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活性炭

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The less the oxygen content and the more content of N element in the form of pyrrole-N were observed under stronger microwave power radiation. It was affirmed that the desulfurization capability of activated carbon could be greatly increased by microwave modification. According to the analysis on surface physical and chemical characteristics, a mechanism was concluded: Modified by microwave, functional groups begin to dissociate, alkalescency is enhanced, and surface oxygen content is reduced; the amount of active sites produced by dissociation of oxygen-containing groups increased, so did the pyrrole-N groups. Apparently, the activated energy of SO〓 adsorption decreased.

通过比较微波改性活性炭前后的吸附脱硫能力,结合它们的表面物理和化学性质的变化分析,确认微波改性活性炭的脱硫性能有显著提高,其作用机理在于微波处理后,活性炭表面微观形貌发生了较大的变化,化学基团发生分解,碱性特征增强,表面含氧量减少,以CO形式释出的含氧官能团分解后产生的活性部位和吡咯氮官能团数量增加,吸附SO〓的表观活化能降低。

In addition, the study on ionic liquid being used as the electrolyte of EDLC was carried out extraneously, a good result of 310F/g was obtained. That the possibility of spherical active carbon used as the electrode materials was also investigated for the convenient preparation of electrode, the specific capacitance of spherical active carbon was 188F/g, having directive function for the preparation from powder SAC to spherical active carbon.

另外,本项目也额外进行了离子液体作为电解液性能的研究,获得了比电容高达310F/g好结果;考虑到电极制作,又研究了活性炭微球作为电极的可能性,得到了比电容为188F/g的结果,为下一步将粉状的超级活性炭制作为球状的活性炭提供了指导与借鉴作用。

Powdered activated carbon, shaped and unshaped activated carbon is made respectively.

并分别得到了定型颗粒活性炭、不定型颗粒活性炭和粉状活性炭

We used wood tar as a blending agent to produce shaped activated carbon and the abrasion resistance of it is larger than 85%; the BET surface area is 1577.55m2/g. The abrasion resistance of unshaped activated carbon is 80% and BET surface area is 1789.87m2/g. The ash contents of powdered activated carbon, and unshaped activated carbon prepared by physical method are less than 0.2%; the iodine number is 1200 mg/g; the maximum 0.15% methylene blue adsorption value is 18ml/0.1g.

其中定型颗粒活性炭是用木焦油为粘合剂,最终产品的强度在85%以上,比表面积为1577.55m~2/g;实验中所制备的不定型颗粒活性炭和粉状活性炭的灰分含量不超过0.2%;碘吸附值达到1200mg/g;亚甲基蓝最高吸附值为18.0ml/0.1g。

The method comprises the steps of dipping and mixing the mipor asphaltic base globular active carbon prepared by the traditional method with an inorganic metal salt solution by a certain ration; heating under an inert atmosphere to 600 to 1200 DEG C at a temperature increasing rate of 1 to 20 DEG C/min for the secondary carbonization; using acid to wash off the remaining metal inside the carbonized material, so as to obtain the asphaltic base globular active carbon with a high mesoporous rate and narrow distribution of mesoporous spertures.

本发明提供了一种浸渍金属盐二次炭化制备中孔沥青基球形活性炭的方法,该方法是将传统方法制备得到的微孔沥青基球形活性炭按一定比例与无机金属盐溶液浸渍混合,然后在惰性气氛下以1~20℃/min的升温速率加热到600~1200℃下进行二次炭化,炭化料经酸洗除去内部残留的金属后,可制得中孔率较高、中孔孔径分布窄的沥青基球形活性炭

The results showed that loading Ag^+, Ni^2+, Cu^2+ or Zn^2+ ion on the activated carbon obviously improved its adsorption of benzothiophene, while loading Fe^3+ or Co^3+ ion on the activated carbon caused a decrease in its adsorption of benzothiophene in comparison with the original unloaded activated carbon, which was due to the variation of the nature of soft and hard acid on the surface of the activated carbon.

采用密度泛函数理论法计算结果表明,苯并噻吩的电负性χ为2.638,属软碱类物质;由于Ag^+为软酸,活性炭负载Ag^+离子,增加了其局部表面的软酸,从而增强了对苯并噻吩硫化物的吸附;由于Ni^2+、Cu^2+和Zn^2+离子属交界酸,负载Ni^2+、Cu^2+、Zn^2+离子增加了活性炭表面的交界酸,也在一定程度上提高了其表面对苯并噻吩硫化物的吸附;当活性炭表面负载了硬酸性Fe^3+或Co^3+离子,其局部表面硬酸增大从而降低了其对苯并噻吩的吸附。

By separating the crude oligosaccharide products with various ratios of activated charcoal and Celite, the results indicate that the products from 30% lactose (L30) had an adsorption percentage of 96.3%, the highest one among all mixtures of activated charcoal and Celite. The following fractionation by eluting successively with 10% and 20% ethanol aqueous solutions gave an oligosaccharide yield of 13.5% and a purity of 97.9%.

合成的寡醣以不同比例活性炭和矽藻土吸附分离,结果发现30%乳糖组(L30)经单活性炭组吸附即有96.3 %的寡醣吸附力,是所有活性炭与矽藻土混合组别中最高者,再经10 %与20 %乙醇冲提画分后可得13.5 %的收率,其寡醣纯度更高达97.9 %。

Another remarkable characteristic of printing and dye the waste water is that the colour is high, is it adopt biological carbon pool is it is it deal with to decolour to go on to it , for activated carbon absorbent spent to design originally, active charcoal adsorption method to utilize porous active charcoal material make one or many kinds of material of waste water it absorbs to be that surface get rid of in active charcoal.

印染废水的另一显著特点就是色度高,本设计采用生物碳池对其进行脱色处理,所用的吸附剂为活性碳,活性炭吸附法就是利用多孔活性炭物质使废水中的一种或者多种物质被吸附在活性炭表面而去除的。

The main problems resulting from the active carbon discolorization from GF extraction liquor in industry are the entrainment of GF in active carbon and environmental pollution due to pile-up and disposal of spent active carbon.

目前工业上采用的活性炭提取液脱色存在的主要问题是,活性炭中难免夹带有灰黄霉素,废弃活性炭的堆积与处置对环境造成污染。

Single ozone oxidation,single active carbon absorption and ozone oxidation-active carbon absorption technology were studied in order to discuss the practicability of removal of micro-content nitrobenzol in drinking water.

通过对O3氧化、活性炭吸附和O3氧化-活性炭吸附工艺的研究,探讨O3-活性炭工艺去除饮用水中少量硝基苯的可行性。

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