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Liquid crystal ; smectic phase ; small angle X-ray.

液晶;近晶相;小角X光

The compounds of series D can't exhibit any mesophases, but the compounds of series A and B possess a polar antiferroelectric smectic phase. The temperature range of B2 phase is the widest for the compound AC5 among them, up to 104.6℃.

研究结果显示系列D并没有液晶相形成,但系列A和系列B都会形成具反铁电性的B2相,其中化合物AC5的B2相温宽最宽,可达104.6℃。

On the other hand, we study the vertical alignment for a ferroelectric liquid crystal that has fast response, high contrast, and analog gray scale capability. In contrast to the conventional rubbing alignment in a planar geometry, smectic layers arrange themselves parallel to the substrates, and thus extremely uniform alignment of molecules in large area is naturally achieved.

此外,本论文也尝试把FLC做垂直配向,讨论其静态与动态光学现象,并观测其光学图样与模拟结果作一比较;FLC在垂直配向不同於水平配向会有缺陷的产生,所以会有很好的暗态表现,其暗态好坏与否与FLC材料的螺旋距和液晶盒的间隙有相当大的相依性。

The structures of two ordered smectic phases of HPAP liquid crystal, SmB and SmB was studied by small angle X-ray diffraction (Position-Sensitive-detec- detector method).

本文应用小角X光衍射研究了HPAP液晶所呈现的两种有序近晶相SmE和SmB结构。测量了近晶相的层厚及其与温度的关系。

Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.

手性2-甲基-1,4-丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体,以3-甲基-3-丁烯-1-醇为原料利用改进的不对称硼氢化-氧化反应,成功地合成了-2-甲基-1,4-丁二醇以及其2种手性衍生物:-2-甲基-4-四氢吡喃氧基-1-醇和-2-甲基-4-四氢吡喃氧基丁醛。

By tailoring the scale between hydrophilic region and lipophilic region, smectic, columnar and cubic mesophases were observed in compounds I-F and II-F. By changing the length of the lateral chains, a series of new columnar phases and a non-conventional semctic phase were obtained in III-F.

通过调节亲水部分和亲脂部分的比例,在I和II-F中观察到了从近晶层相到柱相再到三维立方相的液晶相序列;在波拉分子III-F中通过改变侧链的长度,获得了一系列柱相及新型层相。

The polymerization reactivity of the monomers increases with an increase in the spacer length and only those monomers and polymers with a flexible spacer≥(CH_2)_6 show liquid crystalline with their mesophases being smectic A.

随着柔性间隔基增长,单体的反应活性也相应增加,而且只有当柔性间隔基≥6时聚合物和单体才呈现出近晶A液晶态。

Mesogenic compound M5 exhibits nematic and dendrimer Dl reveals cholesteryl and smectic E liquid crystalline state. Phase behavior of Dl in LC state is K70Chl88I185Ch58S_E48K.

介晶基元化合物(M5)显示向列相,树状物D1显示胆甾相和S_E相。D1的液晶相相行为是K70Ch188I185Ch58S_E-48K。

The spherulitic texture of nematic phase and good nematic liquid crystalline behavior can be observed by HSPM. Since Ia hasn't reported, this is the article′s innovation.

结果表明,合成了预期产物,Ia和SEM都具有向列相的球粒织构,而MBMI具有纹影织构,但都呈现较好的热致液晶行为。

On the other hand, both the mystic Cross ("Staurus"= X = the letter tav of old; see Jewish Encyclopedia, i. 612b; Irenus, lci 2,§ 3; Justin,"Apology," i. 40; and Jol, lcp 147) and the enigmatic primal "av laav," or "avkav," taken from Isa.

在另一方面,无论是神秘的交叉(& staurus &=为x =信tav旧;见犹太百科全书,一612b ; irenus ,国际狮子总会第2 ,第3条;贾斯汀,&道歉&,一, 40 ;若埃尔阿,液晶聚合物147 )和神秘的原始& av laav &,或者说& avkav ,&取之于伊萨。

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