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The results show that the higher yield of CNF obtained by decomposition of carbon monoxide than that of methane over a series of alumina supported Ni/Fe catalysts prepared by deposition-precipitation method is attributed to the role of produced carbon dioxide and the different carbon diffusion mode on metal particle.

结果发现: 1。当采用CO为碳源时,催化剂在36小时内具有较为稳定的活性,当采用CH〓为碳源时,催化剂中Fe的存在不利于得到较高产率的纳米碳纤维;不同的纳米碳纤维产率与生长过程中形成的CO〓及碳在金属表面或者体相中的传递行为密切相关; 2。

The citric acid-producing strain Aspergillus niger 2363-2, was isolated and used in our research. The fermentation conditions were optimized as follows: sucrose as carbon source 8. 0-14. 0%, ammonium chloride as nitrogen source 3. 0-4. 0g/l, initial pH 2. 0, and cultural temperature 30℃. The influential factors of formation of spores were also studied, and a series of measures were taken to restrain the spore formation on the basis of our experimental results. With the consideration of the cultural environment and microbial cell itself, the factors affecting the duration of citric acid-producing activity of microbial cells were examined, and it is found that undissociated citric acid and the ageing of microbial cells are the main factors. The experimental results also show that partial replacement of fermentation broth can lengthen the duration of citric acid -producing acitivity of microbial cells.

筛选出了用于试验研究的柠檬酸发酵用菌Aspergillus niger 2363-2,确定了其最适发酵条件—碳源选用蔗糖,浓度8.0~14.0%,氮源为NH〓Cl,浓度3.0~4.0g/l,发酵初始pH值为2.0,培养温度30℃;讨论了分生孢子产生的影响因素,并通过试验提出了抑制分生孢子产生的措施;从分析微生物所处的环境和微生物本身两个方面出发,探讨了影响微生物菌体产酸活性持久性的因素,认为分子态柠檬酸和菌体本身的老化是影响微生物产酸活性持久性的两个主要因素,并提出采用部分置换发酵液发酵能延长微生物菌体的产酸活性。

The activity test shows that the Ni/Ce-Zr-Al-Ox catalyst has a CH4 conversion of 89% and a good stability, and the CH4 conversion increases to 94% by adding 3.2% steam. In addition, due to the suppression to unreactive carbon, it can be expected that the stability of catalyst will be further promoted.

活性测试结果表明, Ni/C-Zr-Al-Ox催化剂显示了89%的CH4转化率和良好的稳定性,添加3.2%的水蒸汽后活性提高到94%,由于对非活性积碳的抑制,可以预料其稳定性也将进一步提高。

Domestic products raw material, which bastnasite was used as active component for DeSOx additives, were selected to use for the first time, the bastnasite can replace industrial cerium nitrate, it may improve DeSOx activity and abrasive resistance, due to admission bastnasite, but also reduce cost of material of DeSOx additives.

本文采用三种方法拟在活性组分的选择、活性评价及作用机理等方面对DeSOx添加剂强度进行有益的探索;尤其首次选用国产原料——氟碳铈矿作为镁铝尖晶石DeSOx添加剂的活性载体,使得氟炭铈矿可以代替工业硝酸铈,它既可提高脱硫添加剂的活性和耐磨强度,还可以降低原料成本。

The chemical activating mechanism of UA is that CG can stimulate pozzolanicity more effective than gypsum because of higher solubility and looser crystal structure; but CG has poor property on retardation setting, and this shortage can be solved by mixing with gypsum; CS can offer alkali activity, which can depolymerize silica and aluminum glass, and benefit for other activity methods and overcome the disadvantage of HF on setting time; Sodium sulfate improves early strength greatly but loses the final strength. NF can improve both early and final strengths.

联合激发技术的化学激发机理是,煅烧石膏溶解度高及晶体结构松弛,比天然石膏的活性激发效率高,但降低石膏的缓凝作用,与天然石膏混合既可提高活性又能保持缓凝作用;干法电石渣提供碱激发,促进高钙灰中硅、铝玻璃体解聚,并克服高钙灰对凝结时间的不利影响;硫酸钠虽然早强作用明显,但使后期强度倒缩,NF使各龄期活性都得到提高;磨细的物理激发使高钙灰大颗粒中的CaO和富集碳组分被磨细、分散,活性增加而危害性降低。

With the soil planted the konjac as the investigation and study object and planted corn as CK, the soil organic carbon, soil active organic matter, soil entire nitrogen, edaphon quantity and edaphon community structure was determined. The change of soil carbon nitrogen, edaphon carbon nitrogen and edaphon bacterium and fungus was analyzed.

方法]以种植魔芋地的土壤作为调查研究对象,用种植玉米的土壤作为对照,测定土壤有机碳、土壤活性有机质、土壤全氮、土壤微生物量和土壤微生物群落结构,分析土壤碳氮、土壤微生物碳氮和土壤微生物细菌和真菌的变化。

These results indicate that tungsten carbide decorating on the surface of carbon nanotube is one of the effective ways to improve its electrocatalytic activity.

这说明将碳化钨复合到纳米碳管的外表面是提高碳化钨电催化活性的有效技术方法之一。

The thermodynamic functions of NO removal by low carbon hydrocarbons such as methane, ethane, ethene, ethine, propane and propene are calculated,and enthalpy changes of reaction producing activated particles from low carbon hydrocarbons in electric field are calculated to find out the appropriate low carbon hydrocarbons for removing NO.

通过计算甲烷、乙烷、乙烯、乙炔、丙烷和丙烯等低碳烃与NO反应的热力学函数和低碳烃在电场作用下产生活性粒子的反应焓变,找出合适的低碳烃作为脱除NO的添加剂。

Compared with the bare carbon paste electrode, the anodic peak potential shifted negatively by 0.152V and the cathodic peak potential shifted positively by 0.161V for CVs of hydroquinone on the CAW modified carbon paste electrode. The reversibility of the reaction became obviously better, showing the high electrocatalytic activity of CAWs to electrochemical oxidation of Hydroquinone.

与未加碳原子线的空白碳糊电极相比,碳原子线修饰碳糊电极可使对苯二酚的氧化峰负移0.152V,还原峰正移0.161V,ΔEp减小了0.313V,反应的可逆性明显变好,说明该电极具有较高的电催化活性。

Due to the suppression of reverse water gas shift reaction by adding steam in feed gas, more CO〓 participated in and promoted CO〓 reforming of CH〓 reaction, higher catalytic activity and less carbon deposition were obtained. On the surface of used catalyst there were two kinds of carbon species deposited on catalyst, one was decomposed CH〓 fragment, and the another was graphiticlike carbon.

在反应后催化剂表面有两类碳物种,一类在250~350℃出现的少量α-碳,应主要是活性高的CH〓解离碎片,一类是在700℃附近出现的β-碳,应是导致催化剂失活的类石墨化碳。

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