的AR和CP级别。

A selective and mild PS-DIB/ionic-liquid immobilized 2, 2, 6, 6-tetramethyl-piperidin-4-ol-N-oxyl catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via the iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TeMPO catalyst, 4-(2, 2, 6, 6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from TeMPO and 1, 4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化，制得了负载型二乙酰氧碘苯作为氧化剂。2， 2， 6， 6-四甲基－N-氧自由基哌啶醇与1， 4-二溴丁烷反应生成4-溴丁氧基－2， 2， 6， 6-四甲基－哌啶－1-氧化物，再与N-甲基咪唑发生季铵化反应，生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2， 2， 6， 6-四甲基－N-氧自由基哌啶负载离子液体。

The synthesis of l-(4-acetylaminophenyl)-2-bromo-1-propanone was discussed, and the mechanism and possible factors were analyzed. Hence the routine was determined, in which l-(4-acetylaminophenyl)- 1-propanone was reacted with Bromine dissolved in ethanol, so that the a -bromination can be carried on, resulted in the yield of up to 70.4%.

探讨了1-(4-乙酰胺基苯基)-2-溴代-1-丙酮的合成方法，分析了反应机理和影响因素，确定将1-(4-乙酰氨基苯基)-1-丙酮溶解在乙醇中以溴的乙醇溶液进行α-溴化的合成路线，产率可达70.4％。

When bromine was used to bromization reaction with 4-acetyl-guaiacol,the product bromide incompletely or super bromide partial,and the selectivity was poor.

使用单质溴与4-乙酰基愈创木酚进行溴化反应时，产物溴化不完全，或者局部过量的溴化，且选择性较差。

Brominated butyl rubber was prepared by solution method,and its microstructures were characterized by 1H-NMR. It has three main microstructures,that is the unbrominated isoprene structure,the exomethylene allylic bromide structure (structure Ⅱ) and the bromomethyl olefinic structure (structure Ⅲ).

通过溶液法制备溴化丁基橡胶，并用核磁共振对溴化丁基橡胶的微观结构进行了分析，其中存在3种主要微观结构，即未溴化的丁基橡胶结构，溴代仲位烯丙基结构及溴代伯位烯丙基结构。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3，4-二溴马来酰亚胺进行N-甲基化反应合成3，4-二溴-N-甲基马来酰亚胺的同时，以碳酸二甲酯为甲基化试剂，对3，4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究；考察了1，4-二氮杂双环[2.2.2]辛烷，1，8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响，并应用碳酸二甲酯为甲基化试剂，合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

Also, the type of dispersion of four gasliquid-liquid systems: air-decane-aqueous solution of sodium sulfite and surfactant, airmixture of decane and dodecene-aqueous solution of rhodium complex, ligand, and surfactant, air-mixture of decane, dodecene and tridecyl aldehyde-aqueous solution of rhodium complex, ligand and surfactant, and air-mixture of decane and dodeceneaqueous solution of trisodium salt of tri (m-sulfophenyl) phosphine, and surfactant is determined by electric conductivity.

本文采用电导率测量的方法实验研究了空气—正癸烷—亚硫酸钠和十六烷基三甲基溴化铵水溶液、空气—正癸烷和1-十二碳烯混合物—铑膦络合物催化剂和十六烷基三甲基溴化铵水溶液、空气—正癸烷、1-十二碳烯和十三醛混合物—铑膦络合物催化剂和十六烷基三甲基溴化铵水溶液、空气—正癸烷和1-十二碳烯混合物—三间磺化苯基膦三钠盐和十六烷基三甲基溴化铵水溶液四个三相体系的液液分散特性。当有机相与水相体积比分别为7／3、1／1和3／7时，前三个体系均形成水包油型分散，并有稳定的乳状液生成。

Not only lead, but cadium, mercury, hexavalent chromium, polybrominated biphenyl, and polybrominated diphenyl ether flame retardants are limited as well.

不仅带领，但是cadium、水银、六价的铬、多溴化的联苯和多溴化的二苯基以太火焰阻化剂被限制。

And discuss some key point of integrated management system design, include hazard identification and risk assessment and risk control in the occupational health and safety management, the measure of satisfaction target of customer, the flawlessness of law system, the integration of the integrated management system and enterprise standardization system, unify lead institution and work orgnization, integreted internal audit and integrated management review.

同时，论述了一体化管理体系构建中的几个主要问题，包括职业健康安全管理中的危险源辨识、风险评价和风险控制、顾客满意度的科学监测、法律、法规体系的完善、一体化管理体系与企业标准化体系的有机结合、统一的领导机构和工作机构、一体化的内部审核和管理评审。

Deepwater Taranaki is investigated for its petroleum potential, using all available seismic data tied to shallow-water wells.

运用与浅水井相关的现有全部震波探测数据考察了深海区塔拉纳基盆地的油藏前景。