溴乙烷

With half-trace law instead of constant law,bromine ethane not iodine ethane reacts to carbolic acid sodium in order to make benzene ether.

以半微量法代替常量法，用溴乙烷代替碘乙烷与苯酚钠反应制取苯乙醚。

Bis(1,2,3,4-tetrahydroisoquinoline-2-ylmethyl) HBr salt (K2) guest has been synthesized from 1,2,3,4- tetrahydroisoquinoline and ethylenedibromide. The self-assembly interaction models of cucurbit[8]uril (Q[8]) with this synthetic guest have been investigated by using 1H NMR technique, single crystal X-ray diffraction determination and theoretic calculation method.

以用1，2，3，4-四氢喹啉和二溴乙烷合成的二(2-亚甲基-1，2，3，4-四氢异喹啉)的溴化氢酸盐为客体，八元瓜环为主体，利用1H NMR技术，单晶X射线衍射方法以及理论计算等方法，考察了两者的自组装模式。

According to concerned papers ,we have chosen the way in which diquat dibromide is synthesized from 2,2-bipyridyls and ethylene dibromide. This paper makes further research into its technology, thus obtaining better synthesizing conditions.

本文在查阅大量文献的基础上，采用以2，2'-联吡啶和1，2-二溴乙烷为原料合成敌草快二溴盐的合成路线，并对其合成工艺进行了深入的研究，筛选出较佳的工艺条件。

Two kinds of di aniline derivative s connected with oxamethylene bridge or azamethylene bridge were synthesizied by condensation of o nitrophenol and ethylene dibromide (1,4 dibromobutane)or 4 chloro 3,5 dinitrobenzotyifluoride and ethylene diamine(1,6 hexandiamine)and consequent reduction.

由邻硝基苯酚和二溴乙烷以及由4－氯－3， 5－二硝基三氟甲苯和乙二胺为原料通过桥接、还原合成两类由氧亚甲基或氮亚甲基桥联的双苯胺衍生物。

A better understanding of the role of PPAR in insulin action system will be critical in developing more efficacious and safe agent s that act on PPAR and benefit patients with type 2 diabetes. The main content is followed: Synthesis and analysis of 1,3-dicarbonyl compounds. Make use of easily available cheap reagent such as 2-naphthol, 6-hydroxyquinoline, 1,2-dibromoethane, 4- hydroxybenzaldehyde, dimethyl malonate, 2-{4- [(2-napthoxy)ethoxyl] benzyl} malonates and 2-{4 [(1,2,3,4-tetrahydro-6 -quinolinoxy)ethoxyl] benzyl } malonates were synthesized through 6-8 steps in virtue of Williamson, Knoevenagel reaction, Pd/C catalyzed hydrogenation with mild conditions and high yield. The total yield of 40-50%.

本论文的主要内容和研究结果如下： 1，3-二羰基类化合物的合成及分析，采用2-萘酚、6-羟基喹啉、1 ，2二溴乙烷、对羟基苯甲醛、丙二酸二甲酯等常见易得试剂，利用Williamson反应、Knoevenagel反应、钯碳加氢等条件温和且收率高的方法，分别合成了2-{4- [(2-萘氧)乙氧基]苄基}丙二酸衍生物和2-{4 [(1，2，3，4-四氢-6-喹啉氧基)乙氧基]苄基}丙二酸衍生物两个系列8个化合物，经6-8步反应，总收率为40-50%，具有一定绿色化学特性。

The experimental result showed that three byproducts was formed and the optimal condition was as follows: the molar ratio of ethylene glycol, hydrogen bromide, and acetic acid was 1:1:1.3, when ethylene glycol was 1 mol, refluxed 5 h under the action of 100 mL toluene.

结果表明：较适宜的合成条件为乙二醇1 mol， n：n：n=1：1：1.3，在带水剂甲苯(100 mL)的作用下，回流反应5 h，约4 h后分两次追加0.12×2 mol醋酸酐，合成效果最好，产率可达到95%，反应副产2-溴乙醇及少量的1， 2-二溴乙烷、乙二醇二乙酸酯和二乙二醇二乙酸酯。

Then VIII reacted with hydrochloric acid and bromoethlane respectively to get tertiary ammonium chloride and quaternary ammonium bromide cationic surfactants, and the properties of cations were detected by the method of bromophenol blue.

然后再与盐酸和溴乙烷反应，合成铵盐和季铵盐型含氟阳离子表面活性剂，利用酸、碱性溴酚兰实验和铁氰化钾法分别对表面活性剂进行了定性和定量分析。

In the hydrocarbylation reaction,bromoethane was used instead of the expensive iodoethane with the yield 90% and the cost was reduced.

在烃化反应中，以溴乙烷代替价格昂贵的碘乙烷，收率达90％，降低了生产成本。

Deoxybenzoin(3) was prepareded by using the resorcinol and substituted phenylacetic as starting meterials in microwave-mediated.Then the compound(3) was reacted with acetic anhydride to produce(4).The compound(4) was hydrolyzed to convert compound(5) in the acid-mediated. The compound(5) was reacted with the 1,2-dibromo-ethane and 1,3-dibromo-propane in refluxed condition with acetone as solvent to give(6) or(7),respectively.Lastly,the title compounds were synthesized by refluxing(6) or(7) with 2-methyl-benzimidazole and potassium carbonate in acetone solution.

以取代苯乙酸和间苯二酚为起始原料，用微波辐射法合成脱氧安息香(3)，(3)与乙酸酐缩合生成2-甲基-7-乙酰氧基异黄酮(4)，(4)在酸性条件下水解生成相应的异黄酮(5)，化合物(5)分别与1，2-二溴乙烷和1，3-二溴丙烷反应生成(6)和(7)，化合物(6)和(7)再分别与2-甲基苯并咪唑偶合生成目标化合物。

In this thesis, the design, synthesis and application of substituted 1,8-naphthalimides and napthopyrones conjugated with uridine, substituted 1,3,5-triazine, 1,2-dibromoethane, ethyl bromoacetate have been studied.

本论文研究了取代l，8-萘酰亚胺和萘并吡喃酮与尿苷、取代均三嗪、二溴乙烷、溴乙酸乙酯偶合和双l，8-萘酰亚胺之间偶合的设计、合成及应用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。