溴

Secondly, the reaction of crotyl bromide and carbonyl compounds promoted by dysprosium were studied. The γ-adduct of crotyl was mainly obtained in the reaction of ketone and ester. While the α-and γ-adduct mixture were obtained in the reaction of aldehyde.

其次，还研究了镝促进下巴豆基溴与羰基化合物的反应，酮和酯主要得到巴豆基γ-位进攻的产物，而醛则得到α与γ位进攻的混合产物。

As to the catalytic coupling of aryl bromides, when triphenylphosphine as ligand and malononitrile as subtracts, their isolated yields were generally in 72-88%; While using cyanoacetate instead of malononitrile, the yields were in 67-84%.

当采用常见的三苯基膦为配体、对取代溴苯而言，以丙二腈为底物时，偶联产物的分离产率一般都在72-88％之间；以腈基乙酸乙酯为底物时，分离产率在67-84％之间。

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始，经过乙烯酮二硫代缩醛中间体，合成了两个5-氨基-1H-吡唑，以这个两个化合物为中间体，与芳香族和脂肪族α-溴代酮反应，而后经酸催化亚胺化互变异构后得到含咪唑并[1，2-b]吡唑甲硫醚类化合物6a-6g。

In the second part of the thesis, we discussed a L-proline-catalyzed direct Aldol reaction between L-amino acid-derived N,N-dibenzyl -amino aldehydes 15 and acetone, cyclopentanone or hydroxyacetone, which afforded (-amino--hydroxy- or (-amino-,(-dihydroxy-ketones in good to excellent yields (up to 94%) and diastereoseletivities (up to 94.9%).

发现许多情况下，反应的产率和de值超过90%。接着，在碱性条件下，我们将L-亮氨酸衍生的N，N-二苄基--氨基醛15g与羟基丙酮反应得到的主要产物(，-二羟基-γ-氨基酮171d与次溴酸钠反应，得到了具有抗肿瘤活性的天然产物PM-94128的氨基酸片断184。

The results show that the debromination rate of 2-bromophenol can be accelerated significantly by increasing temperature and adding alkaline materials.

结果表明：升高温度和添加碱性物质能显著提高反应的脱溴率。

Kinetics analysis showed that the photochemical reaction kinetics of 4,4'-DI3B was pseudo-first order reaction in n-hexane solution, and the reaction was a process of debromination step by step.

动力学分析表明，4，4'-DBB在正己烷中的光化学反应为准一级反应，是一个逐步脱溴的反应过程。

Hence, pyrolytic debromination experiments were conducted to reveal the effect of blending calcium carbonate (CaCO3) with the wPCB in pyrolysis.

为此采用混合热解吸收技术，着重研究碳酸钙与酚醛型线路板混合热解的脱溴过程。

The paper reviews the progress of ionic liquids as microwave mediums or catalysts in the fields of organic synthesis, mainly including cyclization, nucleophilic substitution, ring closing metathesis, acylation, rearrangement, polymerization, coupling, oxidation and reduction as well as selective debromination, etc.

本文综述了以离子液体为反应介质或催化剂的微波辅助技术在多种类型有机反应中的研究成果，主要包括了环合反应、亲核取代反应、金属复分解反应、酰化反应、重排反应、聚合反应、偶联反应、氧化还原反应和选择性脱溴反应等。

The paper reviews the progress of ionic liquids as microwave medium or catalyst in the fields of organic synthesis, mainly including cyclization reation, nucleophilic subsitution reaction, metathesis reaction, acylation reation, rearragement reaction, polymerization reaction, coupling reaction, oxidation and reduction reaction as well as selective debromination reaction etc.

本文综述了以离子液体为反应介质或催化剂的微波辅助技术在多种类型有机反应中的研究成果，主要包括了环合反应、亲核取代反应、金属复分解反应、酰化反应、重排反应、聚合反应、偶联反应、氧化还原反应和选择性脱溴反应等。

In biodegradation study, debromination of 4-monobrominated diphenyl ether (4-BDE) is investigated with aerobic and anaerobic sludges. This also is the first report demonstrating microbaially mediated biodegradation of 4-BDE under aerobic conditions. 4-BDE biodegraded within 11 days by 68 % and 83 % with toluene and diphenyl ether, respectively, as second carbon sources to stimulate biodegradation.

本研究之生物降解部分，以酒厂之好氧及厌氧活性污泥及经PCE驯化之厌氧活性污泥能有效降解一溴联苯醚(4-mono-BDE， 4-BDE)，结果证实了在好氧情况下微生物降解PBDEs的可行性，而补助碳源的添加有助於提高降解速率，在甲苯或联苯醚存在的情况下，11天内4-BDE分别降解了68 %及83 %。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新