溴乙烯

A new compound,3-_6-{4-(4-vinylene)pyridyl} stilbenyl}-N-ethylcarbazole was synthesized,and characterized by elemental analysis,IR,MS and ~(1)H NMR spectra.

报道一种新型的D-π-D-π-A结构的化合物：3-(4-溴苯乙烯基)-6-[(4-乙烯基吡啶)苯乙烯基]-N-乙基咔唑的合成。

MCM-41, HMS, and MSU mesoporous silica molecular sieves were prepared via S〓I〓, S〓X〓I〓, S〓I〓, and N〓I〓 assembly pathway, in which cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether was used as the template, respectively. The mesostructures were characterized and confirmed by XRD, N〓 adsorption/desorption, TG, and high resolution TEM. The difference and relationship between these mesophases were also investigated.

分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓X〓I〓、S〓I〓和N〓I〓&超分子组装模式&合成了具有MCM-41、HMS和MSU结构的介孔SiO〓分子筛，用XRD、N〓吸附/脱附、TG和高分辩TEM等方法对它们的骨架和孔道结构进行了表征，并系统地比较了这几种介孔结构之间的区别与联系

Titanium incorporated mesoporous molecular sieves Ti-MCM-41, Ti-HMS, and Ti-MSU were synthesized through S〓I〓, S〓I〓, and N〓I〓 pathways using cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether as the structure-directing agents, respectively. The framework structure and the titanium coordination environment of these materials were characterized by XRD, N〓 adsorption/desorption, TG, TEM, FT-1R, DR UV-Vis, and ICP-AES. It was confirmed that the titanium was highly dispersed in the silica-based framework positions, and all samples were free of extra framework titanium impurities. The catalytic performance of these titanium containing mesoporous materials was investigated in the oxidation of styrene with aqueous H〓O〓 as the oxidant.

以TEOS和TBOT为硅源和钛源，分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓I〓和N〓I〓方式合成了含钛的介孔分子筛Ti-MCM-41、Ti-HMS和Ti-MSU，用XRD、N〓吸附/脱附、TEM、FT-IR、DR UV-Vis和ICP-AES等方法对它们的骨架结构、孔道结构以及钛原子的存在方式等进行了系统表征，结果表明钛原子以高分散的形式存在于以SiO〓为基本单元的介孔分子筛的骨架结构中，制备过程中未形成聚集态的骨架外金属氧化物物种。

Treatment of polystyrene-supported selenium ,bromide with lithium acetylides afforded polystyrene-supported selenoacetylene, which reacted with dicyclohexylborane giving a way for stereoselective synthesis of polymer-supported- vinylic selenides .

聚苯乙烯负载硒溴与炔基锂反应合成聚苯乙烯负载炔基硒醚，再与二环己基硼烷反应制得聚苯乙烯负载顺式烯基硒醚；此负载型烯基硒醚在NiCl2(PPh3)2存在下与格氏试剂发生偶联反应，提供了一种有效的-1，2-二取代乙烯的固相有机合成方法

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。