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When ATRP of styrene was investigated with 1-phenylethyl bromide/benzyl a,a-dibromide mixture as initiator, the GPC chromatogram shows two elution peaks and the molecular weighs of the peaks are approximately in a 2/1 ratio. It suggests that benzyl dibromide is a difunctional initiator of ATRP of styrene. The analysis of end group using 1H-NMR also proves the result above.

采用1-苯基乙烷/α,α-二化苄混合引发剂进行苯乙烯的ATRP反应时,所得聚苯乙烯的GPC谱图为双峰,分子量相差一倍,初步证明了α,α-二化苄引发苯乙烯ATRP反应时是双官能引发剂,并用~1H-NMR对聚合物结构进行分析,进一步证明了α,α-二化苄引发苯乙烯ATRP时是双端同时增长的。

①postoperative pain after hemorrhoidectomy can be safely and effectively controlled by Acuepoint inject of lappaconitine hydrobromide ②Using the Ashi-points-injection of lappaconitine hydrobromide after hemorrhoidectomy can reduce the pain for a longtime ③Combined with Yaoshu-point-injection can enhance the anaesthetic effect at the day of surgery④The edema at anal margin can be reduced by using of Ashi-points-injection of lappaconitine hydrobromide

①穴位注射氢酸高乌甲素对痔术后镇痛是安全而有效的;②术毕时使用氢酸高乌甲素阿是穴注射具有术后长效镇痛作用;③联合使用氢酸高乌甲素腰俞穴注射可增强手术当天的镇痛效果;④氢酸高乌甲素穴位注射具有防止痔术后肛缘水肿的作用。

Photodissociation of alkyl bromides has been a popular area of investigation, in view of their ozone depletion potential and of the fundamental interest in photodissociation dynamics.

代烷烃的光解近年来已成为十分活跃的研究领域,一方面是由于代烷烃的光解产物对臭氧层的破坏,另一方面是由于代烷烃光解研究的理论意义。

Seven central depressants,including chloral hydrate,potassium bromide,sodium bromide,cal- cium bromide,alcohol,amytal and chloretone, were studied for their effects on the intraperito- neal toxicity of tartar emetic and sodium stibo- gluconate in mice.

1。关于吐酒石与葡萄糖酸锑 V 钠对小白鼠的致死作用,我们探索了一些中枢抑制药与兴奋药的影响。所试的抑制药有水合氯醛,化钾,化钠,化钙,酒精,安眠妥与三氯叔丁醇七种。兴奋药有苯甲酸钠咖啡硷与士的宁二种,以及咖合剂。2。

Thionyl chloride and bromine were used as raw materials to synthesize α-bromo isobutyric acid chloride which will substitute α-bromo isobutyric acid bromine.

研究了以异丁酸、氯化亚砜和液为主原料合成α-代异丁酰的替代产品———α-代异丁酰氯的工艺。

The possible pathway of ABAS degraded by Zoogloea HP3 was that ABAS was first cleaved to produce o-phthalic acid and products. The former was further degraded and the composites of the latter were 2-amino-3-hydroxyl-5bromobenzenic sulfonic sodium and 2, 3-dihydroxyl-5-bromobenzenic sulfonic sodium.

动胶菌HP3作用下胺酸可能的降解途径为蒽醌环开裂生成中间产物邻苯二甲酸,邻苯二甲酸被进一步降解;胺酸降解后的最终产物为2-氨基-3-羟基-5-苯磺酸钠和2,3-二羟基-5-苯磺酸钠。

One synthetic strategy started fromγ-butyrolactone 38, from which a cyclohexadiene intermediate 30 was prepared in an overall yield of 44% in a 7-step procedure after y-butyrolactone underwent a-bromination, dehydrobromination, Diels-Alder reaction, aminolysis, benzylation, bromination and dehydrobromination, with the key step being the Diels-Alder reaction under harsh condition.

其中一个路线从γ-丁内酯38开始,连续经过α-化、脱化氢、Diels-Alder反应、胺解、苄基化、化和脱化氢共7步反应,制备了一个环己二烯衍生物30,总产率44%,关键步骤是高温高压下Diels-Alder反应。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分,我们研究了α,α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应,发现全氟苄基碘或及α,α一二氟苄基在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐;全氟苄基亚磺酸盐与氯气或反应可生成全氟苄基磺酰氯或磺酰;在烯烃存在下,全氟苄基碘则与烯烃发生加成反应,生成相应的1:1加成产物;在三价醋酸锰的作用下,部分芳香化合物如茴香醚,二甲氧基苯,吡啶,喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应,反应表现出一定的区域选择性,产率良好。

When bromine was used to bromization reaction with 4-acetyl-guaiacol,the product bromide incompletely or super bromide partial,and the selectivity was poor.

使用单质与4-乙酰基愈创木酚进行化反应时,产物化不完全,或者局部过量的化,且选择性较差。

The research progresses in degradation technologies of benzene or some of its derivatives in water are reviewed.The macroscopical reaction mechanism of HNO2(NO2-)and C6H5Br in aqueous solution has been studied.Different influence factors have been discussed,including different pH condition,initial concentration,irradiation time,different anions and the optimization of experimental conditions.By using liquid chromatography,the degradation rate of bromobenzene has been qualitatively analyzed.The concentration variations of Br~and NO2- have been analyzed by using ion chromatography.

本文介绍了苯及其衍生物对水环境所造成的污染和危害,研究了365nm光照下HNO2(NO2-)与C6H5Br混合溶液的宏观反应过程,初步考察了混合体系中苯的降解及衰减行为,较为系统地探讨了影响苯降解过程的各种影响因素,包括溶液的pH值、初始浓度、光照时间、不同离子的影响以及实验条件的优化,并利用液相色谱法进行定量研究苯的降解率,利用离子色谱法分析检测实验过程中离子和亚硝酸根离子的变化。

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