活泼化

This article mainly reviewed the discovery and the research course of natural phosphine ,namely,how phosphine coming into being,and whether phosphine being universal existed gas in natural environment such as in aerosphere,biosphere,hydrosphere.

磷化氢是剧毒的、十分活泼的无色气体，具有强的还原性，在光照、空气等作用下，极易转化为磷的其它形态。

A mild and highly efficient ZnCl2-catalyzed direct alkylation of active methylene compounds with benzylic and allylic alcohols has been reported.

报道了ZnCl2催化的活泼亚甲基化合物和苄醇或烯丙醇的直接烷基化反应。

Second, using DBU as the base for enolization of propargylic esters of unsaturated acids 18e-k, we developed a tandem Ireland-Claisen rearrangement /isomerization reactions. It has been shown that the reaction sequence affords triene molecules 42a-b and 43a-b in moderated to high yields. Interestingly, with allyl hexa-3,5-dienoates 18i-j as the substrate, the rearranged products underwent further aromatization to give uniquely substituted benzyl acids 44a-b.

其次，以含有活泼质子的烯酸炔丙酯18e-k为底物，在DBU为烯醇化碱、TMSCl为硅试剂的条件下，底物18e-h发生了Ireland-Claisen重排/异构化串联反应，得到完全共轭的三烯类化合物42a-b及43a-b；而以己二烯酸炔丙基酯18i-j为底物时，重排/异构化后的产物进一步发生电环化等反应最终得到芳构化产物——取代苯甲酸类化合物44a-b。

Develop English teaching vivaciously , declare and lead the ethics norm of information .

发展活泼化的英语教学，宣导资讯伦理规范。

To explore new synthetic methods, we set out a careful investigation of the reaction of benzimidazolium salt with many nucleophilic agents, including the active aromatic compounds and heteratom nucleophilic agents, and found that the quaternary C=N is not so active; when benzimidazolium salt is reacted with big nitrogen nucleophilic agent? phthalimide, it does not give the expected addition product, instead, produces N-alkyl phthalimide through alkyl-transfermation from benzimidazolium salt to phthalimide.

为了开发新的合成方法，研究了苯并咪唑盐与各种亲核试剂（活泼芳环与杂原子亲核试剂）的反应，发现苯并咪唑盐不与活泼芳环及杂原子亲核试剂发生2位加成反应；在与体积较大的位阻型N亲核试剂邻苯二甲酚亚胺反应时，未得到亲核试剂与极化的C＝N的加成产物，而是得到N烷基化的邻苯二甲酰亚胺，进一步研究表明，苯并咪唑盐将1（3）位N上的烷基转移给了邻苯二甲酰亚胺，并讨论了其反应机理和取代基，溶剂效应。

The studies found that compatibility between ZDDP and succinimide dispersants primarily depended upon active α-amino-group content in succinimides. The active α-amino-group content was affected by the alkylation and amination processes, and also affected by the structure of polyisobutylene in succinimides.

研究结果表明，丁二酰亚胺与 ZDDP 的相互作用主要取决于丁二酰亚胺中活泼的伯胺氮含量，而伯胺氮含量则决定于丁二酰亚胺在生产中的烃化、胺化工艺和聚异丁烯基的结构。

Different from it, the justified act in criminal law of China is an "active element" dissociating from the traditional coupling style system of crime constitution.

与大陆法系、英美法系均将刑法中的正当化行为置于犯罪构成体系之中的做法所不同的是，刑法中的正当化行为是游离于我国传统的耦合式犯罪构成体系之外的一个&活泼元素&。

Under these conditions several aryl iodides bearing a wide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

Under these conditions several aryl iodides bearing awide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化储蓄型投资银条合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

In our research, through derivatization of stable calix[4]pyrroles, active substituting units were jointed on the calixpyrrolic skelecton. After acylamide and free radical transfer reaction, the preparation of new calix[4]pyrrole-bonded stationary phases were fulfilled. the separation abilities of them to inorganic and organic anions and medicines were exploited and new analytical methods were established. The separation mechanisms were discussed. At the same time, through using calix[4]pyrroles as additives in CZE to influence the electrophoresis of inorganic anions, the recognition mechanisms and influencing factors in supramolecular chemistry were also studied.

本项目以新型杯吡咯大环化合物分子识别化学研究为基础，设计合成了含活泼取代基的官能化杯[4]吡咯化合物，通过酰胺化反应和原位自由基链转移反应制备了新型的杯[4]吡咯色谱固定相，系统研究了具有阴离子识别功能的杯[4]吡咯大环化合物作为离子色谱的分离介质对无机、有机离子型化合物和药物分子的色谱分离性能，建立了新的分析方法，对分离机理进行了探索和验证；同时将杯[4]吡咯化合物用作毛细管电泳流动相添加剂，利用其对无机阴离子电泳行为的影响探讨超分子化学中分子识别的机理和影响因素。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。