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The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

L and 72L liquefied propane cylinders of liquefied propylene; 18L, 26L, 28L, 35L, 70L, 80L, 105L, 118L Series liquefied bromomethane cylinders; 400L, 800L liquid chlorine, liquid ammonia cylinder; 720L cylinders and three sulfur 926L, 1180L large size cylinders; 40L, 60L, 82L, 118L, 400L, 800L, 926L, F21, F22, R32, R134a refrigerant and other agents and other specifications of industrial gas cylinders.

b。 12.2L、40L液化丙烷和72L液化丙烯钢瓶;18L、26L、28L、35L、70L、80L、105L、118L系列液化甲烷钢瓶;400L、800L液氯、液氨钢瓶;720L三氧化硫钢瓶和926L、1180L大规格钢瓶;40L、60L、82L、118L、400L、800L、926L、 F21、F22、R32、R134a等各种制冷剂及其它规格工业气瓶。

2 Mm were compared using the Lipophilic Hydrophilic Ratio concept which was defined on the basis of the Washburn equation, and their surface free energy component s were also estimated using the Washburn equation and van Oss-Chaudhurry-Good theory with n-hexane,α-bromonaphthalene, formamide and water as probe liquids.

2mm无烟煤、锰砂和石英砂滤料的润湿性;同时以正己烷、1-萘、甲酰胺和去离子水为探针液,用Washburn方程和vanOss-Chaudhurry-Good理论对滤料表面自由能成分进行了估算。

This thesis studied a novel CL enhancer, bromophenol blue, in the system of Luminol-H_2O_2-HRP, and proposed a new enhanced CL system of Luminol-H_2O_2-HRP-BPB.

本工作研究了新型增强剂酚兰对Luminol-H_2O_2-HRP化学发光反应的增强作用,提出了Luminol-H_2O_2-HRP-BPB化学发光新体系。

GC-MS analysis suggested the formation of bromophenol and nitrophenol.

对产物进行GC-MS分析,表明有苯酚和硝基苯酚生成。

Methods: Agar gel immunodiffusion test was conducted twice in agar gel plate with 0.1 mg/L bromophenol blue, first, agar gel immunodiffusion test was carried out with AFP-HSP70 cross-linking protein and AFP antibody, then the test was conducted again with the processed precipitation band and HSP70 antibody.

在含0.1 mg/L酚蓝的凝胶琼脂板上,进行2次琼脂免疫扩散实验,第1次是用AFP-HSP70交联蛋白和AFP抗体进行琼脂免疫扩散,把扩散后沉淀带处理后再次和HSP70抗体进行琼脂免疫扩散。

Color reaction was performed in organic solution-salt solution biphasic system. The organic solution was 1,2-Dichloroethane-Isoamyl alcohol mixture (V/V=96:4) added Bromophenol blue (per 100 mL added 0.05 g). The salt solution was 55%K2HPO4 aqueous solution added Na3CO3 (per 100 mL added 14 g), under the temperature of color reaction between 12℃ to 25℃.

显色反应在有机溶液-盐溶液两相体系中进行,有机溶液为每100 mL 1,2-二氯乙烷-异戊醇混合溶液(体积比96:4)加入0.05 g酚蓝,12~25℃显色反应条件下,盐溶液为每100 mL 55%K2 HPO4水溶液加入14 g Na2CO3。

In this paper, an efficient and easy biological screening method based on the sensitivity to lovastatin of Neurospora crassa was built to deal with the mutant strain rudely by UV mutation. A high-level strain was screened in the shaking flask culture incorporating with TLC and HPLC. A comparison between this two methods also was originally discussed while identifying dyeing using bromophenol blue as the better treatment of TLC, and offering a kind of simple, practical, fast and economical determination qualitatively and quantitatively.

本文有鉴于此,通过紫外诱变处理,并基于粗糙脉孢酶对洛伐他汀的生物敏感性,对诱变菌株进行了初筛;同时,采用摇瓶培养,结合TLC和HPLC的分析方法,复筛出一株高产菌株;对复筛过程两种分析方法分别进行了初步探讨,比较其优劣,确定TLC法经酚兰显色剂显色处理为较佳方式;从而,建立了一套简单、实用、快速、经济且有效的洛伐他汀生产菌诱变筛选方法。

Just prior to the analysis, prep a re the test solution by adding 0.5ml of the bromophenol blue indicator solution to each 100ml of the aqueous acetone solution and titrating with 0.01 N HCl or 0.01 N NaOH until the test solution is just yellow in color.

分析前准备好测试溶剂,100ml含2%水的丙酮加到锥形瓶中,加0.5ml 1%酚蓝水溶液指示剂,用0.01N NaOH溶液滴定至绿色或蓝色,然后用0.01N 盐酸标准溶液滴定至刚好呈黄色

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。