溴代乙烯

Methods: The twelve volatile halogenated hydrocarbons (1, 1-dichloroethene, dicloromethane, trans-1, 2-dichloroethene, cis-1, 2-dichloroethene, chloroform-1, 1, 1-trichloroethane-1, 2-dichloroethane, tetrachloromethane, bromodichloromethane, dibromochloromethane, tetrachloroentene and bromoform) in drinking water were determined by headspace capillary gas chromatography.

采用顶空毛细管柱气相色谱法测定饮用水中1，1-二氯乙烯、二氯甲烷、反－1，2-二氯乙烯、顺－1，2-二氯乙烯、三氯甲烷、1，1，1-三氯乙烷、1，2-二氯乙烷、四氯化碳、一溴二氯甲烷、二溴一氯甲烷、四氯乙烯及三溴甲烷等12种挥发性卤代有机物。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章，我们研究了在水相介质中金属铟促进的烯丙基溴对1，1-二氰基-2-芳基乙烯的Michael加成反应，生成一个含碳碳双键和二个碳氮叁键的三官能团化合物，另外，金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联，生成砜。

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始，经过乙烯酮二硫代缩醛中间体，合成了两个5-氨基-1H-吡唑，以这个两个化合物为中间体，与芳香族和脂肪族α-溴代酮反应，而后经酸催化亚胺化互变异构后得到含咪唑并[1，2-b]吡唑甲硫醚类化合物6a-6g。

MCM-41, HMS, and MSU mesoporous silica molecular sieves were prepared via S〓I〓, S〓X〓I〓, S〓I〓, and N〓I〓 assembly pathway, in which cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether was used as the template, respectively. The mesostructures were characterized and confirmed by XRD, N〓 adsorption/desorption, TG, and high resolution TEM. The difference and relationship between these mesophases were also investigated.

分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓X〓I〓、S〓I〓和N〓I〓&超分子组装模式&合成了具有MCM-41、HMS和MSU结构的介孔SiO〓分子筛，用XRD、N〓吸附/脱附、TG和高分辩TEM等方法对它们的骨架和孔道结构进行了表征，并系统地比较了这几种介孔结构之间的区别与联系

Titanium incorporated mesoporous molecular sieves Ti-MCM-41, Ti-HMS, and Ti-MSU were synthesized through S〓I〓, S〓I〓, and N〓I〓 pathways using cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether as the structure-directing agents, respectively. The framework structure and the titanium coordination environment of these materials were characterized by XRD, N〓 adsorption/desorption, TG, TEM, FT-1R, DR UV-Vis, and ICP-AES. It was confirmed that the titanium was highly dispersed in the silica-based framework positions, and all samples were free of extra framework titanium impurities. The catalytic performance of these titanium containing mesoporous materials was investigated in the oxidation of styrene with aqueous H〓O〓 as the oxidant.

以TEOS和TBOT为硅源和钛源，分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓I〓和N〓I〓方式合成了含钛的介孔分子筛Ti-MCM-41、Ti-HMS和Ti-MSU，用XRD、N〓吸附/脱附、TEM、FT-IR、DR UV-Vis和ICP-AES等方法对它们的骨架结构、孔道结构以及钛原子的存在方式等进行了系统表征，结果表明钛原子以高分散的形式存在于以SiO〓为基本单元的介孔分子筛的骨架结构中，制备过程中未形成聚集态的骨架外金属氧化物物种。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。