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活化能

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It is shown that the weight gains in the static oxidation of the material under air atmosphere obey the parabolic law.

随弥散相SiC和C的增加,其氧化活化能有不同程度的降低。

The alcoholysis of trichlorosilane has been studied experimentally and theoretically,each step is cooperating endothermic process.

采用溶剂法和B3LYP/6-31G基组研究了三氯硅烷的乙醇解反应,计算得出每一步醇解均为放热反应,并得出了反应的最佳温度、最佳进样方式、主反应和副反应的活化能及其可能的反应途径曲线。计算结果和实验结果有较好的一致性

Progress on preparation and purification of trichlorosilane ;2. Study on synthesis of trifluoropropyl trichlorosilane ;3. The alcoholysis of trichlorosilane has been studied experimentally and theoretically,each step is cooperating endothermic process.

采用溶剂法和B3LYP/6-31G基组研究了三氯硅烷的乙醇解反应,计算得出每一步醇解均为放热反应,并得出了反应的最佳温度、最佳进样方式、主反应和副反应的活化能及其可能的反应途径曲线。

The less the oxygen content and the more content of N element in the form of pyrrole-N were observed under stronger microwave power radiation. It was affirmed that the desulfurization capability of activated carbon could be greatly increased by microwave modification. According to the analysis on surface physical and chemical characteristics, a mechanism was concluded: Modified by microwave, functional groups begin to dissociate, alkalescency is enhanced, and surface oxygen content is reduced; the amount of active sites produced by dissociation of oxygen-containing groups increased, so did the pyrrole-N groups. Apparently, the activated energy of SO〓 adsorption decreased.

通过比较微波改性活性炭前后的吸附脱硫能力,结合它们的表面物理和化学性质的变化分析,确认微波改性活性炭的脱硫性能有显著提高,其作用机理在于微波处理后,活性炭表面微观形貌发生了较大的变化,化学基团发生分解,碱性特征增强,表面含氧量减少,以CO形式释出的含氧官能团分解后产生的活性部位和吡咯氮官能团数量增加,吸附SO〓的表观活化能降低。

The results showed that alkylation of benzene with ethanol occurred via stepwisemechanism.

结果表明,苯与乙醇的烷基化按照分步机理进行,速控步骤的活化能为170.34 kJ/mol。

The conductivity of amphibolite can be fit to Arrhenius equation at 1.0 GPa and 200-700℃, the pre-exponential factor is 25.78-105.32 S/m and the activation energy is 0.57-0.66 eV.

在1.0 GPa、200~700℃条件下,斜长角闪岩样品的电导率符合Arrhenius公式,指前因子为25.78~105.32 S/m,活化能为0.57~0.66 eV。

The activation energy of the reaction with solid super acidic catalyst is obviously lower than that of the reaction without catalyst, Sugesting that S2O8(superscript 2-)/TiO2-Al2O3 is the the effective catalyst of the synthesis of amyl acetate.

固体超强酸S2O82-/TiO2-Al2O3使反应活化能明显降低,是乙酸异戊酯合成的有效催化剂。

Based on the analysis on activation energy between anhydrite and hydrocarbon, the heavy hydrocarbons will be firstly consumed in the TSR process.

通过烃类与硬石膏反应的活化能分析可知,TSR反应是一个优先消耗重烃的过程。

Non-isothermal combustion shows that the apparent activation energy and the frequency factor both decreased with increasing bitumious coal content...

非等温燃烧的研究表明,以特征温度区间计算,表观活化能和频率因子均随混煤中烟煤比例的增加而降低。

We have also studied the kinetics of the cyclohexene epoxidation catalyzed by 2 with TBHP and the apparent reaction order, frequency factor and activation energy are obtained.

本文对该反应的动力学及热力学性质也进行了研究,确定了表观反应级数、速率常数和反应活化能

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。