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Three kinds of ionic liquid were used to support the acetylacetone at the C3 position directly according to the method indicated above. These synthesized ionic liquid supported acetylacetone catalysts include imidazolium salts ionic liquid supported acetylacetone catalysts, pyridinium salts ionic liquid supported acetylacetone catalysts and ammonium salts ionic liquid supported acetylacetone catalysts. All these catalysts were characterized by ~1H-NMR,~(13)C-NMR, IR and elementary analysis.

采用设计过程中预期能够提高乙酰丙酮金属催化剂催化氧化活性的修饰方式,合成了三类离子液体支载的乙酰丙酮金属催化剂:咪唑型离子液体支载乙酰丙酮金属催化剂、吡啶型离子液体支载乙酰丙酮金属催化剂、胺型离子液体支载乙酰丙酮金属催化剂,并采用核磁共振氢谱、碳谱,红外光谱及元素分析来对这些新型的催化剂进行了表征。

For further understanding the effect of the strain on K-bearing silicate mineral, an experiment with KO2 strain cultured in nitrogen-containing and nitrogen-free medium was conducted. By putting mineral powders into the medium and measuring the concentration of capsular polysaccharides, we concluded that the strain can accelerate the weathering rate of silicate minerals. The results showed that the polysaccharides secreted by the strain in the growth process could help the bacterial to adhere to the mineral surface effectively, and created the bacterium-mineral complex, which formed a mircro-enviorment avail the release of potassium. Another result was that there was higher level of Carbonic Anhydrase activity, which revealed that some exo-protein or enzyme produced by the bacterial had postive impact on the process of releasing potassium ion. We carried out the bacterial fermentation for larger scale production of the bacterial secretion, which was used to sperate, and identify the small molecules related to the mineral-bacterial interaction. After the analysis, it was found that the strain can produce many kinds of small molecules, such as 2-Hydroxybenzoic acid, 4-Hydroxyphenylacetic acid, methyl-4-hydroxybenzoate, etc.

分别将菌株接入含有不同矿粉的培养基中培养,检测其在有氮、无氮培养基中荚膜多糖含量的变化,并在以钾长石和黑云母为矿源的情况下,比较研究了菌株在有氮、无氮培养基中对矿物的风化能力,通过一系列的实验,证实胶质芽孢杆菌在生长过程中所分泌的粘稠胞外聚糖可帮助细菌有效黏附在矿物表面,形成细菌-矿物复合体,并改变及维持该复合体内部的微环境,有助于该菌的解钾作用,而且细菌分泌的胞外蛋白质在该菌对含钾硅酸盐矿物的解钾作用过程中发挥重要作用;将胶质芽孢杆菌接入以钾长石和黑云母为矿源的有氮、无氮培养基中培养,检测到该菌碳酸酐酶活性的变化,并进行批量发酵后小分子酸性分泌产物的提取、分离、纯化与鉴定等方面的研究,结果表明,该菌可产生2-羟基苯甲酸,4-羟基苯乙酸,4-羟基苯甲酸甲酯等小分子物质。

The logarithm difference values of partition coefficients of the compounds in butyl ether/water and in cyclohexane/water system were used for the measurement of the Lewis acidity, while the logarithm difference values of partition coefficients in trichloromethane/water and in tetrachloromethane/water system were used for the measurement of the Lewis basicity, and they were used successfully to differentiate the relative strength of Lewis acidity and basicity for 59 benzene and its derivates.

以化合物在正丁醚/水和环己烷/水溶剂体系中分配系数的对数差作为酸性指数,以其在氯仿/水和四氯化碳/水溶剂体系分配系数的对数差作为碱性指数,提出了一种新的度量有机物Lewis酸碱性的方法,按此方法成功地区分了59种苯系物Lewis酸碱性的相对强弱;并成功地将上述酸碱性指数引入定量结构—性质/活性相关研究之中,探讨了苯系物的正辛醇/水分配系数、水溶解度和土壤有机碳吸附系数等常见理化性质与其Lewis酸碱性间的相关性并建立了相应的定量模型,发现它们之间存在良好的相关性。

A direct method to prepare nanometre catalyst of positive electrode for methyl alcohol fuel battery is to add strong oxidant to a mixed solution of manganese nitrate and some other metal nitrate, to coat them on the graphite electrode to have catalyst precursor produced, then to prepare the non-platinum nanometre catalyst of metal ion-doped manganese dioxide with carbon as a carrier by thermolytic reaction of the in-situ precursor. The prepared catalyst has the advantages of high electrical catalytic activity of methyl alcohol, high performance to protect against CO poison and low price, and it can lower the battery manufacturing cost effectively as well as can raise the entire electrical property of the battery so that the price performance and the market competitive edge of the battery are enchnaced effectively.

