溴化乙烯

Ethylene dibromide and methyl bromide,liquid mixture, see

二溴化乙烯和溴甲烷的液态混合物，见

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

Sodium fatty alcohlo ether sulfate, S-80, fatty alcohol-polyoxyethylene ether and S-60 resulted in slow photodecomposition of rotenone in aqueous solution revealing a photo-extinction effect, sodium dodecylberzenesulfonate, tween-60, hexadecyl trimethyl ammonium bromide and poyl vinyl pyrrolidone made the photolysis of rotenone in aqueous solution fast showing an obvious photosensitized effect.

室内条件下研究了鱼藤酮水溶液存在不同表面活性剂时，鱼藤酮的紫外光降解，结果表明：脂肪醇聚氧乙烯醚硫酸钠、司本－80、长链脂肪醇聚氧乙烯醚和司本－60对鱼藤酮在水溶液中的光解速率表现出显著的光猝灭降解效应；十二烷基苯磺酸钠、吐温－60、十六烷基三甲基溴化铵和聚乙烯吡咯烷酮对鱼藤酮在水溶液中的降解表现出一定程度的光敏化作用。

Poly{[2-(4-biphenylamino)phenyl]phenylenevinylene} was prep-ared with 4-nitroanline which was coupled with p-xylene,throughreduction、idionization、Ullmann reaction、bromization、condensepolymerizationto get the final product.

本文提出了两条合成聚(2-芳基苯撑乙烯)的新路线，即聚{ 2-[4-苯基]苯撑乙烯}是以对硝基苯胺为原料，其与对二甲苯经改良的Gomberg-Bachmann反应偶联、再通过还原、碘化、Ullmann反应、溴化、缩聚反应得到。

The synthesis of poly{2-4-[bi(4-tetrabutylphenylamino]phenylphenylenenvinylene} was beginwith 4-tetrabutylbenzoic,through acylation、Hoffmann rearrangement、bromization、idionization、Ullmann reaction、bromization、condensepolymerization.

聚{2-[4-二(4-叔丁基苯胺基苯基]苯撑乙烯}是以对叔丁基苯甲酸为原料，经酰氯化、酰胺化、Hoffmann降解、碘化、Ullmann反应、溴化、缩聚反应得到。

This paper is studied on a new synthesis method of amino-modified organic silicone micro-emulsion of cationic style by one step with a silane-alkyl coupling,3-(2-aminoethyl)-aminopropyl methyl dimethoxy silane while opening-cyclo polymerization of the octa-methyl cyclo tetra siloxane,thus the optimal manufacturing conditions are determined by comparing test of their properties.

采用硅烷偶联剂氨乙基氨丙基甲基二甲氧基硅烷改性，八甲基环四硅氧烷开环聚合，探索一步合成阳离子型氨基改性有机硅微乳新方法，通过其性能测试得出其最佳工艺条件：反应温度：80℃，反应时间：3 h，十六烷基三甲基溴化铵用量：5%，脂肪醇聚氧乙烯醚用量：5%，预乳液滴加时间：2 h。

The leftover from bamboo processing was comminuted into bamboo fine powder, which was surface-treaded with a coupling agent of ethenyl tri (β-methoxyethoxy) silane; and then in the presence of initiator dicumyl peroxide, the powder was compounded with styrene-isoprene block copolymer/bromobutyl rubber blend to prepare a crosslinked vibration-absorbing rubber composite material.

将竹加工的边角料粉碎并用乙烯基三硅烷偶联剂处理，再与苯乙烯－异戊二烯嵌段共聚物和溴化丁基橡胶的共混物进行复合，在过氧化二异丙苯引发剂的作用下制得交联型橡胶吸振复合材料。

The molecular sieve is prepared in the steps: at the room temperature, hexadecyl trimethyl ammonium bromide is mixed and dissolved with the sodium hydroxide, and is added with TEOS in dropping way, and simultaneously added with Me metal salt water solution and lanthanum nitrate solution in dropping way; the pH value of the mixed solution is adjusted by acetic acid to be 10 to 11, and is mixed for 1 to 2 hours after being stabilized; the sol is moved into a polyfluortetraethylene bottle to be heated and crystallized for 2 days in the oven at the temperature of 100 DEG C; after filtering, washing and drying for nights, and being calcined in a muffle at the temperature of 550 DEG C for 3 to 7 hours, the dual-metal-atom improved MCM-41 mesoporous molecular sieve is obtained.

该分子筛的制备为室温下，将十六烷基三甲基溴化铵和氢氧化钠混合溶解，搅拌并滴加入TEOS，同时滴加入Me金属盐水溶液和硝酸镧溶液并搅拌，用乙酸调节pH值至10～11，稳定后搅拌1～2小时，溶胶转入聚四氟乙烯瓶中在100℃下烘箱水热晶化2天，经过滤、洗涤、干燥过夜，马弗炉550℃焙烧3-7h，得双金属原子改性MCM-41介孔分子筛产品。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发，通过与叠氮化钠和碘化物的一锅法1，3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。