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The carbonylation of allyl bromide and hydrogenation of 1-octene were carried out under atmospheric pressure and at 40℃.

研究了它们在烯丙基溴的常压羰基化反应和1-辛烯的常压加氢反应中的催化性能。

However, the sulfonate CF3CFBrOCF2CF(CF3)O(CF2)2SO3Na reacted with sodium dithionite to give only the hydrodebromination product.

7的水解产物CF3CFBrOCF2CF(CF3)O(CF2)2SO3Na(11)与连二亚硫酸钠反应只得到氢化脱溴产物。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2,3-b:3',2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子:1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换;2用LDA对二噻吩并[2,3-b:3',2'-d]噻吩去质子化作用。

Results The synthesis condition was improved. The method of methane sulfonic acid/DL-methionine was found an ideal substitute of BBr3 for less cost. While using hydrobromic acid, the O-demethylation and hydrolyzation could be combined in one stage.

结果 优化了纳洛酮的合成工艺,甲磺酸/DL-甲硫氨酸法试剂价格低廉,可降低生产成本;而氢溴酸法不但试剂价格更低,还可将去氧甲基化和水解合并为一步反应,使新工艺的总收率提高到59.90%,产品质量符合中国药典。

A new monomer,4-hexanoxyl-4′-undecylene-[10]-acyloxyazobenzene was synthesized using the main materials:phenol,underlenic acid,1-bromo- n -hexane, p -nitrophenol,thionyl chloride,by the substitution,reduction,couping and diazotization methods.A new polymer was prepared by hydrosilation reaction of poly (methylhy-drosiloxane) with the monomer.

以苯酚、十一烯酸、正溴己烷、对硝基苯酚和二氯亚砜为主要原料,通过取代、还原、重氮化和偶合等反应,合成了一种新的液晶单体 4-己氧基-4′-十一烯-[10]-酰氧基偶氮苯,并与聚通过硅氢加成生成一种新的高分子液晶。

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Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.

老秋先生为中国秋阳翻译集团的董事长和孔子商学院的院长,致力于国学的研究和推广。