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液态结晶

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The second variation type is called reversion evolution type, which represents the liquid segregation mainly with vapour-liquid fractional distillation. The third variation type is called saltatory variation type, which is formed from the liquid segregation mainly with immiscibility.

称为正向演化类型,是结晶分异结果;②称为反向演化类型,代表气液分馏为主的液态分离;③称为演化突变类型,是不混溶为主的液态分离形成。

By employing such a method, 5 series of elastomers, including natural rubbers, elastomeric polyester fibers and ethylene-octene, ethylene-methyl acrylate as well as SIS triblock copolymers, were investigated with the purpose of studying elongation induced phase structure and mobility changes of the samples. For NR samples, it was demonstrated that there exists a small amount of crystals at RT even for unelongated samples. For both NR and the soft segment of PEE, with the increase of elongation ratio, the elongation-induced crystallinity increases almost linearly in a certain region of R, in accord with the increase of the lamellar thickness of the crystals; The behavior of ethylene copolymers, in terms of elongation induced morphorpholgy changes, are quite different from NR and PEE. The crystals are found to be gradually destroyed with the increase of R, with accord with the decrease of the lamellar thickness; The motional behavior of the soft segment of SIS, changes from "liquid" to "solid", in terms of 13C NMR spin-lattice relaxation.For many of the aformented samples, the dependence of 13C spin-lattice relaxtion time T1 on R are different for different groups, indicating that the changes of mobility at MHz frequency region with elongation are different for different groups.

通过对天然橡胶、聚醚酯嵌段共聚物、乙烯-辛烯共聚物、乙烯-丙烯酸甲酯共聚物、SIS等高分子弹性体样品聚集态结构和分子运动的研究,获得了一些新的实验结果,如:给出了确切的实验证据,证明了室温下未拉伸的天然橡胶样品中存在着微量的结晶;发现随着拉伸比增加,天然橡胶及聚醚酯样品的软段部分会出现拉伸诱导的结晶,且结晶度在一定范围内呈现近似线性的增加,所形成晶片的厚度也随之逐渐增加;而乙烯共聚物随着拉伸比的增加,原有的结晶会被逐渐破坏,晶片厚度逐渐变薄,结晶中的缺陷逐渐增加;随着拉伸比的增加,SIS中PI软段部分的核磁共振弛豫行为会出现从液态到固态的转变等;在对上述多个体系的研究中,还发现不同基团的自旋-晶格弛豫时间随着拉伸比呈现不同的变化趋势,表明不同基团的高频运动随拉伸比增加有不同的变化规律。

Under such a solidification condition that the growth rate is low and the temperature gradient ahead of the solidi fication front is steep, a large amount of α-Al nuclei can be produced by peritectic reaction, during which only metastable Al〓Zr particles or very fine equilibrium Al〓Zr particles rather than larger equilibrium Al〓Zr partiles are involved.

在低的生长速度和高的界面前沿温度梯度条件下,结晶前沿Al〓Zr粒子与液态铝发生包晶反应(只涉及亚稳Al〓Zr或尺寸极小的平衡Al〓Zr,而不涉及尺寸较大的平衡Al〓Zr)产生大量α晶胚,α晶胚呈球面生长,最终形成等轴非枝晶形态。

Through survey carefully, we find that if depend on pouring velocity、structural shape of SEN entocoele、angle slope of outlet 、depth of infusion together to make the liquid steel in model revolution in an order flow then it can utilize this kind of energy completely.

通过仔细研究发现,只要依靠浸入式水口内腔结构形状、出口倾角、浸入深度以及浇注速度就可以使方坯连铸结晶器内钢水为旋转的涡流流动,把液态金属的流动动能利用起来。

The intensity of pressure is the most markable factor that influence the casts mechanical properties and microstructure. When its value exceeds 40MPa, the disfigurement such as shrinkage porosity can be effectively reduced . when its value exceeds 120MPa, the pressure obviously influence the crystal performances of liquid metal also, and compact homogeneous exiguous equiaxial crystal can be obtained. Pressure can also increase the solubility of Cu in a -Al.

比压是对铸件力学性能和显微组织最为显著的因素,其取值超过40MPa时,能有效减少缩松等缺陷,当比压超过120MPa时,除了能减轻铸造缺陷外,还对液态金属的结晶性能产生显著影响,在铸件断面上得到致密、细小且均匀的等轴晶。

In this case, the solidification of the liquid phase formed at the hipping temperature led to the formation of crystalline intergranular phases at all temperatures: however, the chemical compositions of the intergranular phases formed in the specimens with and without carbon additions were different, since for high carbon contents the resulting intergranular phase was observed to be richer in Yttrium(85% at Y/15% at Si).

在这种情况下,加压温度下液态产物的凝固在所有温度范围下都将生成间粒晶体:但是,是否添加了碳则将会使产物晶体的化学成分发生不同,因为在高碳含量下,产物晶体会更富含钇(85%Y比15%Si)另一方面,我们必须强调的时,如果Al2O3作为第三方物质加入反应混合物粉末中,那么产物晶体的结晶度将被破坏。

The results indicate that the surface of the steel wire becomes rugged in small size after the pretreatment which is very good for formation, solidification and crystallization of liquid Cu on the rugged surface of steel wire and also makes grain refinement of Cu steel inlaying each other on the interface with good bonding.

结果表明,经预处理的钢丝表面呈现细微的凸凹不平状态,特别有利于液态铜在钢丝表面异质形核、凝固、结晶,使铜和钢的晶粒在界面上相互镶嵌,达到良好结合。

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这一模式非常关注商人的网络信用基础。

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