一种直接甲醇燃料电池阳极纳米催化剂的制备方法是在硝酸锰和其它金属硝酸盐的混合溶液中加入强氧化剂,涂抹于石墨电极上制成催化剂先驱体,通过先驱体在原位的热分解反应来制备以碳为载体的金属离子掺杂二氧化锰非铂纳米催化剂;制得的催化剂具有高的甲醇电催化活性、高的抗CO毒化性能以及低廉的价格等优点,可以有效地降低电池的制造成本,提高电池的整体电性能,从而有效地提高直接甲醇燃料电池的性能价格比及市场竞争能力。

Type-B Nodule: The source of elements in the nodules comes from slow deposition of the overlying water and the diffusion of the pore water, which comes mainly from the double decomposition reaction of Fe, Mn oxides caused by the oxidation diagenesis of organic material in sediment and its forming process and distribution is controlled by pH in the pore water. There is no corrlation between distribution of the nodules and water depth, topograph.

A型结核主要分布于深海火山沉积环境区,受上覆水Mn〓和Eh制约;B型结核一方面由于在深海火山沉积环境区,受生物作用影响,另一方面在生物沉积环境区,又受火山作用影响,使此类结核的分布与大洋地貌和沉积物的关系不明显;C型结核主要分布在太平洋CCD范围内,受沉积环境上生物和活性有机碳的制约。

The electroactive species Fe2+ can be transported easily through the thin films of KVFe6 to the underlaying glassy C electrode surface to be oxidized directly at less pos. potential, and it can also be oxidized at the film at more pos. potential by means of redox sites in the film.

电活性质点Fe^3^+可穿透六氰亚铁钒薄膜在玻璃碳基体电极表面于较负电位处直接氧化,也可经VHF膜中氧化还原点位的媒介在较正电位处理膜-溶液界面及膜内部发生催化氧化。

The removal efficiency of L-acid and TOC of solution is 57% and 53% respectively when 0.4 g doped photocatalyst is applied in 100 mg·L-1 L-acid solution illuminated by visible light for 4 hours, while it is 13% and 10% respectively in the case of the undoped photocatalyst.

Mo6+的掺杂不影响负载催化剂的紫外光活性及对L-酸的吸附能力。100 mg·L-1的L-酸溶液加0.4 g催化剂,在可见光下反应4 h,掺杂催化剂对L-酸和溶液总有机碳的去除率分别为57%和53%,而未掺杂的催化剂去除率分别为13%和10%。

This experiment takes the sweet potato leaf as the primary data, the white granulated sugar, and the corn syrup as the carbon source, and the active white liquor dry yeast as ferments the fluid , uses the liquid zymotechnics to brew the sweet potato leaf to incite the tonic , and discovers the most superior saccharification condition through the contrast experiment.

试验以红薯叶为主要原料,以白砂糖、玉米糖浆为碳源,以活性白酒干酵母为发酵液,采用液体发酵法酿造红薯叶滋补酒,并通过对比试验找出最优糖化条件:浸提温度80℃,浸提时间2h,加水比1:40。

The evaporation rate of element La at different temperatures in carbonized Mo-La2O3 cathode were calculated according to thermodynamics theory.

摘 要:从理论上计算了碳化Mo-La2O3热阴极材料在不同温度下活性物质镧元素的蒸发速度,分析了镧元素蒸发对材料热电子发射及其稳定性的影响。

Chlorine atoms were selectively introduced into the chlorin ring based on different reactivity between vinyl group at 3-position and 20-meso position by electrophilic addition and electrophilic substitution using hydrogen peroxide/hydrochloric acid, N-chlorosuccinimide, hydrogen chloride (or concentrated hydrochloric acid) as chlorinating reagent.

以过氧化氢/盐酸、N-氯代丁二酰亚胺、氯化氢为氯化剂,根据3-乙烯基和20-meso-位的不同化学反应活性,通过亲电加成和亲电取代反应,在二氢卟吩环上选择性地引进氯原子,完成8种未见报道的具有叶绿素-a基本碳架的氯代二氢卟吩衍生物的合成。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

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