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Just prior to the analysis, prep a re the test solution by adding 0.5ml of the bromophenol blue indicator solution to each 100ml of the aqueous acetone solution and titrating with 0.01 N HCl or 0.01 N NaOH until the test solution is just yellow in color.

分析前准备好测试溶剂,100ml含2%水的丙酮加到锥形瓶中,加0.5ml 1%溴酚蓝水溶液指示剂,用0.01N NaOH溶液滴定至绿色或蓝色,然后用0.01N 盐酸标准溶液滴定至刚好呈黄色

In the second part of the thesis, we discussed a L-proline-catalyzed direct Aldol reaction between L-amino acid-derived N,N-dibenzyl -amino aldehydes 15 and acetone, cyclopentanone or hydroxyacetone, which afforded (-amino--hydroxy- or (-amino-,(-dihydroxy-ketones in good to excellent yields (up to 94%) and diastereoseletivities (up to 94.9%).

发现许多情况下,反应的产率和de值超过90%。接着,在碱性条件下,我们将L-亮氨酸衍生的N,N-二苄基--氨基醛15g与羟基丙酮反应得到的主要产物(,-二羟基-γ-氨基酮171d与次溴酸钠反应,得到了具有抗肿瘤活性的天然产物PM-94128的氨基酸片断184。

Ab initio and density functional theory (B3LYP) in G98 were employed to study the following four direct aldol reactions between acetone and isobutyraldehyde or 3,3-dimethylbutyric aldehyde or benzaldehyde or 4-bromo-phenyl aldehyde catalyzed by-proline .

中文摘要:本文采用G98程序包中的从头计算方法和密度泛函方法计算研究了-脯氨酸催化丙酮与异丁醛、3,3-二甲基丁醛、苯甲醛及对溴苯甲醛的不对称直接羟醛缩合反应,共计四个反应体系。

In the reaction, industrial chlorinating agent and brominating agent with low cost and easy acquisition are used as oxidants to oxidize the ethyl lactate into the ethyl pyruvate.

反应中使用了廉价易得的工业用氯化剂、溴化剂作为氧化剂,将乳酸乙酯氧化为丙酮酸乙酯。

For the bargellini reaction, acetone and chloroform was used instead of a--bromobutyrate to cut the cost.

同时,以丙酮和氯仿代替a-溴代异丁酸酯,显著降低生产成本。

A novel Belousov-Zhabotinskii type oscillating reaction was observed in a closed serine-BrO^-~3-Mn^2^+- H2SO4 system(Ser-BZ system), which exhibited the followign characteristics:(1)Although Ser is unable to be brominated, the sustained oscillations could still be observed in the above system under batchreactor conditions even in the absence of either acetone or inert gas flow.(2)The present oscillations displayed extremely short induction period(0) and very few oscillation number(1).(3)Cl^-, acrylonitrile, or Br^- could effectively inhibit the oscillations. However, in the case when enough Ag^+ was addedinto the system to completely inhibit the oscillations in , the oscillations on the Pt-electrode could still be observed.

首次报道了间歇釜中以丝氨酸-BrO^-~3-Mn^2^+-H2SO4为体系的新型BZ类振荡反应,其特征如下:(1)虽然Ser不能发生溴代反应,但即使在无丙酮或惰性气体流时也能在间歇釜中观察到持续振荡;(2)振荡诱导期极短(~0),振荡次数较少(1次);(3)振荡反应受到Cl^-,Br^-,丙烯腈等的抑制;但当加入足够量Ag^+使的振荡抑制后,仍可在Pt电极上观察到振荡现象。

The phosphines such as 〓, dppm bis(diphenylphosphinemethane, dppebis(diphenylphineethane and dppp bis(diphenylphosphinrpropaneare chosen for study. The chloro alkane, bromide alkane and acetone arechosen as solvents.

选择有机单膦〓和双膦配体dppm二(二苯基膦甲烷、dppe二(二苯基膦乙烷、dppp二(二苯基膦乙烷与〓反应,选择氯代烷、溴代烷和丙酮为反应溶剂。

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